Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 13, Problem 41QP
Interpretation Introduction
Interpretation: The dissolution process which is endothermic and exothermic is to be identified. The numerical value of
Concept introduction:
If heat is supplied for a reaction to occur then it is called endothermic reaction.
If heat is produced during a reaction then it is called exothermic reaction.
Gaseous solutes are less soluble in water with the increase in temperature.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
A
J
то
گای ه
+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants
or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure
and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in
the reactant before being able to draw the arrows corresponding to product formation.
A.
B.
Rearrangement
ΘΗ
Chapter 13 Solutions
Chemistry
Ch. 13.1 - Prob. 1PPACh. 13.1 - Prob. 1PPBCh. 13.1 - Prob. 1PPCCh. 13.2 - Prob. 1CPCh. 13.2 - Prob. 2CPCh. 13.2 - Practice Problem ATTEMPT
Determine (a) the...Ch. 13.2 - Practice Problem BUILD
Determine the molality of...Ch. 13.2 - Prob. 1PPCCh. 13.3 - Practice Problem ATTEMPT
An aqueous solution that...Ch. 13.3 - Practice Problem BUILD
Determine the percent...
Ch. 13.3 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.3 - Prob. 1CPCh. 13.3 - What is the molality of a solution prepared by...Ch. 13.3 - Prob. 3CPCh. 13.3 - Prob. 4CPCh. 13.4 - Practice ProblemATTEMPT Calculate the...Ch. 13.4 - Prob. 1PPBCh. 13.4 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.4 - The solubility of N2 in water at 25°C and an N 2...Ch. 13.4 - Calculate the molar concentration of O 2 in water...Ch. 13.5 - Practice ProblemATTEMPT Calculate the vapor...Ch. 13.5 - Prob. 1PPBCh. 13.5 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 13.5 - 13.5.1 A solution contains 75.0 g of glucose...Ch. 13.5 - Determine the boiling point and the freezing point...Ch. 13.5 - 13.5.3 Calculate the osmotic pressure of a...Ch. 13.5 - 13.5.4 A 1.00-m solution of has a freezing point...Ch. 13.6 - Prob. 1PPACh. 13.6 - Prob. 1PPBCh. 13.6 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.6 - 13.6.1 A solution made by dissolving 14.2 g of...Ch. 13.6 - Prob. 2CPCh. 13.7 - Practice ProblemATTEMPT The freezing-point...Ch. 13.7 - Practice ProblemBUILD Using the experimental van't...Ch. 13.7 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 13.8 - Practice ProblemATTEMPT Determine the osmotic...Ch. 13.8 - Practice Problem BUILD
Determine the...Ch. 13.8 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.9 - Practice Problem ATTEMPT
Calculate the molar mass...Ch. 13.9 - Practice Problem BUILD
What mass of naphthalene...Ch. 13.9 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.10 - Practice Problem ATTEMPT A solution made by...Ch. 13.10 - Practice Problem BUILD What mass of insulin must...Ch. 13.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 13.11 - Practice Problem ATTEMPT An aqueous solution that...Ch. 13.11 - Practice Problem BUILD
An aqueous solution that is...Ch. 13.11 - Practice Problem CONCEPTUALIZE The diagrams...Ch. 13 - Which of the following processes is accompanied by...Ch. 13 - 13.2
For each of the processes depicted here,...Ch. 13 - 13.3
For each of the processes depicted here,...Ch. 13 - Prob. 4KSPCh. 13 - Describe and give examples of an unsaturated...Ch. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - As you know, some solution processes are...Ch. 13 - Prob. 7QPCh. 13 - 13.8 Describe the factors that affect the...Ch. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - 13.21 The alcohol content of hard liquor is...Ch. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - 13.24 The density of an aqueous solution...Ch. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - Prob. 27QPCh. 13 - What is thermal pollution? Why is it harmful to...Ch. 13 - Prob. 29QPCh. 13 - A student is observing two beakers of water. One...Ch. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - The solubility of KNO 3 is 155 g per 100 g of...Ch. 13 - Prob. 34QPCh. 13 - 13.35 The solubility of in water at What is its...Ch. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Prob. 39QPCh. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - 13.46 Write the equations relating boiling-point...Ch. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - What are ion pairs? What effect does ion-pair...Ch. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - 13.57 A solution is prepared by dissolving 396 g...Ch. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - 13.64 How many liters of the antifreeze ethylene...Ch. 13 - Prob. 65QPCh. 13 - Prob. 66QPCh. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - 13.69 Both and are used to melt ice on roads and...Ch. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Calculate the difference in osmotic pressure (in...Ch. 13 - 13.75 Which of the following aqueous solutions has...Ch. 13 - Prob. 76QPCh. 13 - 13.77 Arrange the following solutions in order of...Ch. 13 - Prob. 78QPCh. 13 - Indicate which compound in each of the following...Ch. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - The elemental analysis of an organic solid...Ch. 13 - 13.85 A solution of 2.50 g of a compound having...Ch. 13 - 13.86 The molar mass of benzoic acid determined...Ch. 13 - 13.87 A solution containing 0.8330 g of a polymer...Ch. 13 - Prob. 88QPCh. 13 - A solution of 6.85 g of a carbohydrate in 100.0 g...Ch. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95APCh. 13 - Prob. 96APCh. 13 - 13.97 Acetic acid is a polar molecule and can form...Ch. 13 - Prob. 98APCh. 13 - Prob. 99APCh. 13 - Prob. 100APCh. 13 - Prob. 101APCh. 13 - Prob. 102APCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - A solution of 1.00 g of anhydrous aluminum...Ch. 13 - Explain why reverse osmosis is (theoretically)...Ch. 13 - A 1.32-g sample of a mixture of cyclohexane ( C 6...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Iodine ( I 2 ) is only sparingly soluble in water...Ch. 13 - Concentrated hydrochloric acid is usually...Ch. 13 - Explain each of the following statements: (a) The...Ch. 13 - A mixture of NaCl and sucrose ( C 12 H 22 O 12 )...Ch. 13 - Prob. 120APCh. 13 - At 27°C, the vapor pressure of pure water is 23.76...Ch. 13 - A nonvolatile organic compound Z was used to make...Ch. 13 - Prob. 123APCh. 13 - Prob. 124APCh. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - Prob. 127APCh. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Consider the three mercury manometers shown in the...Ch. 13 - Prob. 133APCh. 13 - Prob. 134APCh. 13 - Prob. 135APCh. 13 - 13.136 In the apparatus shown, what will happen if...Ch. 13 - Prob. 137APCh. 13 - Prob. 138APCh. 13 - Lysozyme is an enzyme that cleaves bacterial cell...Ch. 13 - Prob. 140APCh. 13 - Prob. 141APCh. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - What masses of sodium chloride, magnesium...Ch. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - Hemoglobin, the oxygen-transport protein, binds...Ch. 13 - Prob. 151APCh. 13 - 13.152 The vapor pressure of ethanol and the...Ch. 13 - Prob. 153APCh. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - Prob. 3SEPPCh. 13 - Prob. 4SEPP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forwardArrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidityarrow_forward
- 1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)arrow_forwardAnswers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forward
- The rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward8. Draw all the resonance forms for each of the following molecules or ions, and indicate the major contributor in each case, or if they are equivalent. (4.5 pts) (a) PH2 سمةarrow_forward3. Assign absolute configuration (Rors) to each chirality center. a. H Nitz C. он b. 0 H-C. C H 7 C. ་-4 917-417 refs H 1つ ८ ડુ d. Но f. -2- 01 Ho -OH 2HNarrow_forward
- How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom moleculearrow_forwardIn the drawing area below, draw the major products of this organic reaction: 1. NaOH ? 2. CH3Br If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. No reaction. Click and drag to start drawing a structure. ☐ : A คarrow_forwardPredict the major products of the following organic reaction: NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to draw bonds carefully to show important geometric relationships between substituents. Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the ring structure. You can add any substituents using the pencil tool in the usual way. Click and drag to start drawing a structure. Х аarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY