General, Organic, and Biological Chemistry (3rd Edition)
General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Chapter 12, Problem 2IA.3Q
Summary Introduction

To determine:

The total number of ATP produced by one glucose (two Acetyl CoA) going through the citric acid cycle.

Introduction:

The series of metabolic reactions, in which the energy stored in the compounds is released for the production of ATP(adenosine triphosphate), is called “Krebs’s cycle”. The pyruvate undergoes series of reactions in the citric acid cycle and converts into Acetyl CoA(acetyl coenzyme A) in the presence of oxygen.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
Could you redraw these and also explain how to solve them for me pleas

Chapter 12 Solutions

General, Organic, and Biological Chemistry (3rd Edition)

Ch. 12 - Prob. 12.11PPCh. 12 - Prob. 12.12PPCh. 12 - Name a carbohydrate (if any) that undergoes...Ch. 12 - Prob. 12.14PPCh. 12 - Prob. 12.15PPCh. 12 - Prob. 12.16PPCh. 12 - Prob. 12.17PPCh. 12 - Prob. 12.18PPCh. 12 - Prob. 12.19PPCh. 12 - Prob. 12.20PPCh. 12 - Prob. 12.21PPCh. 12 - Prob. 12.22PPCh. 12 - Prob. 12.23PPCh. 12 - Prob. 12.24PPCh. 12 - Prob. 12.25PPCh. 12 - Prob. 12.26PPCh. 12 - Prob. 12.27PPCh. 12 - Prob. 12.28PPCh. 12 - Prob. 12.29PPCh. 12 - Prob. 12.30PPCh. 12 - Prob. 12.31PPCh. 12 - Prob. 12.32PPCh. 12 - Prob. 12.33PPCh. 12 - Prob. 12.34PPCh. 12 - Prob. 12.35PPCh. 12 - Prob. 12.36PPCh. 12 - Prob. 12.37PPCh. 12 - Prob. 12.38PPCh. 12 - Prob. 12.39PPCh. 12 - Prob. 12.40PPCh. 12 - Prob. 12.41PPCh. 12 - Prob. 12.42PPCh. 12 - Prob. 12.43PPCh. 12 - Prob. 12.44PPCh. 12 - Prob. 12.45PPCh. 12 - Prob. 12.46PPCh. 12 - Prob. 12.47PPCh. 12 - Prob. 12.48PPCh. 12 - Prob. 12.49PPCh. 12 - Prob. 12.50PPCh. 12 - Prob. 12.51PPCh. 12 - Arachidic acid is a saturated C20 fatty acid. a....Ch. 12 - Prob. 12.53PPCh. 12 - Prob. 12.54PPCh. 12 - Prob. 12.55PPCh. 12 - Prob. 12.56PPCh. 12 - Prob. 12.57PPCh. 12 - Prob. 12.58PPCh. 12 - Prob. 12.59APCh. 12 - Prob. 12.60APCh. 12 - Prob. 12.61APCh. 12 - Prob. 12.62APCh. 12 - Identify the type of foodcarbohydrate, fat, or...Ch. 12 - Prob. 12.64APCh. 12 - Prob. 12.65APCh. 12 - Prob. 12.66APCh. 12 - Prob. 12.67APCh. 12 - Prob. 12.68APCh. 12 - Prob. 12.69APCh. 12 - Prob. 12.70APCh. 12 - Prob. 12.71APCh. 12 - Prob. 12.72APCh. 12 - Prob. 12.73APCh. 12 - Prob. 12.74APCh. 12 - Prob. 12.75APCh. 12 - Prob. 12.76APCh. 12 - Prob. 12.77APCh. 12 - Prob. 12.78APCh. 12 - Prob. 12.79APCh. 12 - Prob. 12.80APCh. 12 - Prob. 12.81APCh. 12 - Prob. 12.82APCh. 12 - Prob. 12.83APCh. 12 - Prob. 12.84APCh. 12 - Prob. 12.85APCh. 12 - Prob. 12.86APCh. 12 - Prob. 12.87APCh. 12 - Prob. 12.88APCh. 12 - Prob. 12.89CPCh. 12 - Prob. 12.90CPCh. 12 - Laurie acid, a saturated Cl2 fatty acid, is found...Ch. 12 - A person is brought to the emergency room in what...Ch. 12 - Prob. 12.93CPCh. 12 - Prob. 12.94CPCh. 12 - Prob. 1IA.1QCh. 12 - Prob. 1IA.2QCh. 12 - Prob. 1IA.3QCh. 12 - Prob. 1IA.4QCh. 12 - Prob. 1IA.5QCh. 12 - Prob. 1IA.6QCh. 12 - Prob. 1IA.7QCh. 12 - Prob. 1IA.8QCh. 12 - Prob. 2IA.1QCh. 12 - Prob. 2IA.2QCh. 12 - Prob. 2IA.3QCh. 12 - Prob. 2IA.4QCh. 12 - Prob. 3IA.1QCh. 12 - Prob. 3IA.2QCh. 12 - Prob. 3IA.3QCh. 12 - Prob. 3IA.4QCh. 12 - Prob. 3IA.5QCh. 12 - Prob. 1ICCh. 12 - Prob. 2ICCh. 12 - Prob. 3IC
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