
Interpretation:
The resonance structure of the radical should be identified for the given molecule.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical

Answer to Problem 22PP
Answer
An unpaired electron occupies the allylic position and in is involving in resonance. The arrow pattern of radical resonance is given below (a).
An unpaired electron occupies the allylic position and in is involving in resonance. The arrow pattern of radical resonance is given below (b).
An unpaired electron occupies the allylic position and in is involving in resonance. The arrow pattern of radical resonance is given below (c).
Unpaired electrons resonance with allylic double bonds. The arrow pattern of radical resonance is given below (d).
Unpaired electrons resonance with allylic double bonds. The arrow pattern of radical resonance is given below (f)
Explanation of Solution
The radical resonance structure of the given molecule
The radical resonance structure of the molecule is given below.
An unpaired electron occupies the allylic position and in is involving in resonance. Here three fishhook arrows were used to show the resonance.
The radical resonance structure of the molecule is given below.
An unpaired electron occupies the allylic position and in is involving in resonance. Here three fishhook arrows were used to show the resonance. The resulting resonance structure exhibits an unpaired electrons, the unpaired electrons allylic to another π bond that also involving resonance. Again three fishhook arrows were used for the resonance.
The radical resonance structure of the molecule is given below.
An unpaired electron occupies the allylic position and in is involving in resonance. Here three fishhook arrows were used to show the resonance. The resulting resonance structure exhibits an unpaired electrons, the unpaired electrons allylic to another π bond that also involving resonance. Again three fishhook arrows were used for the resonance.
The radical resonance structure of the molecule is given below.
An unpaired electron occupies the allylic position and in is involving in resonance. Here three fishhook arrows were used to show the resonance. The resulting resonance structure exhibits an unpaired electrons, the unpaired electrons allylic to another π bond that also involving resonance. Again three fishhook arrows were used for the resonance. Similarly the five resonances structure is exist in same manner as shown above structure.
The radical resonance structure of the molecule is given below.
An unpaired electron occupies the allylic position and in is involving in resonance. Here three fishhook arrows were used to show the resonance. The resulting resonance structure exhibits an unpaired electrons, the unpaired electrons allylic to another π bond that also involving resonance. Again three fishhook arrows were used for the resonance. Similarly the five resonances structure is exist in same manner as shown above structure.
Conclusion
The resonance structure of the radical for the given molecule is found.
Want to see more full solutions like this?
Chapter 11 Solutions
Organic Chemistry
- Use diagram to answer the following: 1.Is the overall rxn endo- or exothermic. Explain briefly your answer____________________2. How many steps in this mechanism?_____________3. Which is the rate determining step? Explain briefly your answer____________________4. Identify (circle and label) the reactants,the products and intermediate (Is a Cation, Anion, or a Radical?) Please explain and provide full understanding.arrow_forwardDraw the entire mechanism and add Curved Arrows to show clearly how electrons areredistributed in the process. Please explain and provide steps clearly.arrow_forward15) Create Lewis structure Br Brarrow_forward
- LIOT S How would you make 200. mL of a 0.5 M solution of CuSO4 5H2O from solid copper (II) sulfate? View Rubricarrow_forwardSteps and explantions pleasearrow_forwardMatch the denticity to the ligand. Water monodentate ✓ C₂O2 bidentate H₂NCH₂NHCH2NH2 bidentate x EDTA hexadentate Question 12 Partially correct Mark 2 out of 2 Flag question Provide the required information for the coordination compound shown below: Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2✔ Geometry: linear Oxidation state of transition metal ion: +3 x in 12 correct out of 2 question Provide the required information for the coordination compound shown below. Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2 Geometry: linear 0 Oxidation state of transition metal ion: +3Xarrow_forward
- Can you explain step by step behind what the synthetic strategy would be?arrow_forwardPlease explain step by step in detail the reasoning behind this problem/approach/and answer. thank you!arrow_forward2. Predict the product(s) that forms and explain why it forms. Assume that any necessary catalytic acid is present. .OH HO H₂N OHarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





