Concept explainers
(a)
Interpretation: The constitutional isomers formed by the monochlorination of given
Concept introduction: The compounds with same chemical formula but different arrangement of atoms in space are known as the constitutional isomers.
The reaction of halogen with alkane results in the formation of
Answer to Problem 27P
The five constitutional isomers formed by the reaction of
The four constitutional isomers formed by the reaction of
Explanation of Solution
The compounds with same chemical formula but have different arrangement of atoms in space is known as the constitutional isomer.
The reaction of halogen with alkane results in the formation of alkyl halide. This type of reaction is a radical substitution reaction. The halogenation of alkanes takes place via radical intermediates. If
The given alkanes are shown below.
Figure 1
The given structure is in ball and stick model. The white color balls represent hydrogen atom and black color ball represents carbon atoms.
Therefore, structure of given alkanes are,
Figure 2
The constitutional isomers formed by the reaction of
Figure 3
Therefore, the five constitutional isomers formed by the reaction of
Similarly, the constitutional isomers formed by the reaction of
Figure 4
Therefore, the four constitutional isomers formed by the reaction of
The constitutional isomers formed by monochlorination of given alkanes with
(b)
Interpretation: The major bromination product formed by heating each alkane with
Concept introduction: The reaction of hydrogen halide with alkane results in the formation of alkyl halide. The halogenation of alkanes takes place via radical intermediates. If
Answer to Problem 27P
The major product formed by the reaction of
The major product formed by the reaction of
Explanation of Solution
The reaction of hydrogen halide with alkane results in the formation of alkyl halide. The halogenation of alkanes takes place via radical intermediates. If
The major product formed by the reaction of
Figure 5
The major product formed by the reaction of
Figure 6
The major product formed by monochlorination of given alkanes with
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Chapter 13 Solutions
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