Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 13, Problem 13.52AP
Interpretation Introduction
Interpretation:
Four constitutional isomers has to be drawn for the molecular formula
Concept Introduction:
Constitutional isomers are the ones that have the same molecular formula but they differ in the connectivity of atoms present in the compound. The difference in connectivity between the atoms of the molecules results in different compounds.
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Dr. Mendel asked his BIOL 260 class what their height was and what their
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12pt v
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Experiment:
Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below.
Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization.
Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C
Sample C-Cool the third sample in an ice-bath to 0-2 °C
Results:
weight after recrystalization and melting point temp.
A=0.624g,102-115°
B=0.765g, 80-105°
C=1.135g, 77-108
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100
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c) It contains neither chlorine nor bromine.
80-
60-
40-
20-
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160
m/z
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CI
Chapter 13 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 13.1 - Draw out each compound to clearly show what groups...Ch. 13.1 - Prob. 13.2PCh. 13.2 - Prob. 13.3PCh. 13.2 - Give the structure corresponding to each IUPAC...Ch. 13.2 - Prob. 13.5PCh. 13.2 - Give the structure corresponding to each name. a....Ch. 13.3 - Which compound in each pair has the higher boiling...Ch. 13.3 - Rank the following compounds in order of...Ch. 13.4 - Which compounds are -hydroxy acids? tartaric acid...Ch. 13.4 - Prob. 13.10P
Ch. 13.5 - Prob. 13.11PCh. 13.5 - Prob. 13.12PCh. 13.5 - Prob. 13.13PCh. 13.6 - Prob. 13.14PCh. 13.6 - Prob. 13.15PCh. 13.6 - Prob. 13.16PCh. 13.6 - Prob. 13.17PCh. 13.6 - Prob. 13.18PCh. 13.6 - Prob. 13.19PCh. 13.7 - Prob. 13.20PCh. 13.7 - Prob. 13.21PCh. 13.7 - Prob. 13.22PCh. 13.7 - Prob. 13.23PCh. 13.7 - Prob. 13.24PCh. 13.8 - Prob. 13.25PCh. 13.8 - Prob. 13.26PCh. 13.8 - Prob. 13.27PCh. 13.8 - Draw the product formed when each ammonium salt is...Ch. 13.8 - Prob. 13.29PCh. 13.9 - Prob. 13.30PCh. 13.9 - Prob. 13.31PCh. 13.9 - Prob. 13.32PCh. 13.9 - Why is the boiling point of CH3CONH2(221C) higher...Ch. 13.9 - Prob. 13.34PCh. 13.9 - Prob. 13.35PCh. 13.10 - Prob. 13.36PCh. 13 - Prob. 13.37UKCCh. 13 - Prob. 13.38UKCCh. 13 - Prob. 13.39UKCCh. 13 - Prob. 13.40UKCCh. 13 - Prob. 13.41UKCCh. 13 - Prob. 13.42UKCCh. 13 - Prob. 13.43UKCCh. 13 - Prob. 13.44UKCCh. 13 - Prob. 13.45UKCCh. 13 - Prob. 13.46UKCCh. 13 - Prob. 13.47UKCCh. 13 - Prob. 13.48UKCCh. 13 - Prob. 13.49UKCCh. 13 - Prob. 13.50UKCCh. 13 - Prob. 13.51APCh. 13 - Prob. 13.52APCh. 13 - Prob. 13.53APCh. 13 - Draw the structure of a compound of molecular...Ch. 13 - Prob. 13.55APCh. 13 - Prob. 13.56APCh. 13 - Give an acceptable name for each compound.Ch. 13 - Prob. 13.58APCh. 13 - Prob. 13.59APCh. 13 - Prob. 13.60APCh. 13 - Prob. 13.61APCh. 13 - Prob. 13.62APCh. 13 - Prob. 13.63APCh. 13 - Give an acceptable name for each amine or amide....Ch. 13 - Draw the structure corresponding to each name. a....Ch. 13 - Draw the structure corresponding to each name. a....Ch. 13 - Prob. 13.67APCh. 13 - Draw the structure of each amine or ammonium salt....Ch. 13 - Prob. 13.69APCh. 13 - Which compound in each pair is more water soluble?...Ch. 13 - Prob. 13.71APCh. 13 - Prob. 13.72APCh. 13 - Prob. 13.73APCh. 13 - Prob. 13.74APCh. 13 - Prob. 13.75APCh. 13 - Prob. 13.76APCh. 13 - Prob. 13.77APCh. 13 - Prob. 13.78APCh. 13 - Prob. 13.79APCh. 13 - Prob. 13.80APCh. 13 - Prob. 13.81APCh. 13 - Prob. 13.82APCh. 13 - Prob. 13.83APCh. 13 - Prob. 13.84APCh. 13 - Prob. 13.85APCh. 13 - Prob. 13.86APCh. 13 - Prob. 13.87APCh. 13 - Draw the products of each acid-base reaction.Ch. 13 - Prob. 13.89APCh. 13 - Prob. 13.90APCh. 13 - Prob. 13.91APCh. 13 - Prob. 13.92APCh. 13 - Ritalin is the trade name for methylphenidate, a...Ch. 13 - Prob. 13.94APCh. 13 - Prob. 13.95CPCh. 13 - Prob. 13.96CPCh. 13 - Prob. 13.97CPCh. 13 - Prob. 13.98BTCCh. 13 - Prob. 13.99BTCCh. 13 - Prob. 13.100BTC
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