Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 11, Problem 40PP
Interpretation Introduction
Interpretation:
The formation of the product should be identified.
Concept introduction:
NBS: N-Bromo succinimide is the brominating agent and it is used as a source of bromine in the radical reaction. Bromine can also use as a brominating agent.
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
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C-RSA CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.0 b.092
0.797
1.088
1.813
C-RSA CHROMATOPAC CH=1 Report No. =13
** CALCULATION REPORT **
DATA=1: @CHRM1.000 11/03/05 08:09:52
CH PKNO
TIME
1
2
0.797
3
1.088
4
1.813
AREA
1508566
4625442
2180060
HEIGHT
207739
701206 V
287554 V
MK IDNO
CONC
NAME
18.1447
55.6339
26.2213
TOTAL
8314067 1196500
100
C-R8A CHROMATOPAC CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0. 0
087
337.
0.841
1.150
C-R8A CHROMATOPAC CH=1 Report No. =14
DATA=1: @CHRM1.000 11/03/05 08:12:40
** CALCULATION REPORT **
CH PKNO
TIME
AREA
1
3 0.841
1099933
41.15
4039778
HEIGHT MK IDNO
170372
649997¯¯¯
CONC
NAME
21.4007
78.5993
TOTAL
5139711 820369
100
3
C-R8A CHROMATOPAC
CH=1
DATA 1: @CHRM1.C00
ATTEN=10 SPEED= 10.0
0.100
0:652
5.856
3
1.165
C-RSA CHROMATOPAC CH-1 Report No. =15
DATA=1: @CHRM1.000 11/03/05 08:15:26
** CALCULATION REPORT **
CH PKNO TIME
AREA
HEIGHT MK IDNO CONC
NAME
1 3 3 0.856
4
1.165
TOTAL
1253386
4838738
175481
708024 V
20.5739
79.4261
6092124…
Draw the product of the reaction shown below. Ignore small byproducts that would evaporate please.
Relative Abundance
20-
Problems
501
(b) The infrared spectrum has a medium-intensity peak at about 1650 cm. There is also a
C-H out-of-plane bending peak near 880 cm.
100-
80-
56
41
69
M(84)
LL
15 20 25
30
35
55 60 65 70
75
80
85 90
m/z
Chapter 11 Solutions
Organic Chemistry, Binder Ready Version
Ch. 11.1 - Prob. 1CCCh. 11.1 - Prob. 1LTSCh. 11.1 - Prob. 2PTSCh. 11.1 - Prob. 3ATSCh. 11.1 - Prob. 4ATSCh. 11.1 - Prob. 2LTSCh. 11.1 - Prob. 5PTSCh. 11.1 - Prob. 6ATSCh. 11.2 - Prob. 3LTSCh. 11.2 - Prob. 7PTS
Ch. 11.2 - Prob. 8ATSCh. 11.2 - Prob. 9ATSCh. 11.3 - Prob. 4LTSCh. 11.3 - Prob. 10PTSCh. 11.3 - Prob. 11ATSCh. 11.5 - Prob. 5LTSCh. 11.5 - Prob. 12PTSCh. 11.5 - Prob. 13ATSCh. 11.6 - Prob. 6LTSCh. 11.6 - Prob. 14PTSCh. 11.6 - Prob. 15ATSCh. 11.7 - Prob. 7LTSCh. 11.7 - Prob. 16PTSCh. 11.7 - Prob. 17ATSCh. 11.8 - Prob. 18CCCh. 11.9 - Prob. 19CCCh. 11.10 - Prob. 8LTSCh. 11.10 - Prob. 20PTSCh. 11.10 - Prob. 21ATSCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Prob. 25PPCh. 11 - Prob. 26PPCh. 11 - Prob. 27PPCh. 11 - Prob. 28PPCh. 11 - Prob. 29PPCh. 11 - Prob. 30PPCh. 11 - Prob. 31PPCh. 11 - Prob. 32PPCh. 11 - Prob. 33PPCh. 11 - Prob. 34PPCh. 11 - Prob. 35PPCh. 11 - Prob. 36PPCh. 11 - Prob. 37PPCh. 11 - Prob. 38PPCh. 11 - Prob. 39PPCh. 11 - Prob. 40PPCh. 11 - Prob. 41PPCh. 11 - Prob. 42IPCh. 11 - Prob. 43IPCh. 11 - Prob. 44IPCh. 11 - Prob. 45IPCh. 11 - Prob. 46IPCh. 11 - Prob. 47IPCh. 11 - Prob. 48IPCh. 11 - Prob. 49IP
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