Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134564586
Author: Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 13.4, Problem 13.32PP
What are the kind and number of atoms in the ring portion of the Haworth structure of fructose?
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Complete boxes in the flow chart. Draw the structure of the organic compound foundin each layer after adding 3M NaOH and extraction. Make sure to include any charges. Provide explanation on answers.
==
Vid4Q2
Unanswered
☑
Provide IUPAC name of product in the reaction
below
A 3,4-dimethylcyclohexene
B 1,2-dimethylcyclohexane
C 1,2-dimethylcyclohexene
D 3,4-dimethylcyclohexane
H₂
Pd
5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
Chapter 13 Solutions
Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
Ch. 13.1 - Prob. 13.1PPCh. 13.1 - Prob. 13.2PPCh. 13.1 - Prob. 13.3PPCh. 13.1 - Prob. 13.4PPCh. 13.1 - Prob. 13.5PPCh. 13.1 - Prob. 13.6PPCh. 13.1 - Prob. 13.7PPCh. 13.1 - Prob. 13.8PPCh. 13.1 - Prob. 13.9PPCh. 13.1 - Prob. 13.10PP
Ch. 13.2 - Prob. 13.11PPCh. 13.2 - Prob. 13.12PPCh. 13.2 - Prob. 13.13PPCh. 13.2 - Prob. 13.14PPCh. 13.2 - Prob. 13.15PPCh. 13.2 - Prob. 13.16PPCh. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify each of the following as D or L: a. b. c.Ch. 13.2 - Identify the chiral carbon in each of the...Ch. 13.2 - Prob. 13.20PPCh. 13.3 - Prob. 13.21PPCh. 13.3 - Prob. 13.22PPCh. 13.3 - Prob. 13.23PPCh. 13.3 - Prob. 13.24PPCh. 13.3 - Prob. 13.25PPCh. 13.3 - Prob. 13.26PPCh. 13.3 - Prob. 13.27PPCh. 13.3 - Prob. 13.28PPCh. 13.3 - Prob. 13.29PPCh. 13.3 - Prob. 13.30PPCh. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - What are the kind and number of atoms in the ring...Ch. 13.4 - Prob. 13.33PPCh. 13.4 - Prob. 13.34PPCh. 13.4 - Prob. 13.35PPCh. 13.4 - Identify each of the following as the a or ß...Ch. 13.5 - Prob. 13.37PPCh. 13.5 - Prob. 13.38PPCh. 13.5 - Prob. 13.39PPCh. 13.5 - Prob. 13.40PPCh. 13.6 - Prob. 13.41PPCh. 13.6 - Prob. 13.42PPCh. 13.6 - Prob. 13.43PPCh. 13.6 - Prob. 13.44PPCh. 13.6 - Prob. 13.45PPCh. 13.6 - Prob. 13.46PPCh. 13.7 - Describe the similarities and differences in the...Ch. 13.7 - Prob. 13.48PPCh. 13.7 - Prob. 13.49PPCh. 13.7 - Prob. 13.50PPCh. 13.7 - Prob. 13.51PPCh. 13.7 - Prob. 13.52PPCh. 13.7 - Prob. 13.53PPCh. 13.7 - Prob. 13.54PPCh. 13 - Prob. 13.55UTCCh. 13 - Prob. 13.56UTCCh. 13 - Prob. 13.57UTCCh. 13 - Prob. 13.58UTCCh. 13 - Prob. 13.59UTCCh. 13 - Prob. 13.60UTCCh. 13 - Prob. 13.61APPCh. 13 - Prob. 13.62APPCh. 13 - Prob. 13.63APPCh. 13 - Prob. 13.64APPCh. 13 - Prob. 13.65APPCh. 13 - Prob. 13.66APPCh. 13 - Prob. 13.67APPCh. 13 - Prob. 13.68APPCh. 13 - Prob. 13.69APPCh. 13 - Prob. 13.70APPCh. 13 - Prob. 13.71APPCh. 13 - Prob. 13.72APPCh. 13 - Prob. 13.73APPCh. 13 - Prob. 13.74APPCh. 13 - Prob. 13.75CPCh. 13 - Prob. 13.76CPCh. 13 - 13.77 Gentiobiose is found in saffron. (13.4,...Ch. 13 - Prob. 13.78CP
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