Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Textbook Question
Chapter 12, Problem 19E
Why is vaporization endothermic? Why is condensation exothermic?
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Devise electrochemical cells in which the following reactions could be made to occur. If liquid
junctions are necessary, note them in the cell schematic appropriately, but neglect their effects.
(a) H2OH + OH¯
(b) 2H2O2
H₂O
(c) 2PbSO4 + 2H2O
(d) An
TMPD
PыO₂+ Pb + 4H+ + 20%¯¯
An + TMPD (in acetonitrile, where An and An are anthracene and its
anion radical, and TMPD and TMPD are N,N,N',N'-tetramethyl-p-phenylenediamine and its
cation radical. Use anthracene potentials for DMF solutions given in Appendix C.3).
(e) 2Ce3+ + 2H + BQ 2Ce4+ + H2Q (aqueous, where BQ is p-benzoquinone and H₂Q is p-
hydroquinone)
(f) Ag +Agl (aqueous)
(g) Fe3+ + Fe(CN)6 Fe²+ + Fe(CN) (aqueous)
Consider each of the following electrode-solution interfaces, and write the equation for the elec-
trode reaction that occurs first when the potential is moved in (1) a negative direction and (2) a posi-
tive direction from the open-circuit potential. Next to each reaction write the approximate potential
for the reaction in V vs. SCE (assuming the reaction is reversible).
(a) Pt/Cu2+ (0.01 M), Cd2+ (0.01 M), H2SO4(1 M)
(b) Pt/Sn2+ (0.01 M), Sn4+ (0.01 M), HCl(1 M)
(c) Hg/Cd2+ (0.01 M), Zn2+ (0.01 M), HCl(1 M)
What are the major products of both of the organic reactions. Please be sure to use wedge and dash bonds to show the stereochemistry of the products if it is needed. Please include the final product as well as a digram/drawing to show the mechanism of the reaction.
Chapter 12 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 12 - Prob. 1SAQCh. 12 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 12 - Taking intermolecular forces into account, which...Ch. 12 - What substance experiences dipole-dipole forces?...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Determine the amount of heat (in kJ) required to...Ch. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 11SAQCh. 12 - Why do ethanol and dimethyl ether have such...Ch. 12 - Why are intermolecular forces important?Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Which factors cause transitions between the solid...Ch. 12 - Describe the relationship between the state of a...Ch. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - What is the ion-dipole force? Why is it important?Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - What is capillary action? How does it depend on...Ch. 12 - Explain what happens during the processes of...Ch. 12 - Why is vaporization endothermic? Why is...Ch. 12 - Prob. 20ECh. 12 - What is the heat of vaporization for a liquid, and...Ch. 12 - Explain the process of dynamic equilibrium. How is...Ch. 12 - What happens to a system in dynamic equilibrium...Ch. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Examine the heating curve for water in section...Ch. 12 - What is a phase diagram? What is the significance...Ch. 12 - Draw a generic phase diagram and label its...Ch. 12 - Prob. 35ECh. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Prob. 38ECh. 12 - Arrange these compounds in order of increasing...Ch. 12 - Prob. 40ECh. 12 - Pick the compound with the highest boiling point...Ch. 12 - Pick the compound with the highest boiling point...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Water (a) “wets” some surfaces and beads up on...Ch. 12 - The structures of two isomers of heptanes are...Ch. 12 - Prob. 50ECh. 12 - Water in a glass tube that contains grease or oil...Ch. 12 - When a thin glass tube is put into water, the...Ch. 12 - Which evaporates more quickly: 55 mL of water in a...Ch. 12 - Prob. 54ECh. 12 - Spilling room temperature water over your skin on...Ch. 12 - Prob. 56ECh. 12 - The human body obtains 915 kJ of energy from a...Ch. 12 - Prob. 58ECh. 12 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - How much energy is released when 65.8 g of water...Ch. 12 - Prob. 66ECh. 12 - An 8.5 g ice cube is placed into 255 g of water....Ch. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - The high-pressure phase diagram of ice is shown...Ch. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - How is the density of solid water compared to that...Ch. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Four ice cubes at exactly 00C with a total mass of...Ch. 12 - Prob. 86ECh. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Prob. 89ECh. 12 - A sealed flask contains 0.55 g of water at 280C....Ch. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Given that the heat of fusion of water is —6.02...Ch. 12 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 12 - Prob. 96ECh. 12 - Prob. 97E
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- K Problem 16 of 24 Submit Draw the starting structure that would yield this product under these conditions. Select to Draw 1. NH4Cl, NaCN 2. HCI, H2O, A NH3 + 0arrow_forwardGive detailed me detailed mechanism Solution with explanation needed. Don't give Ai generated solution. avoid handwritten Solutionarrow_forwardShow work with explanation needed. don't give Ai generated solutionarrow_forward
- K Problem 21 of 24 Submit Draw the missing organic structures in the following multistep synthesis. Show the final product at physiological pH (pH = 7.4). Ignore any inorganic byproducts formed. H 0 NH3 Select to Draw HCN H+, H2O Select to Draw Select to Draw Δarrow_forwardShow work with explanation needed. Don't give Ai generated solution. Give correct solutionarrow_forwardK Problem 23 of 24 Submit Draw the product of the reaction shown below at physiological pH (pH = 7.4). Ignore inorganic byproducts. S O 1. NH3, 2. HCN 3. H+, H₂O, A Select to Drawarrow_forward
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