FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
15th Edition
ISBN: 9781119797807
Author: Hein
Publisher: WILEY
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Question
Chapter 13, Problem 41RQ
Interpretation Introduction
Interpretation:
Reason for ice to float on water has to be explained. Whether ice floats on ethyl alcohol or not has to be determined.
Concept Introduction:
Density is generally defined as the ratio of mass of substance per unit volume. It tells about the space occupied by the substance.
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 13 Solutions
FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
Ch. 13.2 - Prob. 13.1PCh. 13.2 - Prob. 13.2PCh. 13.3 - Prob. 13.3PCh. 13.3 - Prob. 13.4PCh. 13.4 - Prob. 13.5PCh. 13.5 - Prob. 13.6PCh. 13.5 - Prob. 13.7PCh. 13.5 - Prob. 13.8PCh. 13.6 - Prob. 13.9PCh. 13.6 - Prob. 13.10P
Ch. 13 - Prob. 1RQCh. 13 - Prob. 2RQCh. 13 - Prob. 3RQCh. 13 - Prob. 4RQCh. 13 - Prob. 5RQCh. 13 - Prob. 6RQCh. 13 - Prob. 7RQCh. 13 - Prob. 8RQCh. 13 - Prob. 9RQCh. 13 - Prob. 10RQCh. 13 - Prob. 11RQCh. 13 - Prob. 12RQCh. 13 - Prob. 13RQCh. 13 - Prob. 14RQCh. 13 - Prob. 15RQCh. 13 - Prob. 16RQCh. 13 - Prob. 17RQCh. 13 - Prob. 19RQCh. 13 - Prob. 20RQCh. 13 - Prob. 21RQCh. 13 - Prob. 22RQCh. 13 - Prob. 23RQCh. 13 - Prob. 24RQCh. 13 - Prob. 25RQCh. 13 - Prob. 26RQCh. 13 - Prob. 27RQCh. 13 - Prob. 28RQCh. 13 - Prob. 29RQCh. 13 - Prob. 30RQCh. 13 - Prob. 31RQCh. 13 - Prob. 32RQCh. 13 - Prob. 33RQCh. 13 - Prob. 34RQCh. 13 - Prob. 35RQCh. 13 - Prob. 36RQCh. 13 - Prob. 37RQCh. 13 - Prob. 38RQCh. 13 - Prob. 39RQCh. 13 - Prob. 40RQCh. 13 - Prob. 41RQCh. 13 - Prob. 42RQCh. 13 - Prob. 43RQCh. 13 - Prob. 1PECh. 13 - Prob. 2PECh. 13 - Prob. 3PECh. 13 - Prob. 4PECh. 13 - Prob. 5PECh. 13 - Prob. 6PECh. 13 - Prob. 7PECh. 13 - Prob. 8PECh. 13 - Prob. 9PECh. 13 - Prob. 10PECh. 13 - Prob. 11PECh. 13 - Prob. 12PECh. 13 - Prob. 13PECh. 13 - Prob. 14PECh. 13 - Prob. 15PECh. 13 - Prob. 16PECh. 13 - Prob. 17PECh. 13 - Prob. 18PECh. 13 - Prob. 19PECh. 13 - Prob. 20PECh. 13 - Prob. 21PECh. 13 - Prob. 22PECh. 13 - Prob. 23PECh. 13 - Prob. 24PECh. 13 - Prob. 25PECh. 13 - Prob. 26PECh. 13 - Prob. 27PECh. 13 - Prob. 28PECh. 13 - Prob. 29PECh. 13 - Prob. 30PECh. 13 - Prob. 31PECh. 13 - Prob. 32PECh. 13 - Prob. 33AECh. 13 - Prob. 34AECh. 13 - Prob. 35AECh. 13 - Prob. 36AECh. 13 - Prob. 38AECh. 13 - Prob. 39AECh. 13 - Prob. 40AECh. 13 - Prob. 41AECh. 13 - Prob. 42AECh. 13 - Prob. 43AECh. 13 - Prob. 44AECh. 13 - Prob. 45AECh. 13 - Prob. 46AECh. 13 - Prob. 47AECh. 13 - Prob. 48AECh. 13 - Prob. 49AECh. 13 - Prob. 50AECh. 13 - Prob. 51AECh. 13 - Prob. 52AECh. 13 - Prob. 53AECh. 13 - Prob. 54AECh. 13 - Prob. 55AECh. 13 - Prob. 56AECh. 13 - Prob. 57AECh. 13 - Prob. 58AECh. 13 - Prob. 59AECh. 13 - Prob. 60AECh. 13 - Prob. 61AECh. 13 - Prob. 62AECh. 13 - Prob. 63AECh. 13 - Prob. 64AECh. 13 - Prob. 65AECh. 13 - Prob. 66AECh. 13 - Prob. 67AECh. 13 - Prob. 69CECh. 13 - Prob. 70CECh. 13 - Prob. 71CECh. 13 - Prob. 72CE
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