Chapter 13.8, Problem 13P

Interpretation Introduction

Interpretation: The products formed from monochlorination of $\left(R\right)\text{-2-bromobutane}$ at $\text{C1}$ and $\text{C4}$ are to be predicted. $R$ and $S$ designations to each stereogenic centers is to be assigned.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from $\text{C}-\text{H}$ sigma bond of the alkane.