(a) Interpretation: The light which has a higher energy is to be predicted. Concept introduction: The energy of a photon is directly proportional to its frequency ( E = h v ) . Frequency and wavelength are inversely proportional to each other ( v = c /λ ) . Therefore, there is an inverse relationship between energy and wavelength.

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Answer 1

Question

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

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Answer 3

Question

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

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Answer 4

Question

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

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Answer 5

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 6

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 7

Chapter 13, Problem 13.13P

Interpretation Introduction

(a)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 8

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 9

Interpretation Introduction

(b)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 10

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 11

Interpretation Introduction

(c)

Interpretation: The light which has a higher energy is to be predicted.

Concept introduction: The energy of a photon is directly proportional to its frequency (E=hv). Frequency and wavelength are inversely proportional to each other (v=c/λ). Therefore, there is an inverse relationship between energy and wavelength.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13 - What is the mass of the molecular ion formed from...Ch. 13 - Prob. 13.2P Ch. 13 - Use the following information to propose a...Ch. 13 - Prob. 13.4P Ch. 13 - What molecular ions would you expect for the...Ch. 13 - The mass spectrum of 2,3-dimethylpentane also...Ch. 13 - The base peak in the mass spectrum of 2, 2,...Ch. 13 - (a) What mass spectral fragments are formed by ...Ch. 13 - What cations are formed in the mass spectrometer...Ch. 13 - The low-resolution mass spectrum of an unknown...

Solution Summary: The author explains that the energy of a photon is directly proportional to its frequency (E=hv).

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Chapter 13 Solutions