Principles of Chemistry: A Molecular Approach (3rd Edition)
3rd Edition
ISBN: 9780321971944
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 13, Problem 6E
Interpretation Introduction
Interpretation:
The rate of change in the concentration of reactants and products for the given reaction is to be calculated and the given table is to be completed.
Concept introduction: The rate of a reaction is defined as the change in concentration of the reactants or the products per unit time.
To determine: The complete table.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 13 Solutions
Principles of Chemistry: A Molecular Approach (3rd Edition)
Ch. 13 - Prob. 13.1PCh. 13 - Prob. 13.2PCh. 13 - Prob. 13.3PCh. 13 - Prob. 13.4PCh. 13 - Prob. 13.5PCh. 13 - Prob. 13.6PCh. 13 - Prob. 13.7PCh. 13 - For Practice 13.8
Use the results from Example...Ch. 13 - Prob. 13.9PCh. 13 - Prob. 1SAQ
Ch. 13 - Prob. 2SAQCh. 13 - Prob. 3SAQCh. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - Prob. 7SAQCh. 13 - Prob. 8SAQCh. 13 - Prob. 9SAQCh. 13 - Prob. 10SAQCh. 13 - Prob. 11SAQCh. 13 - Prob. 12SAQCh. 13 - Prob. 13SAQCh. 13 - Which single-step reacton, according to :collision...Ch. 13 - Carbon monoxide ard chlorine gas react to form...Ch. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Prob. 6ECh. 13 - Prob. 7ECh. 13 - Consider the reaction. NO2(g)NO(g)+12O2(g) The...Ch. 13 - Consider the reaction. H2(g)+Br2(g)2HBr(g) The...Ch. 13 - Consider the reaction. 2H2O2(ag)2H2O(l)+O2(g) This...Ch. 13 - Prob. 11ECh. 13 - Prob. 12ECh. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - The tabuated data show the concentration of N2O5...Ch. 13 - Prob. 27ECh. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - Prob. 31ECh. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Prob. 34ECh. 13 - Prob. 35ECh. 13 - A chemical reaction is endothermic and has an...Ch. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - If a temperature increase from 20.0 °C to 350 °C...Ch. 13 - Prob. 49ECh. 13 - Which of these two reactions would you expect to...Ch. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - consiaer this three-step mechanism for a...Ch. 13 - Consider this two-step mechanism for a reaction....Ch. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - The tabulated data were collected for this...Ch. 13 - Prob. 61ECh. 13 - Consider the reaction: 2O3g3O2g with this rate...Ch. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Prob. 71ECh. 13 - Prob. 72ECh. 13 - Prob. 73ECh. 13 - Prob. 74ECh. 13 - Prob. 75ECh. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Consider the reaction....Ch. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - The f̀rst-order integrated rate law for a reaction...Ch. 13 - Prob. 89ECh. 13 - 90. The rate constant for the first-order...Ch. 13 - Phosgene (Cl2CO), a poison gas used in World War...Ch. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - Consider the reaction CHCl3(g) + Cl2(g) CCL4(g) +...Ch. 13 - Prob. 95ECh. 13 - Prob. 96E
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