Interpretation:
- The property of metals being good conductors of heat and electricity has to be explained.
- The decrease in electrical conductivity of metals with increase in temperature has to be reasoned.
Concept Introduction:
In the periodic classification of elements, metals are located in the group
Metals are known to be good conductors of heat and electricity. Metals exist as solids called Metallic solids. Metallic solid is a typical crystalline solid where metal exist as metal ions by losing their valence electrons. Those valence electrons are termed as free electrons which are delocalized throughout the metal lattice.
Figure 1
The metal ions are arranged in a well-defined, regular, geometric pattern. The free electrons are present more in the metallic lattice that they are often referred as pool of electrons.
Want to see the full answer?
Check out a sample textbook solutionChapter 12 Solutions
Chemistry: Atoms First
- Are changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar heat of fusion and molar heat of vaporization. Why is the molar heat of vaporization of water so much larger than its molar heat of fusion? Why does the boiling point of a liquid vary with altitude?arrow_forwardHow does the sea-of-electrons model explain the high electrical conducitivity of gold ?arrow_forwardWhat is the result of heating copper metal at high temperature?arrow_forward
- Given the information below, calculate the lattice enthalpy for MX(s), where M is a group 1 metal, and X is a group 17 element (standard state: X2(g)). ΔfH°(MX) = -462 kJ mol−1 ΔsubH°(M) = 127 kJ mol−1 D(X2) = 442 kJ mol−1 IE1(M) = 480 kJ mol−1 Eeg1(X) = -142 kJ mol−1 Express your answer to four significant figures. ΔlattH°(MX) = Answer kJ mol−1arrow_forwardWhat is the best explanation for why metals are ductile? Valence electrons carry charge anywhere within molecular orbitals that span the metal. When the nuclei move relative to one another, the valence electrons act as a stretchy glue holding them together. Photons are absorbed and re-emitted. Metallic bonds involve delocalized electrons whereas covalent bonds involve localized electrons.arrow_forwardThe structures of many metals depend on pressure and temperature. Which structure—bcc or hcp—would be more likely in a given metal at very high pressures? Explain your reasoning.arrow_forward
- 22) Evaporation of sweat requires energy and thus take excess heat away from the body. Some of the water that you drink may eventually be converted into sweat and evaporate. If you drink a 20-ounce bottle of water (590g) that had been in the refrigerator at 3.8 °C, how much heat is needed to convert all of that water into sweat and then to vapor? (Note: Your body temperature is 36.6 °C. For the purpose of solving this problem, assume that the therm properties of sweat are the same as for water. Us, liquid water = 4.184 J/g °C Cs, steam= 1.84 J/g °C C3, ice = 2.09 /g °C AHvap = 40.67 kJ/mol at 36.6 °C. %3D A Hus = 6.01 kJ/mol A) 1420 kJ B) 81 kJ C) 1150 kJ 23) Based on the graph shown below, choose the correct statement about sublimation? Gas Liquid sublimation Solid A) Sublimation is a phase transition from solid to gas B) According to Hess Law, AHsub can be calculated as sum of AHvap and AHUS C) Both A and B are correctarrow_forwardWhen heating liquids in a test tube, why is the test tube moved back and forth across the flame?arrow_forward10. Explain why graphite conducts electricity whereas diamond doesn't. – (include a diagram in your explanation)arrow_forward
- Water molecules have an unparalleled ability to form hydrogen bonds with one another.Water also has an unusually high heat capacity, as measured by the amount of energy required to increase the temperature of a gram of water by 1ºC. How does hydrogen bonding contribute to water’s high heat capacity?arrow_forward(a) Consider a substance where the intermolecular forces hold the molecules in fixed rigid positions. What is the process called when enough heat has been added to the substance so that the molecules begin to flow? (b) Consider a substance where the intermolecular forces hold the molecules in close contact with each other, but the molecules can flow. What is the process called when enough heat has been added to the substance so that the molecules escape each other? (c) Consider a substance where the intermolecular forces hold the molecules in fixed rigid positions. What is the process called when enough heat has been added to the substance so that the molecules can escape each other?arrow_forwardThe enthalpy of vaporization of CO2(l) is 9.8 kJ/mol. Would you expect the enthalpy of vaporization of CS2(l) to be 28 kJ/mol, 9.8 kJ/mol, or −8.4 kJ/mol? Discuss the plausibility of each of these answers.arrow_forward
- Living By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHERChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning