Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 12, Problem 85E
Based on the diagram in Exercise 12.83, which of the reactions has the fastest rate? Which has the slowest rate?
Expert Solution & Answer
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Draw the structure of the product of the reaction given the IR and MS data.
Spectral analysis of the product reveals:
MS: M 150, M-15, M-43
CH.COCI
AICI,
IR: 3150-3000 cm, 2950-2850 cm
and 1700 cm
Part II. Identify whether the two protons in blue are homotopic, enantiopic, diasteriotopic, or heterotopic.
a)
HO
b)
Bri
H
HH
c)
d)
H
H H Br
0
None
Chapter 12 Solutions
Chemistry (OER)
Ch. 12 - What is the difference between average rate,...Ch. 12 - Ozone decomposes to oxygen according to the...Ch. 12 - In the nuclear industry, chlorine trifluoride is...Ch. 12 - A study of the rate of dimerization of C4H6 gave...Ch. 12 - A study of the rate of the reaction represented as...Ch. 12 - Consider the following reaction in aqueous...Ch. 12 - Describe the effect of each of the following on...Ch. 12 - Explain why an egg cooks move slowly in boiling...Ch. 12 - Go to the PhET Reactions and change to Angled...Ch. 12 - In the PhET Reactions tab to observe how multiple...
Ch. 12 - In the PhET Reactions under Options. (a) Leave...Ch. 12 - How do the rate of a reaction and its rate...Ch. 12 - Doubling the concentration of a reactant increases...Ch. 12 - Tripling the concentration of a reactant increases...Ch. 12 - How much and in what direction will each of the...Ch. 12 - How will each of the following affect the rate of...Ch. 12 - Regular ?ights of supersonic aircraft in the...Ch. 12 - Radioactive phosphorus is used in the study of...Ch. 12 - The rate constant for the radioactive decay of 14C...Ch. 12 - The decomposition of acetaldehyde is a second...Ch. 12 - Alcohol is removed from the bloodstream by a...Ch. 12 - Under certain conditions the decomposition of...Ch. 12 - Nitrosyl chloride, NOCI, decomposes to NO and CI2....Ch. 12 - From the following data, determine the rate...Ch. 12 - Nitrogen monoxide reacts with chlorine according...Ch. 12 - Hydrogen reacts with nitrogen monoxide to form...Ch. 12 - For the reaction AB+C, the following data were...Ch. 12 - For the reaction QW+X, the following data were...Ch. 12 - The rate constant for the ?rst-order decomposition...Ch. 12 - The annual production of HNO3 in 2013 was 60...Ch. 12 - The following data have been determined for the...Ch. 12 - Describe how graphical methods can be used to...Ch. 12 - Use the data provided to graphically determine the...Ch. 12 - Use the data provided in a graphical method to...Ch. 12 - Pure ozone decomposes slowly to oxygen, 2O33O2(g)....Ch. 12 - From the given data, use a graphical method to...Ch. 12 - What is the half-life for the first-order decay of...Ch. 12 - What is the half-life for the first-order decay of...Ch. 12 - What is the half-life for the decomposition of...Ch. 12 - What is the half-life for the decomposition of O3...Ch. 12 - The reaction of compound A to give compounds C and...Ch. 12 - The half-life of a reaction of compound A to give...Ch. 12 - Some bacteria are resistant to the antibiotic...Ch. 12 - Both technetium-99 and thallium-201 are used to...Ch. 12 - There are two molecules with the formula C3H6...Ch. 12 - Fluorine-18 is a radioactive isotope that decays...Ch. 12 - Suppose that the half-life of steroids taken by an...Ch. 12 - Recently, the skeleton of King Richard III was...Ch. 12 - Nitroglycerine is an extremely sensitive...Ch. 12 - For the past 10 years, the unsaturated hydrocarbon...Ch. 12 - Chemical reactions occur when reactants collide....Ch. 12 - When every collision between reactants leads to a...Ch. 12 - What is the activation energy of a reaction, and...Ch. 12 - Account for the relationship between the rate of a...Ch. 12 - Describe how graphical methods can be used to...Ch. 12 - How does an increase in temperature affect rate of...Ch. 12 - The rate of a certain reaction doubles for every...Ch. 12 - In an experiment, a sample of NaClO3 was 90%...Ch. 12 - The rate constant at 325 C for the decomposition...Ch. 12 - The rate constant for the decomposition of...Ch. 12 - An elevated level of the enzyme alkaline...Ch. 12 - In terms of collision theory, to which of the...Ch. 12 - Hydrogen iodide, HI, decomposes in the gas phase...Ch. 12 - The element Co exists in two oxidation states,...Ch. 12 - The hydrolysis of the sugar sucrose to the sugars...Ch. 12 - Use the PhET Reactions Single collision" tab of...Ch. 12 - Use the PhET Reactions Single collision tab of the...Ch. 12 - Why awe elementary reactions involving three or...Ch. 12 - In general, can we predict the effect of doubling...Ch. 12 - Define these terms: (a) unimolecular reaction (b)...Ch. 12 - What is the rate equation for the elementary...Ch. 12 - Given the following reactions and the...Ch. 12 - Write the rate equation for each of the following...Ch. 12 - Nitrogen (Il) oxide, NO, reacts with hydrogen, H2,...Ch. 12 - Experiments were conducted to study the rate of...Ch. 12 - The reaction of CO with CI2 gives phosgene...Ch. 12 - . Account for the increase in reaction rate...Ch. 12 - Compare the functions of homogeneous and...Ch. 12 - Consider this scenario and answer the following...Ch. 12 - For each of the following pairs of reaction...Ch. 12 - For each of the following pairs of reaction...Ch. 12 - For each of the following reaction diagrams,...Ch. 12 - For each of the following reaction diagrams,...Ch. 12 - Based on the diagrams in Exercise 12.83, which of...Ch. 12 - Based on the diagram in Exercise 12.83, which of...
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