The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated. Concept Introduction: The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom. A photon always moves with a speed of light that is equal to 3 × 10 8 m/s .
The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated. Concept Introduction: The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom. A photon always moves with a speed of light that is equal to 3 × 10 8 m/s .
Solution Summary: The author explains the meaning of an atom in an excited state and in its ground state. The relation between the wavelength of light and the energy of the photons is to be stated.
The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated.
Concept Introduction:
The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom.
A photon always moves with a speed of light that is equal to 3×108m/s.
A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
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