Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 11.9, Problem 19CC
Interpretation Introduction
Interpretation:
The hydrogen atom that gets easily abstracted from the given molecule vitamin E should be determined.
Concept introduction:
Radical or free radical: The unpaired valence electron of an atom, molecule, or ion is called as radical. The stability order for radical is as follows,
The movement of single electron present in the molecule is usually denoted by using the half headed arrows called fishhook arrows.
Resonance: The molecule is said to have resonance structures if it has more than one structure by migrating lone pair, radical or the phi bonds present in the molecule.
Resonance stabilization: Due to the delocalization of electrons within the molecule the overall energy becomes lower and makes the molecule more stable.
Bond strength present in the molecule depends on the formation of the radical, if the radical formed is resonance stabilized then the bond associated with it is weak than the other bond present in the molecule.
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Predict the major products of this reaction:
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Note that the second reactant is used in excess, that is, there is much more of the second reactant than the first.
If there won't be any products, just check the box under the drawing area instead.
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A student claims the right-hand side of the reaction in the drawing area below shows the product of a Claisen condensation.
• If the student is correct, complete the reaction by adding the necessary organic reactants to the left-hand side, and by adding any necessary reagents and
reaction conditions above and below the arrow.
• If the student is incorrect, because it's not possible to obtain this product from a Claisen condensation, check the box under the drawing area instead.
those that will minimize any byproducts or competing
• Note for advanced students: If you have a choice, use the most efficient reactants and reagents
reactions.
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Click and drag to start
drawing a structure.
identify the relationship between the
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H
H-
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Chapter 11 Solutions
Organic Chemistry
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 1LTSCh. 11.1 - Prob. 2PTSCh. 11.1 - Prob. 3ATSCh. 11.1 - Prob. 4ATSCh. 11.1 - Prob. 2LTSCh. 11.1 - Prob. 5PTSCh. 11.1 - Prob. 6ATSCh. 11.2 - Prob. 3LTSCh. 11.2 - Prob. 7PTS
Ch. 11.2 - Prob. 8ATSCh. 11.2 - Prob. 9ATSCh. 11.3 - Prob. 4LTSCh. 11.3 - Prob. 10PTSCh. 11.3 - Prob. 11ATSCh. 11.5 - Prob. 5LTSCh. 11.5 - Prob. 12PTSCh. 11.5 - Prob. 13ATSCh. 11.6 - Prob. 6LTSCh. 11.6 - Prob. 14PTSCh. 11.6 - Prob. 15ATSCh. 11.7 - Prob. 7LTSCh. 11.7 - Prob. 16PTSCh. 11.7 - Prob. 17ATSCh. 11.8 - Prob. 18CCCh. 11.9 - Prob. 19CCCh. 11.10 - Prob. 8LTSCh. 11.10 - Prob. 20PTSCh. 11.10 - Prob. 21ATSCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26PPCh. 11 - Prob. 27PPCh. 11 - Prob. 28PPCh. 11 - Prob. 29PPCh. 11 - Prob. 30PPCh. 11 - Prob. 31PPCh. 11 - Prob. 32PPCh. 11 - Prob. 33PPCh. 11 - Prob. 34PPCh. 11 - Prob. 35PPCh. 11 - Prob. 36PPCh. 11 - Prob. 37PPCh. 11 - Prob. 38PPCh. 11 - Prob. 39PPCh. 11 - Prob. 40PPCh. 11 - Prob. 41PPCh. 11 - Prob. 42IPCh. 11 - Prob. 43IPCh. 11 - Prob. 44IPCh. 11 - Prob. 45IPCh. 11 - Prob. 46IPCh. 11 - Prob. 47IPCh. 11 - Prob. 48IPCh. 11 - Prob. 49IP
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- The right-hand side of this reaction shows the product of an aldol condensation. What are the reactants missing from the left-hand side? Draw them below. ? NaOH Δ If there aren't any reactants that would lead to these products under the reaction conditions given, just check the box under the drawing area. Note for advanced students: don't worry if the reactants you propose might also make some other products under these reaction conditions. Just make sure the product above is one of the major products.arrow_forwardPlease help! I need to identify four labeled unknown bottles based off of their colors doing titration using phenlphtalein. I've included my answers, but I wanted to make sure they were correct and if not, what will be correct thank you in advance.arrow_forwardAn organic chemistry Teaching Assistant (TA) suggested in your last discussion section that there is only one major organic product of the following reaction and that this reaction builds a ring. If the TA is right, draw the product in the drawing area below. If the TA is wrong, just check the box below the drawing area. NaOH ?arrow_forward
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