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(a)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium for the given reaction when
(b)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction.
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium for the given reaction when
(c)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction.
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium for the given reaction when
(d)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction.
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium for the given reaction when argon gas is added.
(e)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction.
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium for the given reaction when volume of reaction is doubled.
(f)
Interpretation: The reaction of decomposition of
Concept introduction: The state when the reactants involved in a chemical reaction and the products formed in the reaction exist in concentrations having no further tendency to change is known as an equilibrium state of the reaction.
According to Le Chatelier’s principle “When equilibrium is subjected to change in variable, the shift in the equilibrium is produced in the direction that nullifies the effect of change.”
To determine: The shift of equilibrium when temperature is decreased (exothermic reaction) for the given reaction.
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Chapter 12 Solutions
Chemistry: An Atoms First Approach
- Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br .OH Brarrow_forwardClassify each molecule as optically active or inactive. Determine the configuration at each H соон Chirality center OH 애 He OH H3C Ноос H H COOH A K B.arrow_forwardQ1: Rank the relative nucleophilicity of the following species in ethanol. CH3O¯, CH3OH, CH3COO, CH3COOH, CH3S Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forward10. The main product of the following reaction is [1.1:4',1"-terphenyl]-2'-yl(1h-pyrazol-4- yl)methanone Ph N-H Pharrow_forwardDraw the Fischer projection for a D-aldo-pentose. (aldehyde pentose). How many total stereoisomers are there? Name the sugar you drew. Draw the Fischer projection for a L-keto-hexose. (ketone pentose). How many total stereoisomers are there? Draw the enantiomer.arrow_forward
- Draw a structure using wedges and dashes for the following compound: H- Et OH HO- H H- Me OHarrow_forwardWhich of the following molecules are NOT typical carbohydrates? For the molecules that are carbohydrates, label them as an aldose or ketose. HO Он ОН ОН Он ОН но ΤΗ HO ОН HO eve Он он ОН ОН ОН If polyethylene has an average molecular weight of 25,000 g/mol, how many repeat units are present?arrow_forwardDraw the a-anomer cyclized pyranose Haworth projection of the below hexose. Circle the anomeric carbons. Number the carbons on the Fischer and Haworth projections. Assign R and S for each chiral center. HO CHO -H HO -H H- -OH H -OH CH₂OH Draw the ẞ-anomer cyclized furanose Haworth projection for the below hexose. Circle the anomeric carbons. Number the carbons on the Fischer and Haworth projections. HO CHO -H H -OH HO -H H -OH CH₂OHarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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