Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Question
Chapter 12, Problem 9E
Interpretation Introduction
To determine: Why are intremolecular forces generally much weaker than bonding forces?
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Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
21.6
50.08
0.03 51.0
22.4
60-080-02 95.0
23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
Chapter 12 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 12 - Prob. 1SAQCh. 12 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 12 - Taking intermolecular forces into account, which...Ch. 12 - What substance experiences dipole-dipole forces?...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Determine the amount of heat (in kJ) required to...Ch. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 11SAQCh. 12 - Why do ethanol and dimethyl ether have such...Ch. 12 - Why are intermolecular forces important?Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Which factors cause transitions between the solid...Ch. 12 - Describe the relationship between the state of a...Ch. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - What is the ion-dipole force? Why is it important?Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - What is capillary action? How does it depend on...Ch. 12 - Explain what happens during the processes of...Ch. 12 - Why is vaporization endothermic? Why is...Ch. 12 - Prob. 20ECh. 12 - What is the heat of vaporization for a liquid, and...Ch. 12 - Explain the process of dynamic equilibrium. How is...Ch. 12 - What happens to a system in dynamic equilibrium...Ch. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Examine the heating curve for water in section...Ch. 12 - What is a phase diagram? What is the significance...Ch. 12 - Draw a generic phase diagram and label its...Ch. 12 - Prob. 35ECh. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Prob. 38ECh. 12 - Arrange these compounds in order of increasing...Ch. 12 - Prob. 40ECh. 12 - Pick the compound with the highest boiling point...Ch. 12 - Pick the compound with the highest boiling point...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Water (a) “wets” some surfaces and beads up on...Ch. 12 - The structures of two isomers of heptanes are...Ch. 12 - Prob. 50ECh. 12 - Water in a glass tube that contains grease or oil...Ch. 12 - When a thin glass tube is put into water, the...Ch. 12 - Which evaporates more quickly: 55 mL of water in a...Ch. 12 - Prob. 54ECh. 12 - Spilling room temperature water over your skin on...Ch. 12 - Prob. 56ECh. 12 - The human body obtains 915 kJ of energy from a...Ch. 12 - Prob. 58ECh. 12 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - How much energy is released when 65.8 g of water...Ch. 12 - Prob. 66ECh. 12 - An 8.5 g ice cube is placed into 255 g of water....Ch. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - The high-pressure phase diagram of ice is shown...Ch. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - How is the density of solid water compared to that...Ch. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Four ice cubes at exactly 00C with a total mass of...Ch. 12 - Prob. 86ECh. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Prob. 89ECh. 12 - A sealed flask contains 0.55 g of water at 280C....Ch. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Given that the heat of fusion of water is —6.02...Ch. 12 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 12 - Prob. 96ECh. 12 - Prob. 97E
Knowledge Booster
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