The substance among the following pair that has the higher boiling point is to be identified. CH 3 OH or CH 3 CH 3 Concept introduction: Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows: 1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule. 2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule. 3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole. 4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule. 5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule. 6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces. The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm . The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows: dispersion forces < dipole − dipole forces < hydrogen bonds < ion − dipole forces

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Question

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Please help with number 6 I got a negative number could that be right?

1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.

Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.

Answer 2

Question

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Answer 3

Question

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Answer 4

Question

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Check out a sample textbook solution

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Answer 5

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 6

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 7

Chapter 12, Problem 12.54P

(a)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

CH3OH or CH3CH3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 8

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 9

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the higher boiling point is to be identified.

FNO or ClNO

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 10

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 11

(c)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the higher boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12.2 - Prob. 12.1AFP Ch. 12.2 - Prob. 12.1BFP Ch. 12.2 - Prob. 12.2AFP Ch. 12.2 - Prob. 12.2BFP Ch. 12.2 - Prob. 12.3AFP Ch. 12.2 - Prob. 12.3BFP Ch. 12.3 - Prob. 12.4AFP Ch. 12.3 - Prob. 12.4BFP Ch. 12.3 - Prob. 12.5AFP Ch. 12.3 - Prob. 12.5BFP

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