Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 13, Problem 13.61E
Interpretation Introduction
Interpretation:
The behavior of an alcohol as a weak Brønsted acid if it reacts with a strong Brønsted base (X) is to be shown. The behavior of an alcohol as a weak Brønsted base in the presence of a strong Brønsted acid (HA) is to be shown.
Concept introduction:
According to Brønsted theory of acids and bases, a substance that donates hydrogen ions
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Draw the most likely conjugate base resulting from this acid-base reaction.
Include all lone pairs. Ignore inorganic byproducts.
Drawing
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NaOCH2CH3
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Answer
2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
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without ambiguity.
a.
CH3
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Ph
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Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
Chapter 13 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 13 - Draw general formulas for an alcohol and phenol,...Ch. 13 - Prob. 13.2ECh. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Assign IUPAC names to the following alcohols: a....Ch. 13 - Several important alcohols are well known by...Ch. 13 - Prob. 13.6ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Draw structural formulas for each of the...Ch. 13 - Name each of the following as a derivative of...Ch. 13 - Name each of the following as a derivative of...
Ch. 13 - Prob. 13.11ECh. 13 - Draw structural formulas for each of the...Ch. 13 - Prob. 13.13ECh. 13 - Classify the following alcohols as primary,...Ch. 13 - Classify the following alcohols as primary,...Ch. 13 - Draw structural formulas for the four aliphatic...Ch. 13 - Why are the boiling points of alcohols much higher...Ch. 13 - Arrange the compounds of each group in order of...Ch. 13 - Prob. 13.19ECh. 13 - Draw structural formulas for the following...Ch. 13 - Prob. 13.21ECh. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the chief product formed...Ch. 13 - Draw the structures of the ethers that can be...Ch. 13 - Prob. 13.25ECh. 13 - Give the structure of an alcohol that could be...Ch. 13 - Give the structure of an alcohol that could be...Ch. 13 - What products would result from the following...Ch. 13 - What products would result from the following...Ch. 13 - Each of the following conversions requires more...Ch. 13 - Each of the following conversions requires more...Ch. 13 - The three-carbon diol used in antifreeze is It is...Ch. 13 - Methanol is fairly volatile and evaporates quickly...Ch. 13 - Prob. 13.34ECh. 13 - Prob. 13.35ECh. 13 - Name an alcohol used in each of the following...Ch. 13 - Prob. 13.37ECh. 13 - Prob. 13.38ECh. 13 - Assign a common name to each of the following...Ch. 13 - Assign a common name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Assign the IUPAC name to each of the following...Ch. 13 - Prob. 13.43ECh. 13 - Draw structural formulas for the following: a....Ch. 13 - Prob. 13.45ECh. 13 - Prob. 13.46ECh. 13 - Prob. 13.47ECh. 13 - Arrange the following compounds in order of...Ch. 13 - Arrange the compounds in Exercise 13.48 in order...Ch. 13 - Prob. 13.50ECh. 13 - Complete the following reactions: a. b....Ch. 13 - Prob. 13.52ECh. 13 - Lipoic acid is required by many microorganisms for...Ch. 13 - Alcohols and thiols can both be oxidized in a...Ch. 13 - Prob. 13.55ECh. 13 - Prob. 13.56ECh. 13 - Prob. 13.57ECh. 13 - Thiols have lower boiling points and are less...Ch. 13 - Prob. 13.59ECh. 13 - Prob. 13.60ECh. 13 - Prob. 13.61ECh. 13 - Prob. 13.62ECh. 13 - A mixture of ethanol and 1propanol is heated to...Ch. 13 - Prob. 13.64ECh. 13 - Prob. 13.65ECh. 13 - Prob. 13.66ECh. 13 - Prob. 13.67ECh. 13 - Figure 13.8 points out that methanol is used as a...Ch. 13 - Figure 13.13 focuses on the use of thiol chemistry...Ch. 13 - Prob. 13.70ECh. 13 - Prob. 13.71ECh. 13 - Prob. 13.72ECh. 13 - The compound that has the greatest polarity is: a....Ch. 13 - Alcoholic beverages contain: a. wood alcohol. b....Ch. 13 - Prob. 13.75ECh. 13 - Which of the following compounds is an ether? a....
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