EBK INTRODUCTION TO CHEMICAL ENGINEERIN
8th Edition
ISBN: 9781259878091
Author: SMITH
Publisher: MCGRAW HILL BOOK COMPANY
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Chapter 13, Problem 13.42P
Interpretation Introduction
Interpretation:
The given equation for the equimolar binary liquid mixture is to be rationalized.
Concept Introduction:
Margules equation for excess Gibbs energy in terms of the composition of the binary system in VLE is:
Here,
For the limiting case of infinite dilution, the equations become:
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Chapter 13 Solutions
EBK INTRODUCTION TO CHEMICAL ENGINEERIN
Ch. 13 - Prob. 13.1PCh. 13 - Assuming Raoult’s law to be valid, prepare a Pxy...Ch. 13 - Assuming Raoult’s law to apply to the system...Ch. 13 - Prob. 13.4PCh. 13 - Prove: An equilibrium liquid/vapor system...Ch. 13 - Of the following binary liquid/vapor systems,...Ch. 13 - A single-stage liquid/vapor separation for the...Ch. 13 - Do all four parts of Prob. 13.7, and compare the...Ch. 13 - A mixture containing equimolar amounts of...Ch. 13 - Do all four parts of Prob. 13.9. and compare the...
Ch. 13 - A binary mixture of mole fraction z1is flashed to...Ch. 13 - Humidity, relating to the quantity of moisture in...Ch. 13 - A concentrated binary solution containing mostly...Ch. 13 - Air, even more than carbon dioxide, is inexpensive...Ch. 13 - Helium-laced gases are used as breathing media for...Ch. 13 - A binary system of species 1 and 2 consists of...Ch. 13 - For the system ethyl ethanoate(l)/n-heptane(2) at...Ch. 13 - A liquid mixture of cyclohexanone(1)/phenol(2) for...Ch. 13 - A binary system of species 1 and 2 consists of...Ch. 13 - For the acetone(l)/methanol(2) system, a vapor...Ch. 13 - The following is a rule of thumb: For a binary...Ch. 13 - A process stream contains light species 1 and...Ch. 13 - If a system exhibits VLE, at least one of the...Ch. 13 - Flash calculations are simpler for binary systems...Ch. 13 - Prob. 13.25PCh. 13 - (a) A feed containing equimolar amounts of...Ch. 13 - A binary mixture of benzene(1) and toluene(2) is...Ch. 13 - Ten (10) kmolhr-1 of hydrogen sulfide gas is...Ch. 13 - Physiological studies show the neutral comfort...Ch. 13 - Prob. 13.30PCh. 13 - Prob. 13.31PCh. 13 - Prob. 13.32PCh. 13 - If Eq. (13.24) is valid for isothermal VLE in a...Ch. 13 - Prob. 13.34PCh. 13 - The excess Gibbs energy for binary systems...Ch. 13 - For the ethanol(l )/chloroform(2) system at 50°C,...Ch. 13 - VLE data for methyl tert-butyl...Ch. 13 - Prob. 13.38PCh. 13 - Prob. 13.39PCh. 13 - Following are VLE data for the system...Ch. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.45PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Prob. 13.50PCh. 13 - Problems 13.43 through 13.54 require parameter...Ch. 13 - Prob. 13.52PCh. 13 - The following expressions have been reported for...Ch. 13 - Possible correlating equations for In 1 in a...Ch. 13 - Prob. 13.57PCh. 13 - Binary VLE data are commonly measured at constant...Ch. 13 - Consider the following model for GE/RT of a binary...Ch. 13 - A breathalyzer measures volume-% ethanol in gases...Ch. 13 - Table 13.10 gives values of parameters for the...Ch. 13 - Prob. 13.62PCh. 13 - A single P-x1- y1data point is available for a...Ch. 13 - A single P- x1, data point is available for a...Ch. 13 - The excess Gibbs energy for the system...Ch. 13 - Prob. 13.66PCh. 13 - A system formed of methane(l) and a light oil(2)...Ch. 13 - Use Eq. (13.13) to reduce one of the following...Ch. 13 - For one of the following substances, determine...Ch. 13 - Departures from Raoult's law are primarily from...Ch. 13 - The relative volatility a12is commonly used in...Ch. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76P
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