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General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Question
Chapter 12, Problem 2IA.3Q
Summary Introduction
To determine:
The total number of ATP produced by one glucose (two Acetyl CoA) going through the citric acid cycle.
Introduction:
The series of
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Students have asked these similar questions
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 12 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 12 - Prob. 12.1PPCh. 12 - How can you identify an anabolic reaction?Ch. 12 - Prob. 12.3PPCh. 12 - Prob. 12.4PPCh. 12 - Prob. 12.5PPCh. 12 - Prob. 12.6PPCh. 12 - Prob. 12.7PPCh. 12 - Prob. 12.8PPCh. 12 - Prob. 12.9PPCh. 12 - Prob. 12.10PP
Ch. 12 - Prob. 12.11PPCh. 12 - Prob. 12.12PPCh. 12 - Name a carbohydrate (if any) that undergoes...Ch. 12 - Prob. 12.14PPCh. 12 - Prob. 12.15PPCh. 12 - Prob. 12.16PPCh. 12 - Prob. 12.17PPCh. 12 - Prob. 12.18PPCh. 12 - Prob. 12.19PPCh. 12 - Prob. 12.20PPCh. 12 - Prob. 12.21PPCh. 12 - Prob. 12.22PPCh. 12 - Prob. 12.23PPCh. 12 - Prob. 12.24PPCh. 12 - Prob. 12.25PPCh. 12 - Prob. 12.26PPCh. 12 - Prob. 12.27PPCh. 12 - Prob. 12.28PPCh. 12 - Prob. 12.29PPCh. 12 - Prob. 12.30PPCh. 12 - Prob. 12.31PPCh. 12 - Prob. 12.32PPCh. 12 - Prob. 12.33PPCh. 12 - Prob. 12.34PPCh. 12 - Prob. 12.35PPCh. 12 - Prob. 12.36PPCh. 12 - Prob. 12.37PPCh. 12 - Prob. 12.38PPCh. 12 - Prob. 12.39PPCh. 12 - Prob. 12.40PPCh. 12 - Prob. 12.41PPCh. 12 - Prob. 12.42PPCh. 12 - Prob. 12.43PPCh. 12 - Prob. 12.44PPCh. 12 - Prob. 12.45PPCh. 12 - Prob. 12.46PPCh. 12 - Prob. 12.47PPCh. 12 - Prob. 12.48PPCh. 12 - Prob. 12.49PPCh. 12 - Prob. 12.50PPCh. 12 - Prob. 12.51PPCh. 12 - Arachidic acid is a saturated C20 fatty acid. a....Ch. 12 - Prob. 12.53PPCh. 12 - Prob. 12.54PPCh. 12 - Prob. 12.55PPCh. 12 - Prob. 12.56PPCh. 12 - Prob. 12.57PPCh. 12 - Prob. 12.58PPCh. 12 - Prob. 12.59APCh. 12 - Prob. 12.60APCh. 12 - Prob. 12.61APCh. 12 - Prob. 12.62APCh. 12 - Identify the type of foodcarbohydrate, fat, or...Ch. 12 - Prob. 12.64APCh. 12 - Prob. 12.65APCh. 12 - Prob. 12.66APCh. 12 - Prob. 12.67APCh. 12 - Prob. 12.68APCh. 12 - Prob. 12.69APCh. 12 - Prob. 12.70APCh. 12 - Prob. 12.71APCh. 12 - Prob. 12.72APCh. 12 - Prob. 12.73APCh. 12 - Prob. 12.74APCh. 12 - Prob. 12.75APCh. 12 - Prob. 12.76APCh. 12 - Prob. 12.77APCh. 12 - Prob. 12.78APCh. 12 - Prob. 12.79APCh. 12 - Prob. 12.80APCh. 12 - Prob. 12.81APCh. 12 - Prob. 12.82APCh. 12 - Prob. 12.83APCh. 12 - Prob. 12.84APCh. 12 - Prob. 12.85APCh. 12 - Prob. 12.86APCh. 12 - Prob. 12.87APCh. 12 - Prob. 12.88APCh. 12 - Prob. 12.89CPCh. 12 - Prob. 12.90CPCh. 12 - Laurie acid, a saturated Cl2 fatty acid, is found...Ch. 12 - A person is brought to the emergency room in what...Ch. 12 - Prob. 12.93CPCh. 12 - Prob. 12.94CPCh. 12 - Prob. 1IA.1QCh. 12 - Prob. 1IA.2QCh. 12 - Prob. 1IA.3QCh. 12 - Prob. 1IA.4QCh. 12 - Prob. 1IA.5QCh. 12 - Prob. 1IA.6QCh. 12 - Prob. 1IA.7QCh. 12 - Prob. 1IA.8QCh. 12 - Prob. 2IA.1QCh. 12 - Prob. 2IA.2QCh. 12 - Prob. 2IA.3QCh. 12 - Prob. 2IA.4QCh. 12 - Prob. 3IA.1QCh. 12 - Prob. 3IA.2QCh. 12 - Prob. 3IA.3QCh. 12 - Prob. 3IA.4QCh. 12 - Prob. 3IA.5QCh. 12 - Prob. 1ICCh. 12 - Prob. 2ICCh. 12 - Prob. 3IC
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