Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 13, Problem 13.10E
Name each of the following as a derivative of phenol:
a.
b.
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4-tert-butyl oxy cyclohex-1-ene
Incorrect, 1 attempt remaining
The systematic name of this compound classifies the -OR group as
a substituent of the hydrocarbon, which is considered the principal
functional group. The ether substituent is named with the suffix
'oxy'.
The general format for the systematic name of a hydrocarbon is:
[prefix/substituent] + [parent] + [functional group suffix]
Substituents are listed in alphabetical order. Molecules with a chiral
center will indicate the absolute configuration at the beginning of its
name with the R and S notation.
5. Compressibility (6 points total). The isothermal compressibility is a measure of how
hard/easy it is to compress an object (how squishy is it?) at constant temperature. It is
др
defined as Br=-()=-(200²)T'
(a) You might wonder why there is a negative sign in this formula. What does it mean when
this quantity is positive and what does it mean when this quantity is negative?
(b) Derive the formula for the isothermal compressibility of an ideal gas (it is very simple!)
(c) Explain under what conditions for the ideal gas the compressibility is higher or lower,
and why that makes sense.
19. (3 pts) in Chapter 7 we will see a reaction of halocyclohexanes that requires that the halogen occupy an axial position with
this in mind, would you expect cis-1-bromo-3-methylcyclohexane or trans-1-bromo-3-methylcyclohexane to be more
reactive in this reaction? Briefly explain your choice using structures to support your answer.
Mere-eries-cecleone)
The tran-i-browse-3-methylcyclohexione
Chapter 13 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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