The increasing stability of the given molecule should be identified. Concept introduction: Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom. Inductive effect : An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule. Hyperconjugation effect : The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation. The increasing order of radical stability is given below Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 1

Question

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 2

Question

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 3

Question

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 4

Question

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

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Answer 5

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 6

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 7

Chapter 11, Problem 32PP

Interpretation Introduction

Interpretation:

The increasing stability of the given molecule should be identified.

Concept introduction:

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

Inductive effect: An inductive effect is polarization of σ bonds which is depends on the electronegativity of the molecule.

Hyperconjugation effect: The electrons in the sigma bond interacts with either empty or nonbonding p orbital and also interacts with antibonding σ or π orbital, or filled π orbital which results in the extra stability of the system and the phenomenon is termed as hyperconjugation.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11.1 - Prob. 1CC Ch. 11.1 - Prob. 1LTS Ch. 11.1 - Prob. 2PTS Ch. 11.1 - Prob. 3ATS Ch. 11.1 - Prob. 4ATS Ch. 11.1 - Prob. 2LTS Ch. 11.1 - Prob. 5PTS Ch. 11.1 - Prob. 6ATS Ch. 11.2 - Prob. 3LTS Ch. 11.2 - Prob. 7PTS

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Chapter 11 Solutions