Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 12, Problem 91CWP
Interpretation Introduction
Interpretation: The equilibrium concentration
Concept introduction: The equilibrium constant
The equilibrium constant depends upon temperature.
Law of mass action is applicable on the equilibrium reactions.
The concentration of the species at equilibrium is known as equilibrium concentration.
To determine: The value of equilibrium concentration of
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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
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Chapter 12 Solutions
Chemistry: An Atoms First Approach
Ch. 12 - Characterize a system at chemical equilibrium with...Ch. 12 - What is the law of mass action? Is it true that...Ch. 12 - Prob. 3RQCh. 12 - Prob. 4RQCh. 12 - Prob. 5RQCh. 12 - Distinguish between the terms equilibrium constant...Ch. 12 - Summarize the steps for solving equilibrium...Ch. 12 - Prob. 8RQCh. 12 - What is Le Chteliers principle? Consider the...Ch. 12 - Prob. 10RQ
Ch. 12 - Consider an equilibrium mixture of four chemicals...Ch. 12 - The boxes shown below represent a set of initial...Ch. 12 - For the reactionH2(g)+I2(g)2HI(g), consider two...Ch. 12 - Prob. 4ALQCh. 12 - Consider the reaction A(g)+2B(g)C(g)+D(g) in a...Ch. 12 - Consider the reactionA(g)+B(g)C(g)+D(g). A friend...Ch. 12 - Prob. 7ALQCh. 12 - Prob. 8ALQCh. 12 - Prob. 9ALQCh. 12 - Prob. 10QCh. 12 - Consider the following reaction:...Ch. 12 - Prob. 12QCh. 12 - Suppose a reaction has the equilibrium constant K...Ch. 12 - Prob. 14QCh. 12 - Consider the following reaction at some...Ch. 12 - Prob. 16QCh. 12 - Prob. 17QCh. 12 - Prob. 18QCh. 12 - For a typical equilibrium problem, the value of K...Ch. 12 - Prob. 20QCh. 12 - Write the equilibrium expression (K) for each of...Ch. 12 - Write the equilibrium expression (Kp) for each...Ch. 12 - Prob. 23ECh. 12 - For the reaction H2(g)+Br2(g)2HBr(g) Kp = 3.5 104...Ch. 12 - Prob. 25ECh. 12 - At high temperatures, elemental nitrogen and...Ch. 12 - At a particular temperature, a 3.0-L flask...Ch. 12 - At a particular temperature a 2.00-L flask at...Ch. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Write expressions for Kp for the following...Ch. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - In a study of the reaction...Ch. 12 - The equilibrium constant is 0.0900 at 25C for the...Ch. 12 - The equilibrium constant is 0.0900 at 25C for the...Ch. 12 - At 900c, Kp = 1.04 for the reaction...Ch. 12 - Ethyl acetate is synthesized in a nonreacting...Ch. 12 - For the reaction 2H2O(g)2H2(g)+O2(g) K = 2.4 103...Ch. 12 - The reaction 2NO(g)+Br2(g)2NOBr(g) has Kp = 109 at...Ch. 12 - A 1.00-L flask was filled with 2.00 moles of...Ch. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Nitrogen gas (N2) reacts with hydrogen gas (H2) to...Ch. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - At 25c, K = 0.090 for the reaction...Ch. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - At o particular temperature, K = 4 .0 107 for the...Ch. 12 - Prob. 59ECh. 12 - Lexan is a plastic used to make compact discs,...Ch. 12 - At 25C, Kp. = 2.9 103 for the reaction...Ch. 12 - A sample of solid ammonium chloride was placed in...Ch. 12 - Prob. 63ECh. 12 - Predict the shift in the equilibrium position that...Ch. 12 - An important reaction in the commercial production...Ch. 12 - What will happen to the number of moles of SO3 in...Ch. 12 - Prob. 67ECh. 12 - Hydrogen for use in ammonia production is produced...Ch. 12 - Old-fashioned smelling salts consist of ammonium...Ch. 12 - Ammonia is produced by the Haber process, in which...Ch. 12 - Prob. 71AECh. 12 - Given the following equilibrium constants at...Ch. 12 - Consider the decomposition of the compound C5H6O3...Ch. 12 - Prob. 74AECh. 12 - The gas arsine, AsH3, decomposes as follows:...Ch. 12 - At a certain temperature, K = 9.1 10-4 for the...Ch. 12 - At a certain temperature, K = 1.1 l03 for the...Ch. 12 - Prob. 78AECh. 12 - At 25C, gaseous SO2Cl2 decomposes to SO2(g) and...Ch. 12 - For the following reaction at a certain...Ch. 12 - Prob. 81AECh. 12 - Consider the reaction Fe3+(aq)+SCN(aq)FeSCN2+(aq)...Ch. 12 - Chromium(VI) forms two different oxyanions, the...Ch. 12 - Prob. 84AECh. 12 - Prob. 85AECh. 12 - For the reaction below, Kp = 1.16 at 800C....Ch. 12 - Many sugars undergo a process called mutarotation,...Ch. 12 - Peptide decomposition is one of the key processes...Ch. 12 - The creation of shells by mollusk species is a...Ch. 12 - Methanol, a common laboratory solvent, poses a...Ch. 12 - Prob. 91CWPCh. 12 - Prob. 92CWPCh. 12 - Prob. 93CWPCh. 12 - Prob. 94CWPCh. 12 - Prob. 95CWPCh. 12 - Prob. 96CWPCh. 12 - Consider the following exothermic reaction at...Ch. 12 - For the following endothermic reaction at...Ch. 12 - Prob. 99CPCh. 12 - A 4.72-g sample of methanol (CH3OH) was placed in...Ch. 12 - At 35C, K = 1.6 105 for the reaction...Ch. 12 - Nitric oxide and bromine at initial partial...Ch. 12 - At 25C. Kp = 5.3 105 for the reaction...Ch. 12 - Prob. 104CPCh. 12 - The partial pressures of an equilibrium mixture of...Ch. 12 - At 125C, KP = 0.25 for the reaction...Ch. 12 - A mixture of N2, H2, and NH3 is at equilibrium...Ch. 12 - Prob. 108CPCh. 12 - Prob. 109CPCh. 12 - Prob. 110CPCh. 12 - Prob. 111CPCh. 12 - A sample of N2O4(g) is placed in an empty cylinder...Ch. 12 - A sample of gaseous nitrosyl bromide (NOBr) was...Ch. 12 - Prob. 114CPCh. 12 - For the reaction NH3(g)+H2S(g)NH4HS(s) K = 400. at...Ch. 12 - Prob. 116IPCh. 12 - In a solution with carbon tetrachloride as the...Ch. 12 - Prob. 118IPCh. 12 - A gaseous material XY(g) dissociates to some...
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