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OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
8th Edition
ISBN: 9781305079311
Author: William L. Masterton; Cecile N. Hurley
Publisher: Cengage Learning US
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Textbook Question
Chapter 12, Problem 23QAP
Ammonium carbamate solid (NH4CO2NH2) decomposes at 313 K into ammonia and carbon dioxide gases. At equilibrium, analysis shows that there are 0.0451 atm of CO2, 0.0961 atm of ammonia, and 0.159 g of ammonium carbamate.
(a) Write a balanced equation for the decomposition of one mole of NH4CO2NH2.
(b) Calculate K at 313 K.
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 12 Solutions
OWLv2 for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 1 term (6 months)
Ch. 12 - The following data are for the system A(g)2B(g)...Ch. 12 - The following data are for the system A(g)2B(g)...Ch. 12 - Prob. 3QAPCh. 12 - Complete the table below for the reaction...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Write the equilibrium expressions (K) for the...Ch. 12 - Given the following descriptions of reversible...Ch. 12 - Given the following descriptions of reversible...
Ch. 12 - Write an equation for an equilibrium system that...Ch. 12 - Write a chemical equation for an equilibrium...Ch. 12 - Consider the following reaction at 250C:...Ch. 12 - Consider the following reaction at 1000 C:...Ch. 12 - At 627C, K=0.76 for the reaction...Ch. 12 - At 800C, K=2.2104 for the following reaction...Ch. 12 - Prob. 17QAPCh. 12 - Given the following data at 25C...Ch. 12 - Given the following data at a certain temperature,...Ch. 12 - Consider the following hypothetical reactions and...Ch. 12 - When one mole of carbon disulfide gas reacts with...Ch. 12 - Calculate K for the formation of methyl alcohol at...Ch. 12 - Ammonium carbamate solid (NH4CO2NH2) decomposes at...Ch. 12 - Consider the decomposition at 25C of one mole of...Ch. 12 - Consider the decomposition of ammonium hydrogen...Ch. 12 - A sealed flask has 0.541 atm of SO3 at 1000 K. The...Ch. 12 - A gaseous reaction mixture contains 0.30 atm SO2,...Ch. 12 - For the system PCl5(g)PCl3(g)+Cl2(g)K is 26 at...Ch. 12 - The reversible reaction between hydrogen chloride...Ch. 12 - The reversible reaction between hydrogen chloride...Ch. 12 - A compound, X, decomposes at 131C according to the...Ch. 12 - Consider the following reaction at 75C:...Ch. 12 - Consider the reaction between nitrogen and steam:...Ch. 12 - At 500C, k for the for the formation of ammonia...Ch. 12 - At a certain temperature, K is 4.9 for the...Ch. 12 - At a certain temperature, K=0.29 for the...Ch. 12 - For the reaction N2(g)+2H2O(g)2NO(g)+2H2(g) K is...Ch. 12 - Nitrogen dioxide can decompose to nitrogen oxide...Ch. 12 - Consider the following reaction:...Ch. 12 - Consider the hypothetical reaction at 325C...Ch. 12 - At a certain temperature, the equilibrium constant...Ch. 12 - At 460C, the reaction SO2(g)+NO2(g)NO(g)+SO3(g)...Ch. 12 - Solid ammonium iodide decomposes to ammonia and...Ch. 12 - Consider the following decomposition at 80C....Ch. 12 - Hydrogen cyanide, a highly toxic gas, can...Ch. 12 - At 800 K, hydrogen iodide can decompose into...Ch. 12 - For the following reactions, predict whether the...Ch. 12 - Follow the directions of Question 47 for the...Ch. 12 - Consider the system SO3(g)SO2(g)+12 O2(g)H=98.9kJ...Ch. 12 - Consider the system...Ch. 12 - Predict the direction in which each of the...Ch. 12 - Predict the direction in which each of the...Ch. 12 - At a certain temperature, nitrogen and oxygen...Ch. 12 - Consider the following hypothetical reaction:...Ch. 12 - Iodine chloride decomposes at high temperatures to...Ch. 12 - Sulfur oxychloride, SO2Cl2, decomposes to sulfur...Ch. 12 - For the following reaction C(s)+2H2(g)CH4(g)...Ch. 12 - For the system 2SO3(g)2SO2(g)+O2(g) K=1.32 at 627....Ch. 12 - For a certain reaction, H is +33 kJ. What is the...Ch. 12 - Prob. 60QAPCh. 12 - Hemoglobin (Hb) binds to both oxygen and carbon...Ch. 12 - Mustard gas, used in chemical warfare in World War...Ch. 12 - Prob. 63QAPCh. 12 - For the decomposition of CaCO3 at 900C, K=1.04....Ch. 12 - Isopropyl alcohol is the main ingredient in...Ch. 12 - Consider the equilibrium H2(g)+S(s)H2S(g)When this...Ch. 12 - Prob. 67QAPCh. 12 - The following data apply to the unbalanced...Ch. 12 - Consider the reaction: A(g)+2B(g)+C(s)2D(g)At 25C,...Ch. 12 - For the reaction C(s)+CO2(g)2CO(g) K=168 at 1273...Ch. 12 - Consider the system A(g)+2B(g)+C(g)2D(g)at 25C. At...Ch. 12 - The graph below is similar to that of Figure 12.2....Ch. 12 - Prob. 73QAPCh. 12 - The figures below represent the following reaction...Ch. 12 - Prob. 75QAPCh. 12 - Prob. 76QAPCh. 12 - Consider the following reaction at a certain...Ch. 12 - Prob. 78QAPCh. 12 - Ammonia can decompose into its constituent...Ch. 12 - Hydrogen iodide gas decomposes to hydrogen gas and...Ch. 12 - For the system SO3(g)SO2(g)+12 O2(g)at 1000 K,...Ch. 12 - A student studies the equilibrium I2(g)2I(g)at a...Ch. 12 - At a certain temperature, the reaction...Ch. 12 - Benzaldehyde, a flavoring agent, is obtained by...Ch. 12 - Prob. 85QAPCh. 12 - Prob. 86QAP
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