The following phenomenon has to be explained – Solid argon of melting point -189 .2°C and boiling point -185 .7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen ( b .p . -195 .8°C ) until it liquefies and then connecting the flask to a vacuum pump.
The following phenomenon has to be explained – Solid argon of melting point -189 .2°C and boiling point -185 .7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen ( b .p . -195 .8°C ) until it liquefies and then connecting the flask to a vacuum pump.
Solution Summary: The author explains that the melting point of cyclohexane increases with increasing pressure exerted on it.
Solid argon of melting point
-189.2°C and boiling point -185.7°C can be prepared by immersing a flask containing argon gas in liquid nitrogen
(b.p. -195.8°C) until it liquefies and then connecting the flask to a vacuum pump.
(b)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
The melting point of cyclohexane
(C6H12) increases with increasing pressure exerted on the solid cyclohexane.
(c)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
Certain high-altitude clouds contain water droplets at
-10°C.
(d)
Interpretation Introduction
Interpretation:
The following phenomenon has to be explained –
When a piece of dry ice is added to a beaker of water, fog forms above the water.
. The molar heat of evaporation of ammonia is 23.4 kJ mol-1.
4(a) How much heat is required to vaporize 1.00 kg of ammonia?
4(b) How many grams of water at 0°C must be frozen to ice at 0°C to ensure the evaporation of 1 kg of ammonia?
Given: M(NH3) = 17 g mol-1, M(H2O) = 18 g mol-1 and heat of fusion (melting) of ice = 6.01 kJ mol-1
4. A. Use the list of intermolecular and interparticle forces listed below to account for the following
phenomena. Justify your answer in each case.
London Dispersion Forces
lonic Bonding
Dipole-Dipole Interactions
Metallic Bonding
Hydrogen Bonding
Covalent Bonding
(i) Nacl has a very high heat of vaporization.
(ii) The high volatility of helium (boiling point is - 267 °C, lowest of any element).
(iii) What are the strongest attractive forces that must be overcome to boil carbon tetrachloride,
(CCl,)?
B. Read the following statement: NaF has a higher melting point than F2 because it has a greater molar
mass. Do you agree with the statement? Explain why you believe the statement is true or falsr
The vapor pressure data for Hg with respect to temperature is given in the table below. From the data given in the table, answer the questions that follow.
(A). Calculate its enthalpy of vaporization, ∆H vap (in KJ/mole).
(B). Calculate its normal boiling point (in Kelvins).
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