Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Question
Chapter 13, Problem 13.57E
Interpretation Introduction
Interpretation:
The reason corresponding to the fact that dehydration reaction is favored at
Concept introduction:
The principle of LeChatelier’s states that if the system in equilibrium is restricted with the limitations like change of temperature, pressure or concentration then the equilibrium of the system shifts or disturbs to compensate the applied changes.
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Identify the alcohol reactant needed to produce each of the following compounds as the major
product of an alcohol dehydration reaction.
H,SO,
Alcohol
→ CH3–CH=CH–CH3
180°C
a.
H,SO,
Alcohol
→ CH,=CH-CH–CH3
180°C
CH3
b.
H,SO,
Alcohol
CH3-CH-CH2–0–CH,-CH–CH3
140°C
ČH3
с.
H,SO,
Alcohol
CH,=CH-CH,–CH3
180°C
H,SO,
Alcohol
CH;-C=C-CH3
180°C
CH3 CH3
e.
1. Write the skeletal structures of propanal, acetone and cyclohexanone. What is the major intermolecular force (IMF) found in them? Based on their major intermolecular force and molecular weight, what can you predict on their solubility in water?
Chemical Name
Skeletal Structures
Major IMF
Solubility in water
Propanal
Acetone
Cyclohexanone
2. What is the purpose of Tollens’ test (Part B)? What is the evidence of a positive result?
3. What is the purpose of oxidation test (Part C)? What is the evidence of a positive result?
Based on Zaitsev's rule, write both products for the dehydration reaction of alcohols and label the major product
Chapter 13 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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- Using the relationship between the structure and the boiling point. Obtain a table for the listed chemicals below showing how the boiling point will be different with (1) the different chemical structures, (2) with different functional groups. Boiling Point and Functionalized Compounds: Chemical: Cyclohexanol Cyclohexanone Cyclohexene Benzaldehyde Benzyl alcoholarrow_forward10 Regarding t-butanol and n-butanol, which is/ are correct statements of the following: |- Both are having equal solubility in water Il- t-butanol is more soluble in water than n- butanol III- Boiling point of t-butanol is lower than n-butanol IV- Boiling point of n-butanol is lower than t-butanol * Only I Only II Only II Il & II III & IVarrow_forwardWrite the skeletal structures of propanal, acetone and cyclohexanone. What is the major intermolecular force (IMF) found in them? Based on their major intermolecular force and molecular weight, what can you predict on their solubility in water? Chemical Name Skeletal Structures Major IMF Solubility in water Propanal Acetone Cyclohexanonearrow_forward
- Which among the representative compounds is/are soluble in NaOH? Write the acid-base reactions involved. 1-butanol 2-butanol tert-butyl-alcohol phenol diisopropyl etherarrow_forwardName 5 types of reactions for alcohols (organic chemistry)arrow_forwardTrue or False:1. When isopropyl alcohol reacts with HCl, the resulting product is 2-chloropropane2. Nucleophilic molecules are electron-rich molecules that can "attack" electron deficient molecules3. Based on the physical property, hydroquinone has a lower boiling point compared to catecholarrow_forward
- Why conversion of ethanol into ethanoic acid is an oxidation reaction?arrow_forwardCan you please give an explanation for question 5 (A, B, and C)? 5 continues on the 2nd page. Thank youarrow_forwardWhat is the importance of making sure that the correct process is done in the process of fermentation in making alcohols?arrow_forward
- Which of these most likely has the highest boiling point? O2-pentanol O diethyl ether O butanoic acid O 1-pentanol O 2-pentanone pentanalarrow_forward7. Draw a circle around the compound in each horizontal row with the greatest water solubility and draw a rectangle around the compound with the lowest solubility in water. 1-pentanol 1-hexanol 1-octanol methanol OH Но OH Но НО 8. Classify the alcohols below as 1° or 2º or 3º. OH HO HO OHarrow_forwardWhat are the chemical reactions for the alcohol? Choices Oxidation of primary alcoholOxidation of secondary alcoholOxidation of tertiary alcoholHydration of alkeneIntramolecular dehydrationIntermolecular dehydrationCombustionHalogenation with hydrogen halidesHalogenation with phosphorus trihalidesarrow_forward
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