(a) Interpretation: Whether the sum of H and Br atomic radii, or the bond length in H − Br is less is to be predicted. Concept introduction: Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

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Answer 1

Question

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

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Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 band

Answer 2

Question

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

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Answer 3

Question

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

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Answer 4

Question

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

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Answer 5

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Answer 6

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Answer 7

Chapter 12, Problem 30E

Interpretation Introduction

(a)

Interpretation:

Whether the sum of H and Br atomic radii, or the bond length in H−Br is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the sum of S and O atomic radii, or the bond length in S=O is less is to be predicted.

Concept introduction:

Covalent bond is formed by the sharing of electrons between the two non metal atoms. The difference between the two nuclei of different atom is known as bond length. The energy is released when two atoms form a covalent bond.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12 - Prob. 1CE Ch. 12 - Prob. 2CE Ch. 12 - Prob. 3CE Ch. 12 - Prob. 4CE Ch. 12 - Prob. 5CE Ch. 12 - Prob. 6CE Ch. 12 - Prob. 7CE Ch. 12 - Prob. 8CE Ch. 12 - Prob. 9CE Ch. 12 - Prob. 10CE

Solution Summary: The author explains that the bond length in H- Br is less than the sum of

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