(a) Interpretation: The absorbance of the solution containing the complex formed between Bi ( III ) and thiourea having a concentration of 4.25 × 10 − 5 M and the molar absorptivity of 9.23 × 10 3 L / mol ⋅ cm is to be calculated. Concept introduction: The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution. The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as. A = ε b c

Question

Draw the Michael Adduct and the final product of the Robinson annulation reaction. Ignore inorganic byproducts.

Answer 1

Question

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

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Draw the Michael Adduct and the final product of the Robinson annulation reaction. Ignore inorganic byproducts.

Draw the Michael adduct and final product of the Robinson annulation reaction. Ignore inorganic byproducts

Post Lab Questions. 1) Draw the mechanism of your Diels-Alder cycloaddition. 2) Only one isomer of product is formed in the Diels-Alder cycloaddition. Why? 3) Imagine that you used isoprene as diene - in that case you don't have to worry about assigning endo vs exo. Draw the "endo" and "exo" products of the Diels-Alder reaction between isoprene and maleic anhydride, and explain why the distinction is irrelevant here. 4) This does not hold for other dienes. Draw the exo and endo products of the reaction of cyclohexadiene with maleic anhydride. Make sure you label your answers properly as endo or exo. 100 °C Xylenes ??? 5) Calculate the process mass intensity for your specific reaction (make sure to use your actual amounts of reagent).

Answer 2

Question

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

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Answer 3

Question

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

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Answer 4

Question

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

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Answer 5

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Answer 6

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Answer 7

Chapter 13, Problem 13.7QAP

Interpretation Introduction

(a)

Interpretation:

The absorbance of the solution containing the complex formed between Bi(III) and thiourea having a concentration of 4.25×10−5 M and the molar absorptivity of 9.23×103 L/mol⋅cm is to be calculated.

Concept introduction:

The absorbance of the solution is the ability of the solution to absorb the monochromatic light passing through it. The absorbance of the solution is defined as the ratio of the intensity of light incident on the solution to the intensity of light absorbed by the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Answer 8

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Answer 9

Interpretation Introduction

(b)

Interpretation:

The percent transmittance of the solution formed from the complex between Bi(III) and thiourea is to be calculated.

Concept introduction:

The percent transmittance of a solution is the ability of the solution to allow the monochromatic light to pass through it. The percent transmittance of a solution is the ratio of the intensity of monochromatic light incident on the solution to the intensity transmitted through the solution.

The relation between the absorbance and transmittance is established by the Beer’s law.

A=−logT

Answer 10

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Answer 11

Interpretation Introduction

(c)

Interpretation:

The concentration of the solution is to be determined for the change in the path length of the cell containing the solution.

Concept introduction:

The concentration of the solution, path length of the cell and the molar absorptivity of the solution plays an important role in determining the absorbance of the solution. If any of the parameter is affected, it leads to change in the absorbance of the solution.

The relation between the absorbance, path length, molar absorptivity and the concentration of the solution is given as.

A=εbc

Answer 12

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Ch. 13 - Prob. 13.1QAP Ch. 13 - Prob. 13.2QAP Ch. 13 - Prob. 13.3QAP Ch. 13 - Prob. 13.4QAP Ch. 13 - Prob. 13.5QAP Ch. 13 - Prob. 13.6QAP Ch. 13 - Prob. 13.7QAP Ch. 13 - At 580 nm, which is the wavelength of its maximum...Ch. 13 - Prob. 13.9QAP Ch. 13 - Zinc(II) and the ligand L form a 1:1 complex that...

Chapter 13 Solutions