Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 12C, Problem 50P
Rank the highlighted carbon atoms in each compound in order of increasing chemical shift.
a. 
b. 
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The following is a two groups (Regular tomato sauce & Salt Reduced Tomato Sauce) of data recorded by a team analysising salt content in tomato sauce using the MOHR titration method:
Regular Tomato Sauce
Salt Reduced Tomato Sauce
340.0mmol/L
262.7mmol/L
QUESTION: For both groups (Regular & Salt Reduced tomato sauce) of data provide answers to the following calculations below:
1. Standard Deviation (Sx)
2. T Values (t0.05,4)
3. 95% Confidence Interval (mmol/L)
4. [Na+] (mg/100 mL)
5. 95% Confidence Interval (mg/100 mL)
If we have leucine (2-amino-4-methylpentanoic acid), alanine (2-aminopropanoic acid) and phenylalanine (2-amino-3-phenylpropanoic acid), indicate the tripeptides that can be formed (use the abbreviated symbols Leu., Ala and Phe).
Briefly state why trifluoroacetic acid is more acidic than acetic acid.
Chapter 12C Solutions
Organic Chemistry (6th Edition)
Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2PCh. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9PCh. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P
Ch. 12C.5 - Problem 14.12 Which compound give a NMR spectrum...Ch. 12C.5 - Prob. 14PCh. 12C.6 - Prob. 15PCh. 12C.6 - For each compound give the number of 1H NMR...Ch. 12C.6 - Prob. 17PCh. 12C.7 - Prob. 18PCh. 12C.7 - Problem 14.18 Describe the NMR spectrum of each...Ch. 12C.8 - Problem 14.19 Draw a splitting diagram for in ,...Ch. 12C.8 - Problem 14.20 Identify A and B, isomers of...Ch. 12C.9 - Problem 14.21 How many signals are present in the ...Ch. 12C.9 - Problem 14.22 What protons in alcohol A give rise...Ch. 12C.9 - How many peaks are observed in the NMR signal for...Ch. 12C.10 -
Problem 14.24 Propose a structure for a compound...Ch. 12C - 14.34 (a) How many NMR signals does each of the...Ch. 12C - 14.35 (a) How many NMR signals does each compound...Ch. 12C - Prob. 38PCh. 12C - 14.37 How many NMR signals does each natural...Ch. 12C - Prob. 40PCh. 12C - 14.39 What effect does increasing the operating...Ch. 12C - Prob. 43PCh. 12C - Prob. 44PCh. 12C - Prob. 45PCh. 12C - Prob. 47PCh. 12C - Prob. 48PCh. 12C - 14.48 How many NMR signals does each compound...Ch. 12C - 14.49 Rank the highlighted carbon atoms in each...Ch. 12C - 14.50 Identify the carbon atoms that give rise to...Ch. 12C - 14.62 Reaction of with , followed by treatment...Ch. 12C - Reaction of aldehyde D with amino alcohol E in the...Ch. 12C - 14.64 Propose a structure consistent with each set...
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