Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 12.2, Problem 12.9PP
Classify each of the following alcohols as primary (1°), secondary (2°), or tertiary (3°):
a.
b. CH3 -CH2 -CH2 -CH2- OH
c.
d.
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Predict the major products of this organic reaction.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between different major products.
☐
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: ☐
+
NaOH
HO
2
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drawing a structure.
Shown below are five NMR spectra for five different C6H10O2 compounds. For each spectrum, draw the structure of the compound, and assign the spectrum by labeling H's in your structure (or in a second drawing of the structure) with the chemical shifts of the corresponding signals (which can be estimated to nearest 0.1 ppm). IR information is also provided. As a reminder, a peak near 1700 cm-1 is consistent with the presence of a carbonyl (C=O), and a peak near 3300 cm-1 is consistent with the presence of an O–H.
Extra information: For C6H10O2 , there must be either 2 double bonds, or 1 triple bond, or two rings to account for the unsaturation. There is no two rings for this problem.
A strong band was observed in the IR at 1717 cm-1
Predict the major products of the organic reaction below.
: ☐
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OH
1. NaH
2. CH₂Br
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drawing a structure.
Chapter 12 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Prob. 12.3PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Give the common name for each of the following: a....Ch. 12.1 - Prob. 12.6PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Draw the condensed structural formula, or...Ch. 12.2 - Classify each of the following alcohols as primary...Ch. 12.2 - Classify each of the following alcohols as primary...
Ch. 12.2 - Prob. 12.11PPCh. 12.2 - Prob. 12.12PPCh. 12.2 - Give an explanation for each of the following...Ch. 12.2 - Give an explanation for each of the following...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Prob. 12.27PPCh. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Prob. 12.33PPCh. 12.4 - Prob. 12.34PPCh. 12.4 - Oxybenzone is an effective sunscreen whose...Ch. 12.4 - Avobenzone is a common ingredient in sunscreen....Ch. 12 - Prob. 12.37UTCCh. 12 - The compound frambinone has the taste of...Ch. 12 - A compound called resveratrol is an antioxidant,...Ch. 12 - A compound called cinnamaldehyde is found in...Ch. 12 - Prob. 12.41UTCCh. 12 - Prob. 12.42UTCCh. 12 - Prob. 12.43APPCh. 12 - Classify each of the following alcohols as primary...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Prob. 12.63CPCh. 12 - Draw the condensed structural formulas and give...Ch. 12 - A compound with the formula C4H8O is synthesized...Ch. 12 - A compound with the formula C5H10O oxidizes to...Ch. 12 - Compound A is a primary alcohol whose formula is...Ch. 12 - Compound X is a secondary alcohol whose formula is...Ch. 12 - Prob. 21CICh. 12 - Prob. 22CICh. 12 - Prob. 23CICh. 12 - Prob. 24CICh. 12 - Prob. 25CICh. 12 - lonone is a compound that gives violets their...
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