Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 11.5, Problem 5LTS
Interpretation Introduction
Interpretation:
The major product obtained from the radical bromination for given molecule should be identified.
Concept introduction:
Radical bromination: It is a type of halogenation reaction in which the bromine atom gets bonded with the
Radical reaction of
Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.
The increasing order of radical stability is given below
Benzylic > allylic > tertiary > secondary > primary > methyl
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 11 Solutions
Organic Chemistry, Binder Ready Version
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 1LTSCh. 11.1 - Prob. 2PTSCh. 11.1 - Prob. 3ATSCh. 11.1 - Prob. 4ATSCh. 11.1 - Prob. 2LTSCh. 11.1 - Prob. 5PTSCh. 11.1 - Prob. 6ATSCh. 11.2 - Prob. 3LTSCh. 11.2 - Prob. 7PTS
Ch. 11.2 - Prob. 8ATSCh. 11.2 - Prob. 9ATSCh. 11.3 - Prob. 4LTSCh. 11.3 - Prob. 10PTSCh. 11.3 - Prob. 11ATSCh. 11.5 - Prob. 5LTSCh. 11.5 - Prob. 12PTSCh. 11.5 - Prob. 13ATSCh. 11.6 - Prob. 6LTSCh. 11.6 - Prob. 14PTSCh. 11.6 - Prob. 15ATSCh. 11.7 - Prob. 7LTSCh. 11.7 - Prob. 16PTSCh. 11.7 - Prob. 17ATSCh. 11.8 - Prob. 18CCCh. 11.9 - Prob. 19CCCh. 11.10 - Prob. 8LTSCh. 11.10 - Prob. 20PTSCh. 11.10 - Prob. 21ATSCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26PPCh. 11 - Prob. 27PPCh. 11 - Prob. 28PPCh. 11 - Prob. 29PPCh. 11 - Prob. 30PPCh. 11 - Prob. 31PPCh. 11 - Prob. 32PPCh. 11 - Prob. 33PPCh. 11 - Prob. 34PPCh. 11 - Prob. 35PPCh. 11 - Prob. 36PPCh. 11 - Prob. 37PPCh. 11 - Prob. 38PPCh. 11 - Prob. 39PPCh. 11 - Prob. 40PPCh. 11 - Prob. 41PPCh. 11 - Prob. 42IPCh. 11 - Prob. 43IPCh. 11 - Prob. 44IPCh. 11 - Prob. 45IPCh. 11 - Prob. 46IPCh. 11 - Prob. 47IPCh. 11 - Prob. 48IPCh. 11 - Prob. 49IP
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