Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 12, Problem 93AE
At 620. K butadiene dimerizes at a moderate rate. The following data were obtained in an experiment involving this reaction:
| t(s) | [C4H6] (mol/L) |
| 0 | 0.01000 |
| 1000.. | 0.00629 |
| 2000. | 0.00459 |
| 3000. | 0.00361 |
- a. Determine the order of the reaction in butadiene.
- b. In how many seconds is the dimerization 1.0% complete?
- c. In how many seconds is the dimerization 10.0% complete?
- d. What is the half-life for the reaction if the initial concentration of butadiene is 0.0200 M?
- e. Use the results from this problem and Exercise 45 to calculate the activation energy for the dimerization of butadiene.
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