Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 12C.2, Problem 7P
Label the protons in each highlighted
a. b. c.
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5) Which of the following type of protons
are chemically equivalent?
A. homotopic only
B. diastereotopic only
C. enantiotopic only
D. A & C
E. A & B
Identify the set of protons as unrelated, homotopic, enantiopic, or diastereotopic.
3. Determine the indicated sets of protons as homotopic, enantiotopic, or diastereotopic
H
OH
а.
b.
с.
H
H
H3C
H
H;C
CH3
d.
е.
Chapter 12C Solutions
Organic Chemistry (6th Edition)
Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2PCh. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9PCh. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P
Ch. 12C.5 - Problem 14.12 Which compound give a NMR spectrum...Ch. 12C.5 - Prob. 14PCh. 12C.6 - Prob. 15PCh. 12C.6 - For each compound give the number of 1H NMR...Ch. 12C.6 - Prob. 17PCh. 12C.7 - Prob. 18PCh. 12C.7 - Problem 14.18 Describe the NMR spectrum of each...Ch. 12C.8 - Problem 14.19 Draw a splitting diagram for in ,...Ch. 12C.8 - Problem 14.20 Identify A and B, isomers of...Ch. 12C.9 - Problem 14.21 How many signals are present in the ...Ch. 12C.9 - Problem 14.22 What protons in alcohol A give rise...Ch. 12C.9 - How many peaks are observed in the NMR signal for...Ch. 12C.10 -
Problem 14.24 Propose a structure for a compound...Ch. 12C - 14.34 (a) How many NMR signals does each of the...Ch. 12C - 14.35 (a) How many NMR signals does each compound...Ch. 12C - Prob. 38PCh. 12C - 14.37 How many NMR signals does each natural...Ch. 12C - Prob. 40PCh. 12C - 14.39 What effect does increasing the operating...Ch. 12C - Prob. 43PCh. 12C - Prob. 44PCh. 12C - Prob. 45PCh. 12C - Prob. 47PCh. 12C - Prob. 48PCh. 12C - 14.48 How many NMR signals does each compound...Ch. 12C - 14.49 Rank the highlighted carbon atoms in each...Ch. 12C - 14.50 Identify the carbon atoms that give rise to...Ch. 12C - 14.62 Reaction of with , followed by treatment...Ch. 12C - Reaction of aldehyde D with amino alcohol E in the...Ch. 12C - 14.64 Propose a structure consistent with each set...
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- a. How many signals are in its 13C NMR spectrum?b. Which signal is at the lowest frequency? (CH3)2C=CH2arrow_forwardLabel the protons in attached highlighted CH2 group as enantiotopic, diastereotopic, or homotopic.arrow_forwardDetermining the Number of Peaks in an NMR Signal How many peaks are present in the NMR signal of the labeled protons of each compound?arrow_forward
- 14. Protons H, and H, in the following compound are Br HD А. homotopic enantiotopic diastereotopic mesotopic none of thes В. C. D. Е. Iarrow_forwardWhich underlined proton (or sets of protons) has the greater chemical shift (that is, the higher frequency signal)?arrow_forwardIdentify pairs of coupled protons in the compound whose COSY spectrum is shown below.arrow_forward
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