Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 12, Problem 93AE
At 620. K butadiene dimerizes at a moderate rate. The following data were obtained in an experiment involving this reaction:
| t(s) | [C4H6] (mol/L) |
| 0 | 0.01000 |
| 1000.. | 0.00629 |
| 2000. | 0.00459 |
| 3000. | 0.00361 |
- a. Determine the order of the reaction in butadiene.
- b. In how many seconds is the dimerization 1.0% complete?
- c. In how many seconds is the dimerization 10.0% complete?
- d. What is the half-life for the reaction if the initial concentration of butadiene is 0.0200 M?
- e. Use the results from this problem and Exercise 45 to calculate the activation energy for the dimerization of butadiene.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Don't used Ai solution
3. Devise a retrosynthesis for the problem given below and then provide the corresponding
synthesis with all necessary reagents/reactants:
RETROSYNTHESIS:
SYNTHESIS:
Br
Several square planar complexes are known for Gold (III) ions but not for Silver (III) why?
Chapter 12 Solutions
Chemistry
Ch. 12 - Define reaction rate. Distinguish between the...Ch. 12 - Distinguish between the differential rate law and...Ch. 12 - One experimental procedure that can be used to...Ch. 12 - The initial rate for a reaction is equal to the...Ch. 12 - Consider the zero-, first-, and second-order...Ch. 12 - Derive expressions for the half-life of zero-,...Ch. 12 - Prob. 7RQCh. 12 - What two requirements must be met to call a...Ch. 12 - Prob. 9RQCh. 12 - Give the Arrhenius equation. Take the natural log...
Ch. 12 - Why does a catalyst increase the rate of a...Ch. 12 - Define stability from both a kinetic and...Ch. 12 - Describe at least two experiments you could...Ch. 12 - Make a graph of [A] versus time for zero-, first-,...Ch. 12 - How does temperature affect k, the rate constant?...Ch. 12 - Consider the following statements: In general, the...Ch. 12 - For the reaction A+BC, explain at least two ways...Ch. 12 - A friend of yours states, A balanced equation...Ch. 12 - Provide a conceptual rationale for the differences...Ch. 12 - The rate constant (k) depends on which of the...Ch. 12 - Table 11-2 illustrates how the average rate of a...Ch. 12 - The rate law for a reaction can be determined only...Ch. 12 - The plot below shows the number of collisions with...Ch. 12 - For the reaction O2(g)+2NO(g)2NO2(g) the observed...Ch. 12 - Each of the statements given below is false....Ch. 12 - Define what is meant by unimolecular and...Ch. 12 - The type of rate law for a reaction, either the...Ch. 12 - The initial rate of a reaction doubles as the...Ch. 12 - Hydrogen reacts explosively with oxygen. However,...Ch. 12 - The central idea of the collision model is that...Ch. 12 - Consider the following energy plots for a chemical...Ch. 12 - Prob. 21QCh. 12 - Prob. 22QCh. 12 - The combustion of carbohydrates and the combustion...Ch. 12 - Would the slope of a ln(k) versus 1/T plot (with...Ch. 12 - Consider the reaction 4PH3(g)P4(g)+6H2(g) If, in a...Ch. 12 - In the Haber process for the production of...Ch. 12 - At 40C, H2O2 (aq) will decompose according to the...Ch. 12 - Consider the general reaction aA+bBcC and the...Ch. 12 - What are the units for each of the following if...Ch. 12 - The rate law for the reaction...Ch. 12 - The reaction 2NO(g)+Cl2(g)2NOCl(g) was studied at...Ch. 12 - The reaction 2I-(aq)+S2O82-(aq)I2(aq)+2SO42-(aq)...Ch. 12 - The decomposition of nitrosyl chloride was...Ch. 12 - The following data were obtained for the gas-phase...Ch. 12 - The reaction I(aq)+OCl(aq)IO(aq)+Cl(aq) was...Ch. 12 - The reaction 2NO(g)+O2(g)2NO2(g) was studied. and...Ch. 12 - The rote of the reaction between hemoglobin (Hb)...Ch. 12 - The following data were obtained for the reaction...Ch. 12 - The decomposition of hydrogen peroxide was...Ch. 12 - A certain reaction has the following general form:...Ch. 12 - The rate of the reaction NO2(g)+CO(g)NO(g)+CO2(g)...Ch. 12 - A certain reaction has the following general form:...Ch. 12 - The decomposition of ethanol (C2H5OH) on an...Ch. 12 - At 500 K in the presence of a copper surface,...Ch. 12 - The dimerization of butadiene 2C4H6(g)C8H12(g) was...Ch. 12 - The rate of the reaction O(g)+NO2(g)NO(g)+O2(g)...Ch. 12 - Experimental data for the reaction A2B+C have been...Ch. 12 - Prob. 48ECh. 12 - The reaction AB+C is known to be zero order in A...Ch. 12 - The decomposition of hydrogen iodide on finely...Ch. 12 - Prob. 51ECh. 12 - A first-order reaction is 75.0% complete in 320....Ch. 12 - The rate law for the decomposition of phosphine...Ch. 12 - DDT (molar mass = 354.49 g/mol) was a widely used...Ch. 12 - The rate law for the reaction...Ch. 12 - Prob. 57ECh. 12 - Theophylline is a pharmaceutical drug that is...Ch. 12 - You and a coworker have developed a molecule...Ch. 12 - Consider the hypothetical reaction A+B+2C2D+3E...Ch. 12 - Write the rate laws for the following elementary...Ch. 12 - A possible mechanism for the decomposition of...Ch. 12 - A proposed mechanism for a reaction is...Ch. 12 - The mechanism for the gas-phase reaction of...Ch. 12 - Is the mechanism NO+Cl2l1NOCl2NOCl2+NOl22NOCl...Ch. 12 - The reaction 2NO(g) + O2(g) 2NO2(g) exhibits the...Ch. 12 - For the following reaction profile, indicate a....Ch. 12 - Draw a rough sketch of the energy profile for each...Ch. 12 - The activation energy for the reaction...Ch. 12 - The activation energy for some reaction...Ch. 12 - The rate constant for the gas-phase decomposition...Ch. 12 - The reaction (CH3)3CBr+OH(CH3)3COH+Br in a certain...Ch. 12 - The activation energy for the decomposition of...Ch. 12 - A first-order reaction has rate constants of 4.6 ...Ch. 12 - A certain reaction has an activation energy of...Ch. 12 - Prob. 76ECh. 12 - Which of the following reactions would you expect...Ch. 12 - Prob. 78ECh. 12 - One mechanism for the destruction of ozone in the...Ch. 12 - One of the concerns about the use of Freons is...Ch. 12 - Assuming that the mechanism for the hydrogenation...Ch. 12 - The decomposition of NH3 to N2 and H2 was studied...Ch. 12 - The decomposition of many substances on the...Ch. 12 - Prob. 84ECh. 12 - A popular chemical demonstration is the magic...Ch. 12 - Prob. 86ECh. 12 - Consider the following representation of the...Ch. 12 - The reaction H2SeO3(aq) + 6I-(aq) + 4H+(aq) Se(s)...Ch. 12 - Consider two reaction vessels, one containing A...Ch. 12 - Sulfuryl chloride (SO2Cl2) decomposes to sulfur...Ch. 12 - For the reaction 2N2O5(g)4NO2(g)+O2(g) the...Ch. 12 - Experimental values for the temperature dependence...Ch. 12 - At 620. K butadiene dimerizes at a moderate rate....Ch. 12 - For a first order gas phase reaction A products,...Ch. 12 - Cobra venom helps the snake secure food by binding...Ch. 12 - Iodomethane (CH3I) is a commonly used reagent in...Ch. 12 - Experiments during a recent summer on a number of...Ch. 12 - The activation energy of a certain uncatalyzed...Ch. 12 - Consider the following initial rate data for the...Ch. 12 - Consider a hypothetical reaction between A and B:...Ch. 12 - Consider the reaction 3A+B+CD+E where the rate law...Ch. 12 - The thiosulfate ion (S2O32) is oxidized by iodine...Ch. 12 - The reaction A(aq)+B(aq)products(aq) was studied,...Ch. 12 - A certain substance, initially present at 0.0800...Ch. 12 - A reaction of the form aAProducts gives a plot of...Ch. 12 - A certain reaction has the form aAProducts At a...Ch. 12 - Which of the following statement(s) is( are) true?...Ch. 12 - Consider the hypothetical reaction A2(g) + B2(g) ...Ch. 12 - Experiments have shown that the average frequency...Ch. 12 - Consider a reaction of the type aA products, in...Ch. 12 - A study was made of the effect of the hydroxide...Ch. 12 - Two isomers (A and B) of a given compound dimerize...Ch. 12 - The reaction NO(g)+O3NO2(g)+O2(g) was studied by...Ch. 12 - Prob. 114CPCh. 12 - In the gas phase, the production of phosgene from...Ch. 12 - Most reactions occur by a series of steps. The...Ch. 12 - You are studying the kinetics of the reaction...Ch. 12 - The decomposition of NO2(g) occurs by the...Ch. 12 - The following data were collected in two studies...Ch. 12 - Consider the following hypothetical data collected...Ch. 12 - Consider the hypothetical reaction A+B+2C2D+3E In...Ch. 12 - Hydrogen peroxide and the iodide ion react in...Ch. 12 - Sulfuryl chloride undergoes first-order...Ch. 12 - Upon dissolving InCl(s) in HCl, In+(aq) undergoes...Ch. 12 - The decomposition of iodoethane in the gas phase...Ch. 12 - Consider the following reaction: CH3X+YCH3Y+X At...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Aiter running various experiments, you determine that the mechanism for the following reaction is bimolecular. CI Using this information, draw the correct mechanism in the space below. X Explanation Check C Cl OH + CI Add/Remove step Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Carrow_forwardComplete the reaction in the fewest number of steps as possible, Draw all intermediates (In the same form as the picture provided) and provide all reagents.arrow_forwardPlease provide steps to work for complete understanding.arrow_forward
- Please provide steps to work for complete understanding.arrow_forwardIdentify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling.arrow_forwardIdentify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling.arrow_forward
- Identify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling.arrow_forwardIdentify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling.arrow_forwardA certain chemical reaction releases 24.7 kJ/g of heat for each gram of reactant consumed. How can you calculate what mass of reactant will produce 1460. J of heat? Set the math up. But don't do any of it. Just leave your answer as a math expression. Also, be sure your answer includes all the correct unit symbols. mass M 0.0 x μ 00 1 Garrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY