Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 11, Problem 32PP
Interpretation Introduction
Interpretation:
The increasing stability of the given molecule should be identified.
Concept introduction:
Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.
Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.
Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.
The increasing order of radical stability is given below
Benzylic > allylic > tertiary > secondary > primary > methyl
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Chapter 11 Solutions
Organic Chemistry
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 1LTSCh. 11.1 - Prob. 2PTSCh. 11.1 - Prob. 3ATSCh. 11.1 - Prob. 4ATSCh. 11.1 - Prob. 2LTSCh. 11.1 - Prob. 5PTSCh. 11.1 - Prob. 6ATSCh. 11.2 - Prob. 3LTSCh. 11.2 - Prob. 7PTS
Ch. 11.2 - Prob. 8ATSCh. 11.2 - Prob. 9ATSCh. 11.3 - Prob. 4LTSCh. 11.3 - Prob. 10PTSCh. 11.3 - Prob. 11ATSCh. 11.5 - Prob. 5LTSCh. 11.5 - Prob. 12PTSCh. 11.5 - Prob. 13ATSCh. 11.6 - Prob. 6LTSCh. 11.6 - Prob. 14PTSCh. 11.6 - Prob. 15ATSCh. 11.7 - Prob. 7LTSCh. 11.7 - Prob. 16PTSCh. 11.7 - Prob. 17ATSCh. 11.8 - Prob. 18CCCh. 11.9 - Prob. 19CCCh. 11.10 - Prob. 8LTSCh. 11.10 - Prob. 20PTSCh. 11.10 - Prob. 21ATSCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26PPCh. 11 - Prob. 27PPCh. 11 - Prob. 28PPCh. 11 - Prob. 29PPCh. 11 - Prob. 30PPCh. 11 - Prob. 31PPCh. 11 - Prob. 32PPCh. 11 - Prob. 33PPCh. 11 - Prob. 34PPCh. 11 - Prob. 35PPCh. 11 - Prob. 36PPCh. 11 - Prob. 37PPCh. 11 - Prob. 38PPCh. 11 - Prob. 39PPCh. 11 - Prob. 40PPCh. 11 - Prob. 41PPCh. 11 - Prob. 42IPCh. 11 - Prob. 43IPCh. 11 - Prob. 44IPCh. 11 - Prob. 45IPCh. 11 - Prob. 46IPCh. 11 - Prob. 47IPCh. 11 - Prob. 48IPCh. 11 - Prob. 49IP
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