Chemistry for Changing Times
14th Edition
ISBN: 9780134212777
Author: John W. Hill; Terry W. McCreary
Publisher: Pearson Education (US)
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Chapter 13, Problem 57P
Interpretation Introduction
Interpretation:
The increase in concentration of carbon dioxide over the last 130 years should be calculate and express the result in percentage.
Concept introduction:
The rise of carbon dioxide concentration in atmosphere starts after industrial revolution, as the concentration of carbon dioxide increases due to industrial and vehicle emissions.
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For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 →> NO₂+ NO3_(K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 →
→
NO2 + O2 + NO (K2)
NO + N2O5-
NO2 + NO2 + NO2 (K3)
d[N₂O5] __2k‚k₂[N2O5]
Indicate whether the following rate expression is acceptable:
dt
k₁₁+ k₂
Consider the following decomposition reaction of N2O5(g):
For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 → NO2 + NO3 (K1)
NO2 + NO3 → N2O5 (k-1)
NO2 + NO3 → NO2 + O2 + NO (K2)
NO + N2O5 → NO2 + NO2 + NO2 (K3)
Indicate whether the following rate expression is acceptable:
d[N2O5]
= -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³
dt
In a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.
Chapter 13 Solutions
Chemistry for Changing Times
Ch. 13 - Prob. 1RQCh. 13 - Name on replacement for CFCs. What problems are...Ch. 13 - Prob. 3RQCh. 13 - Prob. 4RQCh. 13 - Prob. 5RQCh. 13 - Prob. 6RQCh. 13 - Prob. 7RQCh. 13 - Prob. 8RQCh. 13 -
9. What makes photochemical smog different...Ch. 13 - Prob. 10RQ
Ch. 13 - Prob. 11PCh. 13 - Prob. 12PCh. 13 - Prob. 13PCh. 13 - Prob. 14PCh. 13 - Prob. 15PCh. 13 - Prob. 16PCh. 13 - Prob. 17PCh. 13 - Prob. 18PCh. 13 - For Problems 19-22, write the balanced equation...Ch. 13 - For Problems 19-22, write the balanced equation...Ch. 13 - Prob. 21PCh. 13 - For Problems 19-22, write the balanced equation...Ch. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Prob. 27PCh. 13 - Describe two ways in which the level of nitrogen...Ch. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Prob. 44PCh. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Prob. 51PCh. 13 - 52. What kind of particulate matter is often found...Ch. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - Prob. 55PCh. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - Prob. 59APCh. 13 - Prob. 60APCh. 13 - Prob. 61APCh. 13 - Prob. 62APCh. 13 - Prob. 63APCh. 13 - Prob. 64APCh. 13 - Prob. 65APCh. 13 - Prob. 66APCh. 13 - Prob. 67APCh. 13 - Although carbon dioxide is the actual greenhouse...Ch. 13 - Prob. 69APCh. 13 - Explain why a thermal inversion causes pollution...Ch. 13 - The specific heat of a substance is the amount of...Ch. 13 - Prob. 72APCh. 13 - Prob. 73APCh. 13 - Which of the following components is not recycled...Ch. 13 - Prob. 13.1CTECh. 13 - Prob. 13.2CTECh. 13 - Prob. 13.3CTECh. 13 - Prob. 13.4CTECh. 13 - Prob. 13.5CTECh. 13 - Prob. 13.6CTECh. 13 - Prob. 1CGPCh. 13 - Prob. 2CGPCh. 13 - Prob. 3CGPCh. 13 - Prob. 4CGPCh. 13 - Prob. 5CGPCh. 13 - Prob. 6CGPCh. 13 - Prob. 7CGPCh. 13 - Prob. 8CGPCh. 13 - Prob. 1CHQCh. 13 - Prob. 2CHQCh. 13 - Prob. 3CHQ
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- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- k₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forwardk₁ Given the reaction R₂ R + R, indicate k-1 (A). the rate law with respect to R2: (B). the rate law with respect to R: d[R₂] dt d[R] dtarrow_forwardGiven the reaction R+ Q → P, indicate (A). the rate law with respect to P: (B). the rate law with respect to R: (C). the rate law with respect to Q: d[P] dt d[R] dt d[Q] dtarrow_forward
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- a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?arrow_forwardWhen N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forward
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