For the below compound, Fischer projection formula has to be drawn. Concept introduction: Fischer projections: In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

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Answer 1

Question

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?

Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.

a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here? b. What is the purpose of the Na2SO4? c. What equipment would you use to “concentrate [a solution] under reduced pressure”?

Answer 2

Question

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Answer 6

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Answer 7

Chapter 12, Problem 12.99AP

a.

Interpretation Introduction

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Answer 8

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Answer 9

b.

Interpretation Introduction

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

Answer 10

Expert Solution & Answer

Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

Solution Summary: The author explains that the chirality center of the organic compounds is drawn using the following convention.

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.

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Chapter 12 Solutions

Solution Summary: The author explains that the chirality center of the organic compounds is drawn using the following convention.

Interpretation: For the below compound, Fischer projection formula has to be drawn. Concept introduction: Refer to part ‘a.’.

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Chapter 12 Solutions

Interpretation:

For the below compound, Fischer projection formula has to be drawn.

Concept introduction:

Refer to part ‘a.’.