The assumptions made about the volume of the actual molecules themselves in a sample of gas, compared to the bulk volume of the gas overall should be determined. Concept Introduction: Using the kinetic theory of gas, the behavior of an ideal gas is explained. This defined the behavior of individual particles of the gas. The following are the postulated of the kinetic theory of gas: The gas is composed of small particles. The size of the particles is very small thus; volume of a single particle of the gas is negligible. The particles of gas are in constant random motion, they colloid with each other and the container’s wall in which they are kept. The interaction between the gaseous molecules is assumed to be negligible. The kinetic energy of the gas is directly proportional to the temperature of gas in Kelvin temperature.

Question

1. For the four structures provided, Please answer the following questions in the table below. a. Please draw π molecular orbital diagram (use the polygon-and-circle method if appropriate) and fill electrons in each molecular orbital b. Please indicate the number of π electrons c. Please indicate if each molecule provided is anti-aromatic, aromatic, or non- aromatic TT MO diagram Number of π e- Aromaticity Evaluation (X choose one) Non-aromatic Aromatic Anti-aromatic || ||| + IV

Answer 1

Question

Chapter 13, Problem 77QAP

Interpretation Introduction

Interpretation:

The assumptions made about the volume of the actual molecules themselves in a sample of gas, compared to the bulk volume of the gas overall should be determined.

Concept Introduction:

Using the kinetic theory of gas, the behavior of an ideal gas is explained. This defined the behavior of individual particles of the gas.

The following are the postulated of the kinetic theory of gas:

The gas is composed of small particles.

The size of the particles is very small thus; volume of a single particle of the gas is negligible.

The particles of gas are in constant random motion, they colloid with each other and the container’s wall in which they are kept.

The interaction between the gaseous molecules is assumed to be negligible.

The kinetic energy of the gas is directly proportional to the temperature of gas in Kelvin temperature.

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