Concept explainers
(a)
Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.
Concept introduction: Halogens react with
Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.
The reaction between bromine and
(b)
Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.
Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from
Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.
In the presence of peroxide, alkene is oxidized to
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Chapter 13 Solutions
ORG CHEM CONNECT CARD
- Draw structures corresponding to the following IUPAC names: (a) 1, 1-Dimethylcyclooctane (b) 3-Cyclobutylhexane (c) 1, 2-Dichlorocyclopentane (d) l, 3-Dibromo-5-methylcyclohexanearrow_forwardDraw the structures of the following molecules: (a) trans-l-Bromo-3-methylcyclohexane (b) cis-1, 2-Dimethylcyclobutane (c) trans-1 -tert-Butyl-2-ethylcyclohexanearrow_forwardPlease be clear in your writingarrow_forward
- What is the proper name for the following compound? CH;CH2 CH,CH2CH,Br C=C CH;CH2 CH3 O 1-bromo-5-ethyl-4-methyl-3-heptene O 7-bromo-3-ethyl-4-methyl-3-heptene O cis-7-bromo-3-ethyl-4-methyl-3-heptene 1-bromo-3-pentenyl-2-pentene O trans-7-bromo-3-ethyl-4-methyl-3-heptenearrow_forwardWhen 2-pentene is treated with Cl, in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages). CI OCH3 H,CO CI CI CI Cle CH;CHCHCH,CH, + CH;CHCHCH,CH3 + CH,CHČHCH,CH, CH;OH CH;CH=CHCH,CH, 50% 35% 15%arrow_forwardDraw the structure of an alkane with molecular formula C7H16 that contains (a) one 4° carbon; (b) only 1° and 2° carbons; (c) 1°, 2°, and 3° hydrogens.arrow_forward
- What is the name of the organic reactant and the resulting product of the reaction below? H H H H H H H-C-C-ċ=ċ-ċ-c-H + CI-CI H H H H O reactant: cis-3-hexene; product: 3,4-dichlorohexane reactant: trans-3-hexene; product: 3,4-dichlorohexane O reactant: cis-3-hexene product: 3,4-chlorohexane O reactant: cis-3-hexene product: dichlorohexanearrow_forwardGive the proper IUPAC name for the following compounds: CH,- CH, CH,- CH - CH -CH, CH, Br CH CH, Br H:-CH; CH - CH-CH, H;C CH, CH, CH, CH- CH- CH, c=C H,C-CH, CH, CH- CH, H H ОН CIarrow_forwardDraw the product and indicate the stereochemistry when the given alcohol is treated with each reagent: (a) HBr; (b) PBr3; (c) HCl; (d) SOCl2 and pyridine.arrow_forward
- (b) Complete the following reactions : (i) D H3C CH3 H H كما .NO2 B | Bra/Dioxane .COCH3 Aarrow_forward4. The scheme below shows the reaction of a ketone, 2-propanone with methanol. ОН :0 : || CH;-C-CH3 : ОН + H - Н CH,-C-CH3 CH;-C-CH3 N step 1 step 2 step 3 P CH;OH CH3 CH;OH step 4 OCH, CH,-C-CH3 H - H,0 R CH;-C-CH3 step 7 step 6 step 5 OCH3 OCH; i) Write the missing structures (N, O, Q and R) in the above reaction scheme. ii) Name the class of compounds P and S belong to? iii) This is an acid catalyzed reaction. What does this statement mean? iv) Draw the arrow diagram in step 6 to show how intermediate R is formed? Write the equation for this step ONLY. v) Steps 3 and 7 involve loss of a proton from the intermediate ions. Why is this step necessary?arrow_forwardThe action of heating one mole of water (containing a trace of acid catalyst) on one mole of compound Y produces one mole of CH,COOH and one mole of CH, CH,NH, The structure of Y is: Select one: O CHCNCCH, CH,CH,NHCH,CH, OH CH CHNHCH,CH, O CHCH,CNHCH; O CH;CH NHÖCH;arrow_forward
