EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
3rd Edition
ISBN: 9780133858501
Author: Bruice
Publisher: PEARSON CO
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Question
Chapter 13, Problem 42P
Interpretation Introduction
Interpretation:
Product formed when a 1,6-diester instead of a 1,7-diester is used has to be given.
Concept Introduction:
Claisen Condensation is the reaction of an ester having an
Mechanism for Claisen Condensation:
- A base abstracts a proton from the
- The enolate ion gets attached to the carbonyl carbon of another ester.
- The negative charge on oxygen of the carbonyl group reforms, by removing an alkoxide ion.
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Check the box under each structure in the table that is an enantiomer of the molecule shown below. If none of them are, check the none of the above box under
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Molecule 3
----|||
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Molecule 6
none of the above
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Use the vapor-liquid equilibrium data at 1.0 atm. for methanol-water (Table 2-8 ) for the following:
If the methanol vapor mole fraction is 0.600, what is the methanol liquid mole fraction?
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If water liquid mole fraction is 0.350, what is the water vapor mole fraction?
What are the K values of methanol and of water at a methanol mole fraction in the liquid of 0.200?
What is the relative volatility αM-W at a methanol mole fraction in the liquid of 0.200?
Chapter 13 Solutions
EP ESSENTIAL ORG.CHEM.-MOD.MASTERING
Ch. 13.1 - Identify the most acidic hydrogen in each...Ch. 13.1 - Prob. 2PCh. 13.1 - Prob. 3PCh. 13.1 - Prob. 4PCh. 13.1 - Explain why HO cannot remove a proton from the...Ch. 13.2 - Prob. 6PCh. 13.2 - Prob. 7PCh. 13.3 - Prob. 8PCh. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.4 - Prob. 11PCh. 13.5 - Prob. 12PCh. 13.5 - Prob. 13PCh. 13.6 - Prob. 14PCh. 13.7 - Prob. 16PCh. 13.8 - Prob. 17PCh. 13.8 - Prob. 18PCh. 13.8 - Prob. 19PCh. 13.9 - Prob. 20PCh. 13.10 - Propose a mechanism for the formation of...Ch. 13.10 - Prob. 22PCh. 13.10 - a. If the biosynthesis of palmitic acid were...Ch. 13 - Draw the enol tautomers for each of the following...Ch. 13 - Number the following compounds in order from...Ch. 13 - Prob. 26PCh. 13 - Explain why the pKa of a hydrogen bonded to the...Ch. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Using cyclopentanone as the reactant, show the...Ch. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Prob. 44PCh. 13 - Describe how the following compounds can be...Ch. 13 - Prob. 46PCh. 13 - Which would require a higher temperature:...Ch. 13 - Prob. 48PCh. 13 - Propose a mechanism for the following reaction:Ch. 13 - Show how the following compounds could be...Ch. 13 - Prob. 51PCh. 13 - Prob. 52P
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