EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 9780100552234
Author: ZUMDAHL
Publisher: YUZU
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Chapter 13, Problem 105E
Interpretation Introduction
Interpretation: The stepwise
Concept introduction: An acid that is capable of donating two
At equilibrium, the equilibrium constant expression is expressed by the formula,
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20.21 Predict the major product formed by 1,4-addition of HCI to cyclopentadiene.
20.22 Draw structural formulas for the two constitutional isomers with the molecular for-
mula C₂H,Br, formed by adding one mole of Br, to cyclopentadiene.
Add substituents to draw the conformer below (sighting down the
indicated bond), then rotate the back carbon to provide the conformation
that will be capable of an E2 elimination. R/S stereochemistry is graded.
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20.17 Predict the structure of the major product formed by 1,2-addition of HBr to
3-methylenecyclohexene.
3-Methylenecyclohexene
20.18 Predict the major product formed by 1,4-addition of HBr to 3-methylenecyclohexene.
Chapter 13 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 13 - Define each of the following: a. Arrhenius acid b....Ch. 13 - Define or illustrate the meaning of the following...Ch. 13 - Prob. 3RQCh. 13 - How is acid strength related to the value of Ka?...Ch. 13 - Two strategies are followed when solving for the...Ch. 13 - Prob. 6RQCh. 13 - Prob. 7RQCh. 13 - For conjugate acidbase pairs, how are Ka and Kb...Ch. 13 - What is a salt? List some anions that behave as...Ch. 13 - For oxyacids, how does acid strength depend on a....
Ch. 13 - Prob. 1ALQCh. 13 - Differentiate between the terms strength and...Ch. 13 - Sketch two graphs: (a) percent dissociation for...Ch. 13 - Prob. 4ALQCh. 13 - Prob. 5ALQCh. 13 - Prob. 6ALQCh. 13 - Prob. 7ALQCh. 13 - Prob. 8ALQCh. 13 - Consider a solution formed by mixing 100.0 mL of...Ch. 13 - Prob. 10ALQCh. 13 - Prob. 11ALQCh. 13 - Prob. 12ALQCh. 13 - What is meant by pH? True or false: A strong acid...Ch. 13 - Prob. 14ALQCh. 13 - Prob. 15ALQCh. 13 - Prob. 16ALQCh. 13 - Prob. 17ALQCh. 13 - The salt BX, when dissolved in water, produces an...Ch. 13 - Anions containing hydrogen (for example, HCO3 and...Ch. 13 - Prob. 20QCh. 13 - Prob. 21QCh. 13 - Prob. 22QCh. 13 - Prob. 23QCh. 13 - Prob. 24QCh. 13 - Prob. 25QCh. 13 - The following are representations of acidbase...Ch. 13 - Prob. 27QCh. 13 - Prob. 28QCh. 13 - Prob. 29QCh. 13 - Prob. 30QCh. 13 - Prob. 31QCh. 13 - Prob. 32QCh. 13 - Prob. 33QCh. 13 - Prob. 34QCh. 13 - Write balanced equations that describe the...Ch. 13 - Write the dissociation reaction and the...Ch. 13 - Prob. 37ECh. 13 - For each of the following aqueous reactions,...Ch. 13 - Classify each of the following as a strong acid or...Ch. 13 - Consider the following illustrations: Which beaker...Ch. 13 - Use Table 13-2 to order the following from the...Ch. 13 - Prob. 42ECh. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Values of Kw as a function of temperature are as...Ch. 13 - At 40.C the value of Kw is 2.92 1014. a....Ch. 13 - Calculate the pH and pOH of the solutions in...Ch. 13 - Calculate [H+] and [OH] for each solution at 25C....Ch. 13 - Prob. 51ECh. 13 - Fill in the missing information in the following...Ch. 13 - The pH of a sample of gastric juice in a persons...Ch. 13 - The pOH of a sample of baking soda dissolved in...Ch. 13 - What are the major species present in 0.250 M...Ch. 13 - A solution is prepared by adding 50.0 mL of 0.050...Ch. 13 - Calculate the pH of each of the following...Ch. 13 - Calculate the pH of each of the following...Ch. 13 - Calculate the concentration of an aqueous HI...Ch. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - A solution is prepared by adding 50.0 mL...Ch. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - Calculate the concentration of all species present...Ch. 13 - Calculate the percent dissociation for a 0.22-M...Ch. 13 - For propanoic acid (HC3H5O2, Ka = 1.3 105),...Ch. 13 - A solution is prepared by dissolving 0.56 g...Ch. 13 - Monochloroacetic acid, HC2H2ClO2, is a skin...Ch. 13 - A typical aspirin tablet contains 325 mg...Ch. 13 - Calculate the pH of a solution that contains 1.0 M...Ch. 13 - Prob. 72ECh. 13 - Calculate the percent dissociation of the acid in...Ch. 13 - Prob. 74ECh. 13 - A 0.15-M solution of a weak acid is 3.0%...Ch. 13 - An acid HX is 25% dissociated in water. If the...Ch. 13 - Trichloroacetic acid (CCl3CO2H) is a corrosive...Ch. 13 - The pH of a 0.063-M solution of hypobromous acid...Ch. 13 - A solution of formic acid (HCOOH, Ka = 1.8 104)...Ch. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - You have 100.0 g saccharin, a sugar substitute,...Ch. 13 - Write the reaction and the corresponding Kb...Ch. 13 - Write the reaction and the corresponding Kb...Ch. 13 - Prob. 85ECh. 13 - Use Table 13-3 to help order the following acids...Ch. 13 - Use Table 13-3 to help answer the following...Ch. 13 - Prob. 88ECh. 13 - Calculate the pH of the following solutions. a....Ch. 13 - Calculate [OH], pOH, and pH for each of the...Ch. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - What mass of KOH is necessary to prepare 800.0 mL...Ch. 13 - Calculate the concentration of an aqueous Sr(OH)2...Ch. 13 - Prob. 95ECh. 13 - For the reaction of hydrazine (N2H4) in water,...Ch. 13 - Calculate [OH], [H+], and the pH of 0.20 M...Ch. 13 - Calculate [OH], [H+], and the pH of 0.40 M...Ch. 13 - Calculate the pH of a 0.20-M C2H5NH2 solution (Kb...Ch. 13 - Prob. 100ECh. 13 - What is the percent ionization in each of the...Ch. 13 - Prob. 102ECh. 13 - The pH of a 0.016-M aqueous solution of...Ch. 13 - Calculate the mass of HONH2 required to dissolve...Ch. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - Prob. 107ECh. 13 - Arsenic acid (H3AsO4) is a triprotic acid with Ka1...Ch. 13 - Prob. 109ECh. 13 - Calculate [CO32] in a 0.010-M solution of CO2 in...Ch. 13 - Prob. 111ECh. 13 - Calculate the pH of a 5.0 103-M solution of...Ch. 13 - Arrange the following 0.10 M solutions in order of...Ch. 13 - Prob. 114ECh. 13 - Prob. 115ECh. 13 - The Kb values for ammonia and methylamine are 1.8 ...Ch. 13 - Determine [OH], [H+], and the pH of each of the...Ch. 13 - Calculate the concentrations of all species...Ch. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - Prob. 121ECh. 13 - Papaverine hydrochloride (abbreviated papH+Cl;...Ch. 13 - An unknown salt is either NaCN, NaC2H3O2, NaF,...Ch. 13 - Prob. 124ECh. 13 - A 0.050-M solution of the salt NaB has a pH of...Ch. 13 - Prob. 126ECh. 13 - Prob. 127ECh. 13 - Prob. 128ECh. 13 - Are solutions of the following salts acidic,...Ch. 13 - Prob. 130ECh. 13 - Prob. 131ECh. 13 - Prob. 132ECh. 13 - Place the species in each of the following groups...Ch. 13 - Prob. 134ECh. 13 - Will the following oxides give acidic, basic, or...Ch. 13 - Prob. 136ECh. 13 - Prob. 137ECh. 13 - Prob. 138ECh. 13 - Prob. 139ECh. 13 - Zinc hydroxide is an amphoteric substance. Write...Ch. 13 - Prob. 141ECh. 13 - Prob. 142ECh. 13 - Prob. 143AECh. 13 - Prob. 144AECh. 13 - A solution is tested for pH and conductivity as...Ch. 13 - The pH of human blood is steady at a value of...Ch. 13 - Prob. 147AECh. 13 - Prob. 148AECh. 13 - Prob. 149AECh. 13 - Prob. 150AECh. 13 - Acrylic acid (CH29CHCO2H) is a precursor for many...Ch. 13 - Prob. 152AECh. 13 - Prob. 153AECh. 13 - Prob. 154AECh. 13 - Prob. 155AECh. 13 - Prob. 156AECh. 13 - Prob. 157AECh. 13 - Prob. 158AECh. 13 - Prob. 159AECh. 13 - Prob. 160AECh. 13 - Prob. 161AECh. 13 - For solutions of the same concentration, as acid...Ch. 13 - Prob. 163CWPCh. 13 - Consider a 0.60-M solution of HC3H5O3, lactic acid...Ch. 13 - Prob. 165CWPCh. 13 - Prob. 166CWPCh. 13 - Consider 0.25 M solutions of the following salts:...Ch. 13 - Calculate the pH of the following solutions: a....Ch. 13 - Prob. 169CWPCh. 13 - Prob. 170CPCh. 13 - Prob. 171CPCh. 13 - Prob. 172CPCh. 13 - Prob. 173CPCh. 13 - Prob. 174CPCh. 13 - Calculate the pH of a 0.200-M solution of C5H5NHF....Ch. 13 - Determine the pH of a 0.50-M solution of NH4OCl....Ch. 13 - Prob. 177CPCh. 13 - Prob. 178CPCh. 13 - Consider 1000. mL of a 1.00 104-M solution of a...Ch. 13 - Calculate the mass of sodium hydroxide that must...Ch. 13 - Prob. 181CPCh. 13 - Prob. 182CPCh. 13 - Will 0.10 M solutions of the following salts be...Ch. 13 - Prob. 184CPCh. 13 - A 0.100-g sample of the weak acid HA (molar mass =...Ch. 13 - Prob. 186CPCh. 13 - A 2.14 g sample of sodium hypoiodite is dissolved...Ch. 13 - Isocyanic acid (HNCO) can be prepared by heating...Ch. 13 - Prob. 189IPCh. 13 - An aqueous solution contains a mixture of 0.0500 M...Ch. 13 - Prob. 191MP
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- + Draw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. Br Drawing Strong Base H Q Atoms, Bonds Charges and Rings Draw or tap a new bond to see suggestions. Remove Done 語 Reset Undo + Drag To Panarrow_forwardDraw a vicinal alkyl bromide that would produce the following alkene in an E2 elimination. Use a dash or wedge bond to indicate stereochemistry on asymmetric centers, where applicable. Ignore any inorganic byproducts. + Drawing Į Strong Base H Br Q Atoms, Bonds and Rings Charges Draw or tap a new bond to see suggestions. Undo Reset 謂 Remove Done Drag To Pan +arrow_forwardDraw the product of the E2 reaction shown below. Include the correct stereochemistry. Ignore any inorganic byproducts. + Br CH3 Q Strong Base Drawing Atoms, Bonds and Rings Charges Undo Reset H "Br H N Br. Remove Done .N. Drag To Panarrow_forward
- Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the product of this elementary step in an elimination mechanism. Include all lone pairs and charges as appropriate. Ignore stereochemistry. Ignore byproducts. + Br: .. 8 0.01 M NaOH heat Drawing Q Atoms, Bonds and Rings Charges and Lone Pairs Draw or tap a new bond to see suggestions. Undo Reset Remove Done + Drag To Panarrow_forward+ Draw the product of the E2 reaction shown below. Include the correct stereochemistry. Ignore any inorganic byproducts. Ph CH2CH3 H H3C H Br DBN [૪] Drawing Atoms, Bonds and Rings H | OH Charges ―00 H. C | Undo Reset Br I Remove Done Drag To Pan +arrow_forwardReaction A Now the production A Œ In the product of reaction i 12 Dear the product of actionarrow_forward
- Macmillan Learnin When an unknown amine reacts with an unknown acid chloride, an amide with a molecular mass of 163 g/mol (M* = 163 m/z) is formed. In the infrared spectrum, important absorptions appear at 1661, 750 and 690 cm-1. The 13C NMR and DEPT spectra are provided. Draw the structure of the product as the resonance contributor lacking any formal charges. 13C NMR DEPT 90 200 160 120 80 40 0 200 160 120 80 DEPT 135 200 160 120 80 40 0 Draw the unknown amide. 40 40 0arrow_forwardDraw the major product karmed when I reach with the epoxide. Use walge dah bonds, including hydrogen al alcach genic center, to show the chemistry of the product Beeldraw any hydrogen akams on coxygen where applicablearrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. H I Select to Add Arrows + H H 'H Q H2O H2O CI:O .H H H H I Select to Add Arrows I : C H2O H H H Select to Add Arrows 'Harrow_forward
- + Draw an alkyl halide that produces ONLY the following alkene in an E2 elimination. Ignore any inorganic byproducts. Drawing Strong Base Q Atoms, Bonds and Rings Charges HO Br H2N Undo Reset Remove Done Drag To Panarrow_forwardFor the dehydrohalogenation (E2) reaction shown, draw the major organic product. Хок Br tert-butanol heat Select Drew Templates More Erase CH QQQarrow_forwardMacmillan Learning Draw the major, neutral organic product for each substitution reaction. For this question, assume that each substitution reaction goes to completion. Disregard elimination. Reaction A. CI H₂O Select Draw Templates More Erase C Harrow_forward
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