EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781119227946
Author: Willard
Publisher: VST
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Chapter 13, Problem 34AE
Interpretation Introduction
Interpretation:
Whether liquid water at
Concept Introduction:
Heat of vaporization is the quantity of heat absorbed on vaporization of a liquid. Every substance has different heat of vaporization. It is represented as
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Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
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H2O
H2O
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Select to Add Arrows
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Draw an alkyl halide that produces ONLY the following alkene in an E2
elimination. Ignore any inorganic byproducts.
Drawing
Strong Base
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Atoms, Bonds
and Rings
Charges
HO
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H2N
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Reset
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For the dehydrohalogenation (E2) reaction shown, draw the major organic product.
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tert-butanol
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Chapter 13 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 13.2 - Prob. 13.1PCh. 13.2 - Prob. 13.2PCh. 13.3 - Prob. 13.3PCh. 13.3 - Prob. 13.4PCh. 13.4 - Prob. 13.5PCh. 13.5 - Prob. 13.6PCh. 13.5 - Prob. 13.7PCh. 13.5 - Prob. 13.8PCh. 13.6 - Prob. 13.9PCh. 13.6 - Prob. 13.10P
Ch. 13 - Prob. 1RQCh. 13 - Prob. 2RQCh. 13 - Prob. 3RQCh. 13 - Prob. 4RQCh. 13 - Prob. 5RQCh. 13 - Prob. 6RQCh. 13 - Prob. 7RQCh. 13 - Prob. 8RQCh. 13 - Prob. 9RQCh. 13 - Prob. 10RQCh. 13 - Prob. 11RQCh. 13 - Prob. 12RQCh. 13 - Prob. 13RQCh. 13 - Prob. 14RQCh. 13 - Prob. 15RQCh. 13 - Prob. 16RQCh. 13 - Prob. 17RQCh. 13 - Prob. 19RQCh. 13 - Prob. 20RQCh. 13 - Prob. 21RQCh. 13 - Prob. 22RQCh. 13 - Prob. 23RQCh. 13 - Prob. 24RQCh. 13 - Prob. 25RQCh. 13 - Prob. 26RQCh. 13 - Prob. 27RQCh. 13 - Prob. 28RQCh. 13 - Prob. 29RQCh. 13 - Prob. 30RQCh. 13 - Prob. 31RQCh. 13 - Prob. 32RQCh. 13 - Prob. 33RQCh. 13 - Prob. 34RQCh. 13 - Prob. 35RQCh. 13 - Prob. 36RQCh. 13 - Prob. 37RQCh. 13 - Prob. 38RQCh. 13 - Prob. 39RQCh. 13 - Prob. 40RQCh. 13 - Prob. 41RQCh. 13 - Prob. 42RQCh. 13 - Prob. 43RQCh. 13 - Prob. 1PECh. 13 - Prob. 2PECh. 13 - Prob. 3PECh. 13 - Prob. 4PECh. 13 - Prob. 5PECh. 13 - Prob. 6PECh. 13 - Prob. 7PECh. 13 - Prob. 8PECh. 13 - Prob. 9PECh. 13 - Prob. 10PECh. 13 - Prob. 11PECh. 13 - Prob. 12PECh. 13 - Prob. 13PECh. 13 - Prob. 14PECh. 13 - Prob. 15PECh. 13 - Prob. 16PECh. 13 - Prob. 17PECh. 13 - Prob. 18PECh. 13 - Prob. 19PECh. 13 - Prob. 20PECh. 13 - Prob. 21PECh. 13 - Prob. 22PECh. 13 - Prob. 23PECh. 13 - Prob. 24PECh. 13 - Prob. 25PECh. 13 - Prob. 26PECh. 13 - Prob. 27PECh. 13 - Prob. 28PECh. 13 - Prob. 29PECh. 13 - Prob. 30PECh. 13 - Prob. 31PECh. 13 - Prob. 32PECh. 13 - Prob. 33AECh. 13 - Prob. 34AECh. 13 - Prob. 35AECh. 13 - Prob. 36AECh. 13 - Prob. 38AECh. 13 - Prob. 39AECh. 13 - Prob. 40AECh. 13 - Prob. 41AECh. 13 - Prob. 42AECh. 13 - Prob. 43AECh. 13 - Prob. 44AECh. 13 - Prob. 45AECh. 13 - Prob. 46AECh. 13 - Prob. 47AECh. 13 - Prob. 48AECh. 13 - Prob. 49AECh. 13 - Prob. 50AECh. 13 - Prob. 51AECh. 13 - Prob. 52AECh. 13 - Prob. 53AECh. 13 - Prob. 54AECh. 13 - Prob. 55AECh. 13 - Prob. 56AECh. 13 - Prob. 57AECh. 13 - Prob. 58AECh. 13 - Prob. 59AECh. 13 - Prob. 60AECh. 13 - Prob. 61AECh. 13 - Prob. 62AECh. 13 - Prob. 63AECh. 13 - Prob. 64AECh. 13 - Prob. 65AECh. 13 - Prob. 66AECh. 13 - Prob. 67AECh. 13 - Prob. 69CECh. 13 - Prob. 70CECh. 13 - Prob. 71CECh. 13 - Prob. 72CE
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- Macmillan Learning Draw the major, neutral organic product for each substitution reaction. For this question, assume that each substitution reaction goes to completion. Disregard elimination. Reaction A. CI H₂O Select Draw Templates More Erase C Harrow_forwardMacmillan Learning Reaction B: CI HO_ 곳으 / Select Draw Templates More с € H D Erasearrow_forwardWhen 2-bromo-93-dimethylbutane is heated with sodium methoxide, one majors.. në la formed. 4th attempt Part 1 (0.5 point) t Ji See Periodic Table See Hint Draw the major alkene product and all other byproducts. Be sure to include lone-pair electrons and charges. Part 2 (0.5 point) What type of mechanism is occuring? Choose one: AS1 3rd attempt X H 41 See Hint Part 1 (0.5 point) Feedback See Periodic Table See Hintarrow_forward
- Complete the mechanism for the E1 reaction below by following the directions written above each of the five boxes. Be sure to include lone pair electrons and nonzero formal charges. 2nd attempt 1 Provide the missing curved arrow notation. E+ RUDDA 1st attempt Feedback See Periodic Table See Hint Iir See Periodic Table See Hintarrow_forwardHeating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of Sy1. 3rd attempt h Draw curved arrow(s) to show how the alcohol reacts with phosphoric acid. TH © 1 0 0 +1% # 2nd attempt Feedback H Ju See Periodic Table See Hint H Jud See Periodic Table See Hintarrow_forwardPart 2 (0.5 point) 0- Draw the major organic product with the correct geometry. 10 1: 70000 х く 1st attempt Part 1 (0.5 point) Feedback Please draw all four bonds at chiral centers. P See Periodic Table See Hintarrow_forward
- Heating an alcohol in the presence of sulfuric or phosphoric acid will cause a dehydration to occur: the removal of the elements of water from a molecule, forming an alkene. The reaction usually follows an E1 mechanism. The SN1 pathway is suppressed by using a strong acid whose conjugate base is a poor nucleophile. Further, heating the reaction mixture causes a greater increase in the rate of E1 compared to the rate of S№1. 2nd attempt 0 See Periodic Table See Hint Draw the organic intermediate from the first step (no byproducts) and draw curved arrow(s) to show how it reacts. TH +11: 1st attempt Feedback H H H C F F See Periodic Table See Hintarrow_forwardThis molecule undergoes an E1 mechanism when stirred in methanol. 3rd attempt CH₂OH CH₂OH 6148 O See Periodic Table. See Hint Draw 3 chemical species including formal charges and lone pairs of electrons. Add the missing curved arrow notation. H N O O SA 3 Br Iarrow_forwardComplete the mechanism for the E1 reaction below by following the directions written above each of the five boxes. Be sure to include lone pair electrons and nonzero formal charges. 1st attempt Y 0 + Provide the missing curved arrow notation. 01: See Periodic Table See Hint H C Br Iarrow_forward
- Please help answer number 2. Thanks in advance.arrow_forwardHow do I explain this? Thank you!arrow_forwardWhen an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 40 0 DEPT 135 T 200 160 120 80 40 0 Draw the unknown amide. Select Dow Templates More Fragearrow_forward
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