Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 15PS
To melt an ionic solid, energy must be supplied to disrupt the forces between ions so the regular array of ions collapses. Predict (and explain) how the melting point is expected to vary as a function of the distance between cation and anion.
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Chapter 12 Solutions
Chemistry & Chemical Reactivity
Ch. 12.1 - (a) Determining an Atom Radius from Lattice...Ch. 12.2 - If an ionic solid has an fcc lattice of anions (X)...Ch. 12.2 - Potassium chloride has the same unit cell as NaCl....Ch. 12.6 - Prob. 1.1ACPCh. 12.6 - Describe the unit cell of lithium (see Figure).Ch. 12.6 - Prob. 1.3ACPCh. 12.6 - Prob. 1.4ACPCh. 12.6 - Prob. 2.1ACPCh. 12.6 - Prob. 2.2ACPCh. 12.6 - Prob. 2.3ACP
Ch. 12.6 - How many tin atoms are contained in the tetragonal...Ch. 12.6 - Prob. 3.2ACPCh. 12.6 - Prob. 3.3ACPCh. 12.6 - Prob. 3.4ACPCh. 12 - Outline a two-dimensional unit cell for the...Ch. 12 - Outline a two-dimensional unit cell for the...Ch. 12 - A portion of the crystalline lattice for potassium...Ch. 12 - The unit cell of silicon carbide, SiC, is...Ch. 12 - Prob. 5PSCh. 12 - Rutile, TiO2, crystallizes in a structure...Ch. 12 - Cuprite is a semiconductor. Oxide ions are at the...Ch. 12 - The mineral fluorite, which is composed of calcium...Ch. 12 - Calcium metal crystallizes in a face-centered...Ch. 12 - The density of copper metal is 8.95 g/cm3. If the...Ch. 12 - Potassium iodide has a face-centered cubic unit...Ch. 12 - A unit cell of cesium chloride is illustrated in...Ch. 12 - Predict the trend in lattice energy, from least...Ch. 12 - Prob. 14PSCh. 12 - To melt an ionic solid, energy must be supplied to...Ch. 12 - Which compound in each of the following pairs...Ch. 12 - Prob. 17PSCh. 12 - Prob. 18PSCh. 12 - Considering only the molecular orbitals formed by...Ch. 12 - Prob. 20PSCh. 12 - Prob. 21PSCh. 12 - Prob. 22PSCh. 12 - Prob. 23PSCh. 12 - Prob. 24PSCh. 12 - Prob. 25PSCh. 12 - Prob. 26PSCh. 12 - Prob. 27PSCh. 12 - Prob. 28PSCh. 12 - A diamond unit cell is shown here. Unit cell of...Ch. 12 - The structure of graphite is given in Figure...Ch. 12 - We have identified six types of solids (metallic,...Ch. 12 - Prob. 32PSCh. 12 - Classify each of the following materials as...Ch. 12 - Prob. 34PSCh. 12 - Benzene, C6H6, is an organic liquid that freezes...Ch. 12 - The specific heat capacity of silver is 0.235 J/g ...Ch. 12 - Prob. 37PSCh. 12 - Prob. 38PSCh. 12 - Prob. 39PSCh. 12 - If your air conditioner is more than several years...Ch. 12 - Sketch a phase diagram for O2 from the following...Ch. 12 - Tungsten crystallizes in the unit cell shown here....Ch. 12 - Silver crystallizes in a face-centered cubic unit...Ch. 12 - The unit cell shown here is for calcium carbide....Ch. 12 - The very dense metal iridium has a face-centered...Ch. 12 - Vanadium metal has a density of 6.11 g/cm3....Ch. 12 - Prob. 47GQCh. 12 - Prob. 48GQCh. 12 - Prob. 49GQCh. 12 - Consider the three types of cubic units cells. (a)...Ch. 12 - The solid-state structure of silicon is shown...Ch. 12 - The solid-state structure of silicon carbide is...Ch. 12 - Spinels are solids with the general formula AB2O4...Ch. 12 - Using the thermochemical data below and an...Ch. 12 - Prob. 55GQCh. 12 - Prob. 56GQCh. 12 - Prob. 57GQCh. 12 - Prob. 58GQCh. 12 - Prob. 59GQCh. 12 - Prob. 60GQCh. 12 - Like ZnS, lead(II) sulfide, PbS (commonly called...Ch. 12 - CaTiO3, a perovskite, has the structure below. (a)...Ch. 12 - Potassium bromide has the same lattice structure...Ch. 12 - Calculate the lattice energy of CaCl2 using a...Ch. 12 - Why is it not possible for a salt with the formula...Ch. 12 - Prob. 67SCQCh. 12 - Prob. 68SCQCh. 12 - Prob. 69SCQCh. 12 - Phase diagrams for materials that have allotropes...
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- A mixture of three compounds Phen-A, Acet-B and Rin-C was analyzed using TLC with 1:9 ethanol: hexane as the mobile phase. The TLC plate showed three spots of R, 0.1 and 0.2 and 0.3. Which of the three compounds (Phen-A; Acet-B or Rin-C) would have the highest (Blank 1), middle (Blank 2) and lowest (Blank 3) spot respectively? 0 CH: 0 CH, 0 H.C OH H.CN OH Acet-B Rin-C phen-A A A <arrow_forwardHow many chiral carbons are in the molecule? Farrow_forwardcan someone give the curly arrow mechanism for this reaction written with every intermediate and all the side products pleasearrow_forward
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