The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined. Concept introduction: Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows: 1. The simple cubic unit cell 2. Body-centered unit cell 3. Face-centered unit cell In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 1 8 , atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 1 2 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1 . The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively. The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

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Answer 1

Question

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

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Answer 2

Question

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

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Answer 3

Question

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

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Answer 4

Question

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

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Answer 5

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 6

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 7

Chapter 12.6, Problem 12.6AFP

(a)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in PbS is to be determined. Also, the coordination number of ions in PbS is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in W is to be determined. Also, the coordination number of atoms in W is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of atoms (or ions) per unit cell in Al is to be determined. Also, the coordination number of atoms in Al is to be determined.

Concept introduction:

Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:

1. The simple cubic unit cell

2. Body-centered unit cell

3. Face-centered unit cell

In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is 18, atom at the face is shared by 2 adjacent cells so the contribution of an atom at the face is 12 and atom at the body center is shared by 1 cell so the contribution of an atom at the body center is 1. The number of atoms present in a simple cubic, a body-centered cubic, and a face-centered cubic unit cell are 1, 2 and 4 respectively.

The nearest neighbors of an atom crystallize in a crystal is known as coordination number.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12.2 - Prob. 12.1AFP Ch. 12.2 - Prob. 12.1BFP Ch. 12.2 - Prob. 12.2AFP Ch. 12.2 - Prob. 12.2BFP Ch. 12.2 - Prob. 12.3AFP Ch. 12.2 - Prob. 12.3BFP Ch. 12.3 - Prob. 12.4AFP Ch. 12.3 - Prob. 12.4BFP Ch. 12.3 - Prob. 12.5AFP Ch. 12.3 - Prob. 12.5BFP

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