Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 13, Problem 109IE
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Curved arrows are used to illustrate the flow of electrons. Using
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Curved arrows are used to illustrate the flow of electrons using the provided starting and product structures draw the curved electron pushing arrows for the following reaction or mechanistic steps Ether(solvent)
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Chapter 13 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 13.3 - The labels have fallen off three bottles...Ch. 13.3 - Explain how a redox reaction involves electrons in...Ch. 13.3 - Prob. 13.2.1PECh. 13.3 - Prob. 13.2.2PECh. 13.4 -
4.11 Which data set, of the two graphed here,...Ch. 13.4 - You are titrating an acidic solution with a basic...Ch. 13.4 - State whether each of the following statements is...Ch. 13.4 - State whether each of the following statements is...Ch. 13.4 -
4.15 We have learned in this chapter that many...Ch. 13.4 - Prob. 13.5.2PE
Ch. 13.4 -
4.17 Specify what ions are present in solution...Ch. 13.4 - Prob. 13.6.2PECh. 13.5 - Prob. 13.7.1PECh. 13.5 - Acetone. CH3COCH3, is a nonelectrolyte;...Ch. 13.5 -
4.21 Using solubility guidelines, predict whether...Ch. 13.5 - Prob. 13.8.2PECh. 13.5 - Prob. 13.9.1PECh. 13.5 - Prob. 13.9.2PECh. 13.5 -
4 3 Use the molecular representations shown here...Ch. 13.5 - The concept of chemical equilibrium is very...Ch. 13.5 -
4 5 You are presented with a white solid and told...Ch. 13.5 - Which of the following ions will always be a...Ch. 13 - Which element is oxidized, and which is reduced in...Ch. 13 - Which of the following are redox reactions? For...Ch. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - The solubility of Xe in water at 1 atm pressure...Ch. 13 - The coinage metals (Group 1B) copper, silver, and...Ch. 13 - Prob. 8ECh. 13 - The contents of the closed box in each of the...Ch. 13 - An aqueous solution of an unknown solute is tested...Ch. 13 -
4.42 Because the oxide ion is basic, metal oxides...Ch. 13 - Prob. 12ECh. 13 -
4.44 As K20 dissolves in water, the oxide ion...Ch. 13 - True or false: If a substance is oxidized, it is...Ch. 13 - Prob. 15ECh. 13 - Which region of the periodic table shown here...Ch. 13 - Determine the oxidation number of sulfur in each...Ch. 13 - Determine the oxidation number for the indicated...Ch. 13 - Determine the oxidation number for the indicated...Ch. 13 - Write balanced molecular and net ionic equations...Ch. 13 - Using the activity series (Table 4.5), write...Ch. 13 - The enthalpy of solution of KBr in water is about...Ch. 13 - Prob. 23ECh. 13 -
4.58 The following reactions (note that the...Ch. 13 - Is the concentration of a solution an intensive or...Ch. 13 - Prob. 26ECh. 13 - Calculate the molarity of a solution that contains...Ch. 13 -
4.62
Calculate the molarity of a solution made by...Ch. 13 - Prob. 29ECh. 13 -
4.66 The average adult male has a total blood...Ch. 13 -
4.67
How many grams of ethanol, CH2CH2OH should...Ch. 13 - Prob. 32ECh. 13 - Which will have the highest concentration of...Ch. 13 - Prob. 34ECh. 13 - Prob. 35ECh. 13 - 13.36 Explain why pressure substantially affects...Ch. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Prob. 39ECh. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Some sulfuric acid is spilled on a lab bench You...Ch. 13 -
4.84 The distinctive odor of vinegar is due to...Ch. 13 - A 4.36-g sample of an unknown alkali metal...Ch. 13 -
4.86 An 8.65-g sample of an unknown group 2A...Ch. 13 - A solution of 100.0 mL of 0.200 M KOH is mixed...Ch. 13 - A 1.248-9 sample of limestone rock is pulverized...Ch. 13 - 4.91 Uranium hexafluoride, UF6, is processed to...Ch. 13 - The accompanying photo shows the reaction between...Ch. 13 - Prob. 53ECh. 13 -
4.94 You choose to investigate some of the...Ch. 13 -
4 95 Antacids are often used to relieve pain and...Ch. 13 -
4 96 The commercial production of nitric acid...Ch. 13 - Consider the following reagents: zinc, copper,...Ch. 13 - 98 Bronze is a solid solution of Cu(s) and Sn(s);...Ch. 13 - Prob. 59ECh. 13 - Tartaric acid. H2C4H4O6, has two acidic hydrogens....Ch. 13 - Prob. 61ECh. 13 - A solid sample of Zn(OH)2 is added to 0.350 L of...Ch. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Prob. 65ECh. 13 - A fertilizer railroad car carrying 34,300 gallons...Ch. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 -
4.115 Federal regulations set an upper limit of...Ch. 13 - A mixture of gases A2 and B2 are introduced to a...Ch. 13 - Practice Exercise 2 Calculate the change in the...Ch. 13 - A solid sample of Zn(OH)2 is added to 0.350 L of...Ch. 13 -
Practice Exercise 2
Calculate the work, in J, if...Ch. 13 - Practice Exercise 1 A chemical reaction that gives...Ch. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Practice Exercise 1 When 0.243 g of Mg metal is...Ch. 13 - Practical exercise 2 When 50.0 mL of 0.100MAgNO3...Ch. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - Prob. 84ECh. 13 - Prob. 85ECh. 13 - Calculate H for the reaction C(s)+...Ch. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - Prob. 89ECh. 13 - Prob. 90ECh. 13 - Prob. 91AECh. 13 - Prob. 92AECh. 13 -
Use the average bond enthalpies in Table 5.4 to...Ch. 13 - Prob. 94AECh. 13 - Prob. 95AECh. 13 - One of the important ideas of thermodynamics is...Ch. 13 - Two positively charged spheres, each with a charge...Ch. 13 - SI The accompanying photo shows a pipevine...Ch. 13 - Consider the accompanying energy diagram. Does...Ch. 13 - Write balanced net ionic equations for the...Ch. 13 -
4.27 Separate samples of a solution of an unknown...Ch. 13 - Prob. 102AECh. 13 - Prob. 103AECh. 13 - Prob. 104AECh. 13 - Prob. 105AECh. 13 - Prob. 106IECh. 13 - State whether each of the following statements is...Ch. 13 - State whether each of the following statements is...Ch. 13 - A textbook on chemical thermodynamics states, “The...Ch. 13 - Prob. 110IECh. 13 - Prob. 111IECh. 13 - Complete and balance the following molecular...Ch. 13 -
[13.113]At 35°C the vapor pressure of acetone,...Ch. 13 - Write balanced molecular and net ionic equations...
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- Use the References to access important values if needed for this question. What is the IUPAC name of each of the the following? 0 CH3CHCNH₂ CH3 CH3CHCNHCH2CH3 CH3arrow_forwardYou have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…arrow_forwardb) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppmarrow_forward
- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY