For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined. Concept introduction: Chirality center: When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

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Answer 1

Question

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

Answer 2

Question

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

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Answer 3

Question

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

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Answer 4

Question

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

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Answer 5

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

Answer 6

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

Answer 7

Chapter 12, Problem 12.105AP

a.

Interpretation Introduction

Interpretation:

For the lactic acid compound the chirality centers has to be labeled and number of chiral centers should be determined.

Concept introduction:

Chirality center:

When a carbon atom is bonded to four different groups, then that carbon is named as chiral carbon and it is called as chirality center. Generally, the carbon atom contains tetrahedral valency, therefore it bonded to four atoms or molecules. The chiral center is bonded with four different elements or groups. If the single carbon atom is bonded to two or more identical group or atom, then it is also not considered as chiral carbon. In addition to this, if the carbon atom contains multiple bond then it does not able to bond with four different groups then it is not considered to be as a chirality center.

Answer 8

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

Answer 9

b.

Interpretation Introduction

Interpretation:

For the lactic acid compound, Fischer projection formula has to be drawn.

Concept introduction:

Fischer projections:

In Fischer projection, the chirality center of the organic compounds are drawn using the following convention. First, the carbon atom is placed at the meeting point of the two lines of the cross. In a tetrahedron structure, the horizontal bonds indicate forward and denoted by wedges. The vertical bonds indicate backward and denoted by dashed lines. Finally, Fischer projection structure is abbreviated by cross formula.

Enantiomers:

Enantiomers are mirror image of one another and these are chiral molecules, but that are non superimposable on one another.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - a. Label the hydroxyl groups, thiols, halogens,...Ch. 12.1 - Draw out each compound to clearly show what groups...Ch. 12.2 - Classify each alcohol as 1, 2, or 3.Ch. 12.2 - Classify each hydroxyl group in sorbitol as 1, 2,...Ch. 12.2 - Which compound in each pair has the higher boiling...Ch. 12.2 - Label each compound as water soluble or water...Ch. 12.2 - Give the IUPAC name for each compound.Ch. 12.2 - Give the structure corresponding to each name. a....Ch. 12.3 - Name each ether. a. CH3OCH2CH2CH2CH3 b....Ch. 12.3 - Prob. 12.10P

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