
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 13, Problem 13.85E
In propene (
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Using the Nernst equation to calculate nonstandard cell voltage
A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction:
MnO2 (s)+4H* (aq)+2Cr²+ (aq) → Mn²+ (aq)+2H₂O (1)+2Cr³+ (aq)
+
2+
2+
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Suppose the cell is prepared with 7.44 M H* and 0.485 M Cr²+ in one half-cell and 7.92 M Mn² and 3.73 M Cr³+ in the other.
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☐
x10
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?
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Calculating standard reaction free energy from standard reduction...
Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG° for the following redox reaction.
Be sure your answer has the correct number of significant digits.
NO (g) +H₂O (1) + Cu²+ (aq) → HNO₂ (aq) +H* (aq)+Cu* (aq)
kJ
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Calculating the pH of a weak base titrated with a strong acid
b
An analytical chemist is titrating 116.9 mL of a 0.7700M solution of aniline (C6H5NH2) with a 0.5300M solution of HNO3. The pK of aniline is 9.37.
Calculate the pH of the base solution after the chemist has added 184.2 mL of the HNO 3 solution to it.
Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HNO3 solution added.
Round your answer to 2 decimal places.
pH = ☐
☑
5
Chapter 13 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 13 - In your own words, explain why an object that has...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Identify the symmetry elements present in the...Ch. 13 - Prob. 13.4ECh. 13 - Prob. 13.5ECh. 13 - Prob. 13.6ECh. 13 - Prob. 13.7ECh. 13 - Prob. 13.8ECh. 13 - Any axis of symmetry Cn that rotates an object by...Ch. 13 - Prob. 13.10E
Ch. 13 - Prob. 13.11ECh. 13 - Prob. 13.12ECh. 13 - Prob. 13.13ECh. 13 - What are the number of classes and the order of...Ch. 13 - Prob. 13.15ECh. 13 - a Show that the C3v point group satisfies the...Ch. 13 - a In the Td point group, an S41 improper rotation...Ch. 13 - Determine which single symmetry operation of the...Ch. 13 - Prob. 13.19ECh. 13 - Prob. 13.20ECh. 13 - Prob. 13.21ECh. 13 - Figure 13.27 shows the structure of the molecule...Ch. 13 - Prob. 13.23ECh. 13 - Identify all the symmetry elements present in the...Ch. 13 - Point groups are called such because all of the...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point group of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Determine the point groups of the following...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Structural isomers can have very different point...Ch. 13 - Prob. 13.32ECh. 13 - Identify the point group of the wave functions of...Ch. 13 - Identify the point group of the wave functions of...Ch. 13 - Prob. 13.35ECh. 13 - Determine if the following species have permanent...Ch. 13 - Determine if the following species have permanent...Ch. 13 - Which of the following species will not have...Ch. 13 - Prob. 13.39ECh. 13 - Explain why a molecule with a center of inversion...Ch. 13 - a Unlike methane, bromochlorofluoromethane...Ch. 13 - Prob. 13.42ECh. 13 - Prob. 13.43ECh. 13 - Prob. 13.44ECh. 13 - Show that the irreducible representations of the...Ch. 13 - Show that any two of the irreducible...Ch. 13 - Show that any irreducible representation of these...Ch. 13 - Explain why this proposed irreducible...Ch. 13 - Prob. 13.49ECh. 13 - Prob. 13.50ECh. 13 - Why is it unnecessary to consider whether an...Ch. 13 - Prob. 13.52ECh. 13 - Prob. 13.53ECh. 13 - Prob. 13.54ECh. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Prob. 13.58ECh. 13 - Reduce the following reducible representations...Ch. 13 - Determine the resulting representations for the...Ch. 13 - Prob. 13.61ECh. 13 - Without using the great orthogonality theorem,...Ch. 13 - Assume that you are evaluating the integral of...Ch. 13 - Prob. 13.64ECh. 13 - Assume that x- polarized light can be assigned an...Ch. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Prob. 13.68ECh. 13 - Prob. 13.69ECh. 13 - Prob. 13.70ECh. 13 - Construct the symmetry-adapted linear combination...Ch. 13 - Prob. 13.72ECh. 13 - Prob. 13.73ECh. 13 - Prob. 13.74ECh. 13 - Prob. 13.75ECh. 13 - Prob. 13.76ECh. 13 - Prob. 13.77ECh. 13 - Suppose you use p0,p1 and p+1 along with s...Ch. 13 - Show that the individual sp orbitals, as written...Ch. 13 - Prob. 13.80ECh. 13 - What is the rough hybridization of the carbon...Ch. 13 - Determine the symmetry species of the D3h point...Ch. 13 - Determine the D3h symmetry species of the sp3d...Ch. 13 - Prob. 13.84ECh. 13 - In propene CH3CH=CH2, the first carbon has sp3...Ch. 13 - Prob. 13.87ECh. 13 - Prob. 13.88ECh. 13 - Prob. 13.89E
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