
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 13, Problem 4KSP
Interpretation Introduction
Interpretation:
The category of the dissolution of ionic solutes is be chosen when this process causes decrease in the entropy and occurs spontaneously.
Concept introduction:
Entropy is defined as the degree of randomness in the system.
An endothermic process is defined as the process in which the energy of the system increases.
Endothermic process is the process that requires or absorbs heat from the surroundings.
In an endothermic process, potential energy of the system increases resulting in increase in entropy of the system.
An exothermic process is the process where the system releases energy.
In an exothermic process, potential energy of the system decreases resulting in decrease in entropy of the system.
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 13 Solutions
Chemistry
Ch. 13.1 - Prob. 1PPACh. 13.1 - Prob. 1PPBCh. 13.1 - Prob. 1PPCCh. 13.2 - Prob. 1CPCh. 13.2 - Prob. 2CPCh. 13.2 - Practice Problem ATTEMPT
Determine (a) the...Ch. 13.2 - Practice Problem BUILD
Determine the molality of...Ch. 13.2 - Prob. 1PPCCh. 13.3 - Practice Problem ATTEMPT
An aqueous solution that...Ch. 13.3 - Practice Problem BUILD
Determine the percent...
Ch. 13.3 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.3 - Prob. 1CPCh. 13.3 - What is the molality of a solution prepared by...Ch. 13.3 - Prob. 3CPCh. 13.3 - Prob. 4CPCh. 13.4 - Practice ProblemATTEMPT Calculate the...Ch. 13.4 - Prob. 1PPBCh. 13.4 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.4 - The solubility of N2 in water at 25°C and an N 2...Ch. 13.4 - Calculate the molar concentration of O 2 in water...Ch. 13.5 - Practice ProblemATTEMPT Calculate the vapor...Ch. 13.5 - Prob. 1PPBCh. 13.5 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 13.5 - 13.5.1 A solution contains 75.0 g of glucose...Ch. 13.5 - Determine the boiling point and the freezing point...Ch. 13.5 - 13.5.3 Calculate the osmotic pressure of a...Ch. 13.5 - 13.5.4 A 1.00-m solution of has a freezing point...Ch. 13.6 - Prob. 1PPACh. 13.6 - Prob. 1PPBCh. 13.6 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.6 - 13.6.1 A solution made by dissolving 14.2 g of...Ch. 13.6 - Prob. 2CPCh. 13.7 - Practice ProblemATTEMPT The freezing-point...Ch. 13.7 - Practice ProblemBUILD Using the experimental van't...Ch. 13.7 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 13.8 - Practice ProblemATTEMPT Determine the osmotic...Ch. 13.8 - Practice Problem BUILD
Determine the...Ch. 13.8 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.9 - Practice Problem ATTEMPT
Calculate the molar mass...Ch. 13.9 - Practice Problem BUILD
What mass of naphthalene...Ch. 13.9 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.10 - Practice Problem ATTEMPT A solution made by...Ch. 13.10 - Practice Problem BUILD What mass of insulin must...Ch. 13.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 13.11 - Practice Problem ATTEMPT An aqueous solution that...Ch. 13.11 - Practice Problem BUILD
An aqueous solution that is...Ch. 13.11 - Practice Problem CONCEPTUALIZE The diagrams...Ch. 13 - Which of the following processes is accompanied by...Ch. 13 - 13.2
For each of the processes depicted here,...Ch. 13 - 13.3
For each of the processes depicted here,...Ch. 13 - Prob. 4KSPCh. 13 - Describe and give examples of an unsaturated...Ch. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - As you know, some solution processes are...Ch. 13 - Prob. 7QPCh. 13 - 13.8 Describe the factors that affect the...Ch. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - 13.21 The alcohol content of hard liquor is...Ch. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - 13.24 The density of an aqueous solution...Ch. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - Prob. 27QPCh. 13 - What is thermal pollution? Why is it harmful to...Ch. 13 - Prob. 29QPCh. 13 - A student is observing two beakers of water. One...Ch. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - The solubility of KNO 3 is 155 g per 100 g of...Ch. 13 - Prob. 34QPCh. 13 - 13.35 The solubility of in water at What is its...Ch. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Prob. 39QPCh. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - 13.46 Write the equations relating boiling-point...Ch. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - What are ion pairs? What effect does ion-pair...Ch. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - 13.57 A solution is prepared by dissolving 396 g...Ch. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - 13.64 How many liters of the antifreeze ethylene...Ch. 13 - Prob. 65QPCh. 13 - Prob. 66QPCh. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - 13.69 Both and are used to melt ice on roads and...Ch. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Calculate the difference in osmotic pressure (in...Ch. 13 - 13.75 Which of the following aqueous solutions has...Ch. 13 - Prob. 76QPCh. 13 - 13.77 Arrange the following solutions in order of...Ch. 13 - Prob. 78QPCh. 13 - Indicate which compound in each of the following...Ch. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - The elemental analysis of an organic solid...Ch. 13 - 13.85 A solution of 2.50 g of a compound having...Ch. 13 - 13.86 The molar mass of benzoic acid determined...Ch. 13 - 13.87 A solution containing 0.8330 g of a polymer...Ch. 13 - Prob. 88QPCh. 13 - A solution of 6.85 g of a carbohydrate in 100.0 g...Ch. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95APCh. 13 - Prob. 96APCh. 13 - 13.97 Acetic acid is a polar molecule and can form...Ch. 13 - Prob. 98APCh. 13 - Prob. 99APCh. 13 - Prob. 100APCh. 13 - Prob. 101APCh. 13 - Prob. 102APCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - A solution of 1.00 g of anhydrous aluminum...Ch. 13 - Explain why reverse osmosis is (theoretically)...Ch. 13 - A 1.32-g sample of a mixture of cyclohexane ( C 6...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Iodine ( I 2 ) is only sparingly soluble in water...Ch. 13 - Concentrated hydrochloric acid is usually...Ch. 13 - Explain each of the following statements: (a) The...Ch. 13 - A mixture of NaCl and sucrose ( C 12 H 22 O 12 )...Ch. 13 - Prob. 120APCh. 13 - At 27°C, the vapor pressure of pure water is 23.76...Ch. 13 - A nonvolatile organic compound Z was used to make...Ch. 13 - Prob. 123APCh. 13 - Prob. 124APCh. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - Prob. 127APCh. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Consider the three mercury manometers shown in the...Ch. 13 - Prob. 133APCh. 13 - Prob. 134APCh. 13 - Prob. 135APCh. 13 - 13.136 In the apparatus shown, what will happen if...Ch. 13 - Prob. 137APCh. 13 - Prob. 138APCh. 13 - Lysozyme is an enzyme that cleaves bacterial cell...Ch. 13 - Prob. 140APCh. 13 - Prob. 141APCh. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - What masses of sodium chloride, magnesium...Ch. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - Hemoglobin, the oxygen-transport protein, binds...Ch. 13 - Prob. 151APCh. 13 - 13.152 The vapor pressure of ethanol and the...Ch. 13 - Prob. 153APCh. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - Prob. 3SEPPCh. 13 - Prob. 4SEPP
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