EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM
8th Edition
ISBN: 9780134554433
Author: CORWIN
Publisher: PEARSON CO
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Chapter 12, Problem 36E
Interpretation Introduction

(a)

Interpretation:

The electron dot formula and structural formula for HOCl molecule, is to be stated.

Concept introduction:

The electron dot formula shows the valence electrons which form the bond between the atoms in a molecule. The electron pairs that are shared by the atoms are known as bonding electrons. The other electrons that are present in order to complete the octet are known as non-bonding electrons. The electron dot formula is also known as the Lewis structure.

Expert Solution
Check Mark

Answer to Problem 36E

The electron dot formula for HOCl molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  1

The structural formula for HOCl molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  2

Explanation of Solution

The total number of valence electron in HOCl molecule is the sum of valence electron of one oxygen atom, one chlorine atom and one hydrogen atom. The number of valence electron in each oxygen atom is six. The number of valence electron in each chlorine atom is seven. The number of valence electron in each hydrogen atom is one. Therefore, the total number of valence electron in HOCl molecule is calculated as shown below.

Totalnumberofvalenceelectron=(1+6+7)e=14e

Therefore, the number of electron pair is seven (14/2=7). The electron dot formula for HOCl molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  3

Figure 1

Out of seven electron pairs, two electron pairs are involved in bonding. Therefore, there is five lone pair. The structural formula for HOCl molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  4

Figure 2

Conclusion

The electron dot formula for HOCl molecule is shown in figure 1.

The structural formula for HOCl molecule is shown in figure 2.

Interpretation Introduction

(b)

Interpretation:

The electron dot formula and structural formula for SO2 molecule, is to be stated.

Concept introduction:

The electron dot formula shows the valence electrons which form the bond between the atoms in a molecule. The electron pairs that are shared by the atoms are known as bonding electrons. The other electrons that are present in order to complete the octet are known as non-bonding electrons. The electron dot formula is also known as the Lewis structure.

Expert Solution
Check Mark

Answer to Problem 36E

The electron dot formula for SO2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  5

The structural formula for SO2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  6

Explanation of Solution

The total number of valence electron in SO2 molecule is the sum of valence electron of one sulfurs atom and two oxygen atoms. The number of valence electron in each sulfur atom is six. The number of valence electron in each oxygen atom is six. Therefore, the total number of valence electron in SO2 molecule is calculated as shown below.

Totalnumberofvalenceelectron=(6+(2×6))e=(6+12)e=18e

Therefore, the number of electron pair is nine (18/2=9). The electron dot formula for SO2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  7

Figure 3

Out of nine electron pairs, only four electron pairs are involved in bonding. Therefore, there is five lone pair. The structural formula for SO2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  8

Figure 4

Conclusion

The electron dot formula for SO2 molecule is shown in Figure 3.

The structural formula for SO2 molecule is shown in Figure 4.

Interpretation Introduction

(c)

Interpretation:

The electron dot formula and structural formula for CS2 molecule, is to be stated.

Concept introduction:

The electron dot formula shows the valence electrons which form the bond between the atoms in a molecule. The electron pairs that are shared by the atoms are known as bonding electrons. The other electrons that are present in order to complete the octet are known as non-bonding electrons. The electron dot formula is also known as the Lewis structure.

Expert Solution
Check Mark

Answer to Problem 36E

The electron dot formula for CS2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  9

The structural formula for CS2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  10

Explanation of Solution

The total number of valence electron in CS2 molecule is the sum of valence electron of one carbon atom and two sulfur atoms. The number of valence electron in each carbon atom is four. The number of valence electron in each sulfur atom is six. Therefore, the total number of valence electron in CS2 molecule is calculated as shown below.

Totalnumberofvalenceelectron=(4+(2×6))e=(4+12)e=16e

Therefore, the number of electron pair is eight (16/2=8). The electron dot formula for CS2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  11

Figure 5

Out of eight electron pairs, four electron pairs are involved in bonding. Therefore, there is four lone pair. The structural formula for CS2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  12

Figure 6

Conclusion

The electron dot formula for CS2 molecule is shown in Figure 5.

The structural formula for CS2 molecule is shown in Figure 6.

Interpretation Introduction

(d)

Interpretation:

The electron dot formula and structural formula for C2H2 molecule, is to be stated.

Concept introduction:

The electron dot formula shows the valence electrons which form the bond between the atoms in a molecule. The electron pairs that are shared by the atoms are known as bonding electrons. The other electrons that are present in order to complete the octet are known as non-bonding electrons. The electron dot formula is also known as the Lewis structure.

Expert Solution
Check Mark

Answer to Problem 36E

The electron dot formula for C2H2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  13

The structural formula for C2H2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  14

Explanation of Solution

The total number of valence electron in C2H2 molecule is the sum of valence electron of two carbon atom and two hydrogen atoms. The number of valence electron in each carbon atom is four. The number of valence electron in each hydrogen atom is one. Therefore, the total number of valence electron in C2H2 molecule is calculated as shown below.

Totalnumberofvalenceelectron=((2×4)+(2×1))e=(8+2)e=10e

Therefore, the number of electron pair is five (10/2=5). The electron dot formula for C2H2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  15

Figure 7

All electron pair is involved in bonding. Therefore, there is no lone pair. The structural formula for C2H2 molecule is shown below.

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM, Chapter 12, Problem 36E , additional homework tip  16

Figure 8

Conclusion

The electron dot formula for C2H2 molecule is shown in Figure 7.

The structural formula for C2H2 molecule is shown in Figure 8.

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Chapter 12 Solutions

EP INTRODUCTORY CHEM.-MOD.MASTERINGCHEM

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