General Chemistry - Standalone book (MindTap Course List)
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 12, Problem 12.132QP
Interpretation Introduction

Interpretation:

A solution of – 0.360 mol Na3PO4, 0.100 mol Ca(NO3)2 and 0.100 mol AgNO3 are prepared in 4.000 L of water.  Occurrence of precipitation reaction has to be confirmed by writing balanced equation.  Molarity of each ion in its solution has to be calculated.

Concept Introduction:

Molarity is a term used to express concentration of a solution.  It is expressed as,

Molarity = number of moles of solutevolume of solution in L

Expert Solution & Answer
Check Mark

Answer to Problem 12.132QP

Molarity of Na+, PO42- and NO3- ions are calculated as 0.270 M, 0.650 M, 0.0750 M respectively.

Explanation of Solution

Determine the number of moles of each ion present in the solution.  Totally five types ions are present in the solution as follows – Na+, PO43, Ca2+, Ag+ and NO3 .

No. of moles of 3 Na+ ions = 3×0.360 mol = 1.080 molNo. of moles of PO43 ions =  0.360 molno. of moles of Ca2+ ions = 0.100 molno.of moles of Ag+ ions = 0.100 molno.of moles of NO3 ions = 0.100 mol + 2(0.100 mol) = 0.300 mol

Calcium ions and Silver ions get precipitated by phosphate ions that two compounds are precipitated.  The precipitation is represented in equation as follows –

Ca2+(aq) + 2 PO43(aq)  Ca3(PO4)2(s)3Ag+(aq) + PO43(aq)    Ag3PO4(s)

Na+ ions are not precipitated by CO32 ions.  All amount of CO32 ions don’t involve in precipitation reaction.  The remaining moles of CO32 are –

0.360 mol23×0.100 - 13×0.100 mol = 0.2600 mol

Volume of the solution is 4.000 L .  As Ca2+and Ag+ ions are precipitated, only Na+,PO43and NO3 ions are left over in the solution.  Molarity of each ion in the solution is calculated as,

Molarity of Na+ ions =  no. of moles of Na+ ionsvolume of solution in L               =   0.1080 mol Na+4.000 L = 0.270 MMolarity of PO43 ions =  no. of moles of PO43 ions4.000 L               =   0.2600 mol Na+4.000 L = 0.650 MMolarity of NO3 ions =  no. of moles of NO3 ionsvolume of solution in L               =   0.300 mol NO32.000 L = 0.0750 M

Conclusion

Molarity of various ions present in a solution is calculated using number of moles of the ions.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
Calculate the maximum solubility of calcium fluoride, CaF2 in g/L when in the presence of 0.077 M Ca(NO3)2. The solubility product of CaF2 is 4.2x1011 and CaF2 has a molar mass of 78.08 g/mol. Express your answer to the correct number of significant figures, in scientific notation and include the unit with your answer.
Calculate the concentration of the aqueous product that forms when 0.111 L of 0.017 M CaBr2 is added to 0.137 L of 0.87 M (NH4)2CO3. Report the concentration in M units. Don't forget to consider volume change when the two solutions are added together.
How to prepare these solutions? 250.0 mL 0.125 M stock Na2S2O3 solution from Na2S2O3·5H2O crystals 250 mL 0.10 M NaOHNOTE: Use the 1.0 M NaOH prepared250.0 mL standard 2500 ppm Cu(II) stock solutiona. Weigh and dissolve appropriate amount of Cu(NO3)2·5H2O crystals in enough distilled water.

Chapter 12 Solutions

General Chemistry - Standalone book (MindTap Course List)

Ch. 12.4 - Prob. 12.7ECh. 12.4 - A solution is 0.120 m methanol dissolved in...Ch. 12.4 - A solution is 0.250 mole fraction methanol, CH3OH,...Ch. 12.4 - Urea, (NH2)2CO, is used as a fertilizer (sec the...Ch. 12.4 - Prob. 12.11ECh. 12.5 - Naphthalene, C10H8, is used to make mothballs....Ch. 12.5 - Prob. 12.5CCCh. 12.6 - How many grams of ethylene glycol, CH2OHCH2OH,...Ch. 12.6 - A 0.930-g sample of ascorbic acid (vitamin C) was...Ch. 12.6 - A 0.205-g sample of white phosphorus was dissolved...Ch. 12.7 - Calculate the osmotic pressure at 20C of an...Ch. 12.7 - Prob. 12.6CCCh. 12.8 - Prob. 12.17ECh. 12.8 - Each of the following substances is dissolved in a...Ch. 12.9 - Prob. 12.18ECh. 12.9 - If electrodes that are connected to a direct...Ch. 12 - Prob. 12.1QPCh. 12 - Prob. 12.2QPCh. 12 - Explain in terms of intermolecular attractions why...Ch. 12 - Prob. 12.4QPCh. 12 - Using the concept of hydration, describe the...Ch. 12 - What is the usual solubility behavior of an ionic...Ch. 12 - Give one example of each: a salt whose heat of...Ch. 12 - What do you expect to happen to a concentration of...Ch. 12 - Prob. 12.9QPCh. 12 - Pressure has an effect on the solubility of oxygen...Ch. 12 - Prob. 12.11QPCh. 12 - When two beakers containing different...Ch. 12 - Prob. 12.13QPCh. 12 - Prob. 12.14QPCh. 12 - Prob. 12.15QPCh. 12 - Prob. 12.16QPCh. 12 - One can often see sunbeams passing through the...Ch. 12 - Prob. 12.18QPCh. 12 - Explain on the basis that like dissolves like why...Ch. 12 - Prob. 12.20QPCh. 12 - Calculate the number of moles of barium chloride...Ch. 12 - Prob. 12.22QPCh. 12 - If 291g of a compound is added to 1.02 kg of water...Ch. 12 - A 5.1-g sample of CaCl2 is dissolved in a beaker...Ch. 12 - Consider two hypothetical pure substances, AB(s)...Ch. 12 - Equal numbers of moles of two soluble, substances,...Ch. 12 - Even though the oxygen demands of trout and bass...Ch. 12 - You want to purchase a salt to melt snow and ice...Ch. 12 - Prob. 12.29QPCh. 12 - Prob. 12.30QPCh. 12 - Prob. 12.31QPCh. 12 - Consider the following dilute NaCl(aq) solutions....Ch. 12 - Prob. 12.33QPCh. 12 - Prob. 12.34QPCh. 12 - If l-mol samples of urea, a nonelectrolyte, sodium...Ch. 12 - Prob. 12.36QPCh. 12 - Prob. 12.37QPCh. 12 - Prob. 12.38QPCh. 12 - Prob. 12.39QPCh. 12 - Prob. 12.40QPCh. 12 - Arrange the following substances in order of...Ch. 12 - Indicate which of the following is more soluble in...Ch. 12 - Prob. 12.43QPCh. 12 - Which of the following ions would be expected to...Ch. 12 - Arrange the following alkaline-earth-metal iodates...Ch. 12 - Explain the trends in solubility (grams per 100 mL...Ch. 12 - The solubility of carbon dioxide in water is 0.161...Ch. 12 - Prob. 12.48QPCh. 12 - Prob. 12.49QPCh. 12 - Prob. 12.50QPCh. 12 - Prob. 12.51QPCh. 12 - Prob. 12.52QPCh. 12 - Vanillin, C2H2O3, occurs naturally in vanilla...Ch. 12 - Lauryl alcohol, C12H25OH, is prepared from coconut...Ch. 12 - Fructose, C6H12O6, is a sugar occurring in honey...Ch. 12 - Caffeine. C8H10N4O2, is a stimulant found in tea...Ch. 12 - A 100.0-g sample of a brand of rubbing alcohol...Ch. 12 - An automobile antifreeze solution contains 2.50 kg...Ch. 12 - Prob. 12.59QPCh. 12 - Prob. 12.60QPCh. 12 - Concentrated hydrochloric acid contains 1.00 mol...Ch. 12 - Concentrated aqueous ammonia contains 1.00 mol NH3...Ch. 12 - Prob. 12.63QPCh. 12 - Prob. 12.64QPCh. 12 - A solution of vinegar is 0.763 M acetic arid,...Ch. 12 - A beverage contains tartaric acid, H2C4H4O6, a...Ch. 12 - Calculate the vapor pressure at 35C of a solution...Ch. 12 - What is the vapor pressure at 23C of a solution of...Ch. 12 - What is the boiling point of a solution of 0.133 g...Ch. 12 - A solution was prepared by dissolving 0.800 g of...Ch. 12 - An aqueous solution of a molecular compound...Ch. 12 - Urea, (NH2)2CO, is dissolved in 250.0 g of water....Ch. 12 - Prob. 12.73QPCh. 12 - Prob. 12.74QPCh. 12 - Safrole is contained in oil of sassafras and was...Ch. 12 - Butylated hydroxytoluene (BHT) is used as an...Ch. 12 - Prob. 12.77QPCh. 12 - Prob. 12.78QPCh. 12 - What is the freezing point of 0.0075 m aqueous...Ch. 12 - What is the freezing point of 0.0088 m aqueous...Ch. 12 - Prob. 12.81QPCh. 12 - In a mountainous location, the boiling point of...Ch. 12 - Prob. 12.83QPCh. 12 - Prob. 12.84QPCh. 12 - Prob. 12.85QPCh. 12 - Prob. 12.86QPCh. 12 - A gaseous mixture consists of 87.0 mole percent N2...Ch. 12 - A natural gas mixture consists of 88.0 mole...Ch. 12 - Prob. 12.89QPCh. 12 - Prob. 12.90QPCh. 12 - A 55-g sample of a gaseous fuel mixture contains...Ch. 12 - Prob. 12.92QPCh. 12 - A liquid solution consists of 0.30 mole fraction...Ch. 12 - What is the total vapor pressure at 20C of a...Ch. 12 - A sample of potassium aluminum sulfate 12-hydrate....Ch. 12 - A sample of aluminum sulfate 18-hydrate,...Ch. 12 - Urea, (NH2)2CO, has been used to melt ice from...Ch. 12 - Calcium chloride, CaCl2, has been used to melt ice...Ch. 12 - Prob. 12.99QPCh. 12 - Prob. 12.100QPCh. 12 - Which aqueous solution has the lower freezing...Ch. 12 - Which aqueous solution has the lower boiling...Ch. 12 - Commercially, sulfuric acid is usually obtained as...Ch. 12 - Prob. 12.104QPCh. 12 - A compound of manganese, carbon, and oxygen...Ch. 12 - A compound of cobalt, carbon, and oxygen contains...Ch. 12 - The carbohydrate digitoxose contains 48.64% carbon...Ch. 12 - Analysis of a compound gave 39.50% C, 2.21% H, and...Ch. 12 - Fish blood has an osmotic pressure equal to that...Ch. 12 - Prob. 12.110QPCh. 12 - Prob. 12.111QPCh. 12 - Prob. 12.112QPCh. 12 - How are phospholipids similar in structure to a...Ch. 12 - Prob. 12.114QPCh. 12 - Two samples of sodium chloride solutions are...Ch. 12 - Prob. 12.116QPCh. 12 - You have an aqueous, dilute solution of a...Ch. 12 - Prob. 12.118QPCh. 12 - Prob. 12.119QPCh. 12 - Prob. 12.120QPCh. 12 - When 79.3 g of a particular compound is dissolved...Ch. 12 - What is the boiling point of a solution made by...Ch. 12 - Prob. 12.123QPCh. 12 - Prob. 12.124QPCh. 12 - Prob. 12.125QPCh. 12 - Prob. 12.126QPCh. 12 - Prob. 12.127QPCh. 12 - Prob. 12.128QPCh. 12 - An aqueous solution is 0.797 M magnesium chloride....Ch. 12 - A CaCl2 solution at 25C has an osmotic pressure of...Ch. 12 - Prob. 12.131QPCh. 12 - Prob. 12.132QPCh. 12 - The lattice enthalpy of sodium chloride, H for...Ch. 12 - Prob. 12.134QPCh. 12 - Prob. 12.135QPCh. 12 - Prob. 12.136QPCh. 12 - Prob. 12.137QPCh. 12 - An aqueous solution is 20.0% by mass of sodium...Ch. 12 - Prob. 12.139QPCh. 12 - The freezing point of 0.109 m aqueous formic acid...Ch. 12 - A compound of carbon, hydrogen, and oxygen was...Ch. 12 - A compound of carbon, hydrogen, and oxygen was...
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY